WET SCRUBBERS W ì fCermetli C. Schffftner, BSMi Technical Director, Compliance Systems International How ard E« Hesicetli, Ph.D., P Professor Emeritus, Southern Illinois University Taylor &. Francis Taylor &. Francis Group Boca Raton London New York CRC is an imprint of the Taylor & Francis Group, an informa business Published in 1996 by CRC Press Taylor & Francis Group 6000 Broken Sound Parkway NW, Suite 300 Boca Raton, FL 33487-2742 © 1996 by Taylor & Francis Group, LLC CRC Press is an imprint of Taylor & Francis Group No claim to original U.S. Government works Printed in the United States of America on acid-free paper 10 9 8 7 6 5 4 3 International Standard Book Number-10: 1-56676-379-7 (Softcover) International Standard Book Number-13: 978-1-56676-379-0 (Softcover) Library of Congress catalog number: 95-62014 This book contains information obtained from authentic and highly regarded sources. Reprinted material is quoted with permission, and sources are indicated. A wide variety of references are listed. Reasonable efforts have been made to publish reliable data and information, but the author and the publisher cannot assume responsibility for the validity of all materials or for the consequences of their use. No part of this book may be reprinted, reproduced, transmitted, or utilized in any form by any electronic, mechanical, or other means, now known or hereafter invented, including photocopying, microfilming, and recording, or in any information storage or retrieval system, without written permission from the publishers. Trademark Notice: Product or corporate names may be trademarks or registered trademarks, and are used only for identification and explanation without intent to infringe. Library of Congress Cataloging-in-Publication Data Catalog record is available from the Library of Congress informa Visit thè Taylor & Francis Web site at http://www.taylorandfrancis.com Taylor & Francis Group and thè CRC Press Web site at is the Academic Division of Informa pic. http://www.crcpress.com TABLE OF CONTENTS Preface vii Preface to the First Edition IX Acknowledgements xi Introduction xiii Nomenclature xv Chapter 1. Application Engineering Basics 1.1 Introduction 1 1.2 Scrubber Types 4 1.3 Basic Calculations 10 1.4 Particulate Scrubbers Available 30 1.5 Absorber Calculations 47 1.6 Mist Elimination 54 1.7 Additional Suggested Reading 61 1.8 References 64 Chapter 2. Fiberbed Filters and Wet Scrubbing . . . .67 2.1 Collection by Direct Interception 71 2.2 Collection by Inertial Interception 72 2.3 Collection by Brownian Motion of Particles 72 2.4 Pressure Drop 76 2.5 Reentrainment 80 2.6 References 85 VI Table of Contents Chapter 3. Scrubber Applications ............ .87 3„1 Introduction 87 3.2 Asphalt Plant Scrubbers 87 3.3 Bark Boiler Scrubbers 92 3.4 Foundry Cupola Scrubbers (Ferrous Metals) 100 3.5 Lime Kiln Scrubbers 104 3.6 Municipal Sledge Incinerator Scrubbers 115 3.7 Sewage Sledge Dryer Scrubbers 120 3.8 Industrial Boiler Scrubbers 129 3.9 Odor Control Scrubbers 141 3.10 Hybrid Scrubbers 148 3.11 Waste Minimization Using Wet Scrubbing Techniques 162 3.12 References 173 Chapter 4« Maintenance and Control 175 4.1 Introduction 175 4.2 Optimization 175 4.3 System Characteristics 179 4.4 Chemical Control 180 4.5 Other Instrumentation 181 4.6 Personnel 181 4.7 Checklists 181 4.8 References 184 Chapter 5. Testing Wet Scrubbers . . . 185 5.1 Introduction 185 5.2 Dry Flue Gas Composition 185 5.3 Diagnostic Testing 186 5.4 Compliance Testing 190 5.5 References 192 Chapter 6. Suggested Readings .........................................193 Index 199 About the Authors 205 PREFACE Welcome to the second edition of Wet Scrubbers. It hardly seems that it was more than a decade ago that Dr. Howard Hesketh and I wrote the first edition of Wet Scrubbers. The purpose then was to provide an easy-to-read, easy-to-understand technical book on the design and application of gas cleaning technologies that use liquids. The original edition found its way onto the reference shelves of plant engineers, environmental engineers, regulatory personnel, and others who spend all or part of their time studying and/or solving air pollution problems. It has also been added to many libraries as a useful reference tool for students and others interested in pollution control. We have been very pleased to hear many favorable comments from those individuals who use Wet Scrubbers as a reference. Our purpose in providing this second edition is to build upon that base and update a number of chapters to reflect the exciting changes that have oc curred in the industry during the last decade. We have added to the theory of operation of wet scrubbers, included a section on new ‘‘hybrid” scrubber systems that use multiple control techniques, and added a section on ir rigated fiberbed filters that utilize Brownian motion capture techniques for fine aerosol capture. During the last decade, regulatory codes have become increasingly strin gent, prompting designers to seek either better performance for their ex isting control equipment or to add new equipment of higher efficiency. Technology to control specific pollutants such as mercury compounds, hexavalent chrome, and dioxins have all been “developed” in the last decade in response to real or perceived needs to control these pollutants. Some of the processes “developed,” such as flux force condensation scrubbing, were in actuality rediscovered. Coupled with cost constraints, the challenge VII VIII Preface facing personnel confronted with environmental compliance can appear daunting. A careful review of the technologies available, however, can lead to successful completion of such projects. It can be said that air pollution control is a mixture of control technology, economics, health sciences, safety considerations, plant design, law, statis tics, judgment, and, yes, beliefs. The air pollution control engineering en vironment, we feel, is regulatory-driven, based upon the popular belief that the public health should be protected at a reasonable cost. It is based upon the concept that, when we derive benefit from Nature, we should not de stroy Nature in the process. Some say this effort should be tempered by ap plying “cost/benefit analysis” to these health issues. The response is that we already do. The marketplace performs a cost/benefit analysis when an indi vidual or company selects a specific pollution control technology to use. It can be further argued, “What is the dollar value of a human life?” Is it not priceless? The air pollution control industry reacts by agreeing that human life is indeed priceless, but one should not have to go bankrupt to protect it. Choosing the appropriate system and operating it properly goes a long way in this regard, and thousands of air pollution control systems in suc cessful operation around the world are testament to the fact that one can protect the public health without excessive cost. In addition, pollution con trol engineers work daily to reduce the operating cost of control equipment. New products continually arrive on the scene offering efficiency improve ments at reduced cost. Older, less efficient, more costly systems fade away. This second edition of Wet Scrubbers will help personnel who are in volved with air pollution control issues make important decisions regarding how pollution can be reduced in an economical manner and feel confident that they have made the proper decision. The contents of this book are in tended to supplement other information the readers may have about the problem and to reach an educated conclusion about the best course of ac tion. PREFACE TO THE FIRST EDITION The application of wet scrubbers to industrial sources is both an art and a science. The science is called “applications engineering.” The art is called “experience.” In this monograph, we provide information of sufficient detail to permit plant engineers and those interested in air pollution control to select and properly apply commercially available technology, combining art with sci ence. To make this task easier, we have endeavored to present basic back ground information, as well as specific examples, in a concise manner. Each application section is summarized by an Applications Guide. These guides contain general information regarding each specific application, in cluding expected pressure drops, types of equipment, possible trouble areas, items to avoid and design specifics. We do not pretend to present the only “right way”; there are various means to the same end when it comes to air pollution control. Our examples are based on successful installations, with information contributed as much by those people and firms who use the equipment as by those who designed the systems. The use of equipment exposes its advantages and pitfalls beyond the picture painted by the salesman, his brochures or the company he represents. Use alone shows whether the design is proper for the applica tion. Use reflects the true cost of an air pollution control system, not merely the initial cost. Proper use is the successful blending of application en gineering science and the art of experience. Kenneth C. Schifftner Howard E. Hesketh IX