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Thennal History of Sedimentary Basins Nancy D. Naeser Thane H. McCulloh Editors Thermal History of Sedimentary Basins Methods and Case Histories With 197 Illustrations Springer-Verlag New York Berlin Heidelberg London Paris Tokyo NANCY D. NAESER United States Geological Survey Denver Federal Center Denver, Colorado 80225, USA THANE H. MCCULLOH Mobil Exploration and Producing Services, Inc. Dallas, Texas 75265-0232, USA Library of Congress Cataloging-in-Publication Data Thermal history of sedimentary basins: methods and case histories / edited by Nancy D. Naeser and Thane H. McCulloh. p. cm. Papers from the Society of Economic Paleontologists and Mineralogists Research Symposium on "Thermal History of Sedimentary Basins Methods and Case Histories," held during the annual convention of the American Association of Petroleum Geologists in New Orleans, March 1985. Includes bibliographies and index. 1. Earth temperature-Congresses. 2. Sedimentation and deposition-Congresses. 3. Organic geochemistry-Congresses. I. Naeser, Nancy, Dearlen, 1944- . II. McCulloh, Thane Hubert, 1926- . III. Society of Economic Paleontologists and Mineralogists. IV. Research Symposium on "Thermal History of Sedimentary Basins Methods and Case Histories" (1985 : New Orleans, La.) QE509.T48 1988 551.1'2-dcI9 88-4024 Printed on acid-free paper. © 1989 by Springer-Verlag New York Inc. Copyright is not claimed for works prepared by US Government employees as part of their official duties. Softcover reprint of the hardcover 1s t edition 1989 All rights reserved. This work may not be translated or copied in whole or in part without the written permission of the publisher (Springer-Verlag, 175 Fifth Avenue, New York, New York 10010, USA), except for brief excerpts in connection with reviews or scholarly analysis. Use in connection with any form of information storage and retrieval, electronic adaptation, com puter software, or by similar or dissimilar methodology now known or hereafter developed is forbidden. The use of general descriptive names, trade names, trademarks, etc. in this publication, even if the former are not especially identified, is not to be taken as a sign that such names, as understood by the Trade Marks and Merchandise Marks Act, may accordingly be used freely by anyone. Typeset by Publishers Service, Bozeman, Montana. 9 8 7 6 5 432 1 ISBN-13: 978-1-4612-8124-5 e-ISBN-13: 978-1-4612-3492-0 DOl: 10.1007/978-1-4612-3492-0 Preface The collection of papers in this volume is a direct result of the Society of Economic Paleontologists and Mineralogists Research Symposium on "Thermal History of Sedimentary Basins: Methods and Case Histories" held as part of the American Association of Petroleum Geologists Annual Convention in New Orleans in March 1985. The original goal of the sym posium was to provide a forum where specialists from a variety of dis ciplines could present their views of methods that can be used to study the thermal history of a sedimentary basin or an important portion of a basin. An explicit part of that goal was to illustrate each method by presentation of a case history application. The original goal is addressed by the chapters in this volume, each of which emphasizes a somewhat different approach and gives field data in one way or another to illustrate the practical useful ness ofthe method. The significance of our relative ignorance of the thermal conductivities of sedimentary rocks, especially shales, in efforts to understand or model sedimentary basin thermal histories and maturation levels is a major thrust of the chapter by Blackwell and Steele. Creaney focuses on variations in kerogen composition in source rocks of different depositional environments and the degree to which these chem-. ically distinct kerogens respond differently to progressive burial heating. Molecular indicators of thermal maturity from kerogen and kerogen extract are the principal subject of the chapter by Curiale, Larter, Sweeney, and Bromley. They review this subject against a broad background of the more commonly measured bulk thermal maturity parameters such as Rock Eval pyrolysis data and vitrinite reflectance. In particular, they examine specific aromatization reactions relative to measured "maturity levels" with appropriate concerns about reaction kinetics and heating rates. Bulk organic matter maturities (mainly vitrinite reflectance) from many localities that are classified as burial diagenesis, geothermal system, or contact metamorphic environments are examined by Barker in terms of maximum temperature, exposure time, and reaction rates. He concludes that maximum temperature reached is the overwhelmingly dominant con trol and that reaction time spent at temperatures only slightly lower than the maximum can be neglected. Preface VI Empirical chemical thermometers based on the compositions of the dis solved substances in waters from oil wells, hot springs, and geothermal wells can be used to estimate the subsurface reservoir temperatures from the surface to depths corresponding to 350°C, according to Kharaka and Mariner. Estimates are within lOoC of measured values for reservoir tem peratures higher than about 70°C. A new Mg-Li geothermometer is presented and recommended for all subsurface water (except those from gas wells). Determination of paleotemperatures from measurements made on fluid inclusions in diagenetic minerals is the subject of an up-to-date review by Burruss, in which a pointed discussion is presented of the problems posed by reequilibration of early diagenetic fluid inclusions under deeper burial pressure-temperature conditions. Pytte and Reynolds assemble and discuss data from six selected sites where duration of time near peak temperature can be estimated for the smectite to illite transformation. An empirical kinetic reaction model is fit to the data and adequately describes the smectite to illite reaction extent for conditions that range from volcanic contact alteration to long-term burial diagenesis under low-temperature conditions. Temperature is the dominant control on reaction progress (provided the chemistry of the system permits reaction). The use of 4°Arj39Ar age spectrum analysis of detrital low-temperature potassium feldspar from buried clastic sequences as a means to trace the thermal evolution of a sedimentary basin is the subject of the chapter by Harrison and Burke. Data from the southernmost San Joaquin basin, California, the Albuquerque basin section of the Rio Grande Rift, New Mexico, and the southern Viking Graben of the North Sea basin are used to illustrate the technique. Naeser, Naeser, and McCulloh discuss fission-track dating of detrital apatite and zircon from clastic sequences as a method of defining the over all temperature-time history of a basin. In addition, localized temperature anomalies, the sediment provenance, and the sedimentation record of the basin 'can be analyzed. They illustrate the method with studies in the San Joaquin basin, California, and the Green River basin, Wyoming. Green, Duddy, Gleadow, and Lovering also discuss the application offis sion tracks to basin studies, but they emphasize the importance of using the shortening of fission tracks in apatite, and the resulting variation in mean track length and track length distribution, with progressive annealing as a paleotemperature indicator. They illustrate this with data from wells in the Otway basin, Australia. Feinstein, Kohn, and Eyal have combined vitrinite reflectance and fission-track data to reconstruct the thermal history recorded in folded rocks of a discontinuous succession of Early Permian to Tertiary age in southern Israel. According to the authors, following a brief intense Jurassic thermal episode, the coalification process "froze," despite progressive burial, reflecting a thermal decay since Early Cretaceous time. Armagnac, Bucci, Kendall, and Lerche present a method of using the variation in vitrinite reflectance with depth in a well to estimate the thick ness of sediment removed at unconformities. They illustrate use of the Preface VII method in wells in the National Petroleum Reserve of Alaska and in a well in the Rharb basin, Morocco. A one-dimensional finite-element modeling procedure is used by Issler and Beaumont to study the postrifting thermal and subsidence history of the Labrador continental margin, northeastern Canada. Model-derived temperatures are used to predict vitrinite reflectance and the progress of selected aromatization-isomerization biomarker compound reactions. Preliminary results from seven wells show overall good agreement with observations of maturity measures, crustal thickness (refraction), cor rected bottom-hole temperatures, and paleobathymetry and stratigraphy. McDonald, von Rosenberg, Jines, Burke, and Uhler use a two dirriensional, transient, finite-difference modeling procedure to derive the time-temperature history of sedimentary basins. The model simulates processes that occur during basin evolution, including subsidence, sedimentation, uplift and erosion, internal heat generation, surface tem perature variations, magmatic activity, faulting, and changes in sediment thermal conductivity with burial. Use of the model is illustrated for a hypothetical Late Cenozoic basin. A steady-state two-dimensional, finite-difference, numerical modeling procedure is used by Hagen and Surdam to examine the thermal evolution of the northern Bighorn basin, Wyoming and Montana. Integration of this thermal evolution model with time-temperature reconstructions derived from basin geology results in temperature histories for Cretaceous hydrocarbon source rocks. Heasler and Surdam use their previously proposed thermal model for coastal California as a basis for modeling hydrocarbon maturation in Mio cene Monterey Formation source rocks of the Pismo and Santa Maria basins. The authors use the model to predict the level of thermal exposure necessary to generate high API gravity crude oil in the rocks. We would like to thank all of the authors and the reviewers of the chap ters in this volume. Their conscientious work has made the volume possi ble. We thank Dale Issler and Christopher Beaumont for permission to use a modified version of one of their figures as the cover illustration. We would also like to thank Tom Kostick, U.S. Geological Survey, Denver, for preparing the cover illustration and for helping to modify a number of illus trations in the volume. Nancy Naeser wishes to thank Ian Mackenzie, New Zealand Department of Scientific and Industrial Research, for the early training in editing that made working on this volume so much easier. NANCY D. NAESER THANE H. MCCULLOH Contents Preface. . ... . .. .. . .. . .... . . .. . .. . ... . .. ... . . .... . . .. . . . . v Contributors ............................................ xi 1 Thermal History of Sedimentary Basins: Introduction and Overview. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 ThANE H. MCCULLOH and NANCY D. NAESER 2 Thermal Conductivity of Sedimentary Rocks: Measurement and Significance. . ... . . . . . . . . . . . . . . . . . . . . . . . 13 DAVID D. BLACKWELL and JOHN L. STEELE 3 Reaction of Organic Material to Progressive Geological Heating. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37 STEPHEN CREANEY 4 Molecular Thermal Maturity Indicators in Oil and Gas Source Rocks ............................ 53 JOSEPH A. CURIALE, STEPHEN R. LARTER, ROBERT E. SWEENEY, and BRUCE W. BROMLEY 5 Temperature and Time in the Thermal Maturation of Sedimentary Organic Matter .......................... 73 CHARLES E. BARKER 6 Chemical Geothermometers and Their Application to Formation Waters from Sedimentary Basins. . . . . . . . . . . . . . 99 YOUSIF K. KHARAKA and ROBERT H. MARINER 7 Paleotemperatures from Fluid Inclusions: Advances in Theory and Technique . . . . . . . . . . . . . . . . . . . . . .. 119 ROBERT C. BURRUSS 8 The Thermal Transformation of Smectite to Illite 133 A. M. PYTTE and R. C. REYNOLDS x Contents 9 4°Arj39Ar Thermochronology of Sedimentary Basins Using Detrital Feldspars: Examples from the San Joaquin Valley, California, Rio Grande Rift, New Mexico, and North Sea ........................... 141 T. MARK HARRISON and KEVIN BURKE 10 The Application of Fission-Track Dating to the Depositional and Thermal History of Rocks in Sedimentary Basins. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 157 NANCY D. NAESER, CHARLES W. NAESER, and THANE H. MCCULLOH 11 Apatite Fission-Track Analysis as a Paleotemperature Indicator for Hydrocarbon Exploration. . . . . . . . . . . . . . . . . .. 181 PAUL F. GREEN, IAN R. DUDDY, ANDREW IW. GLEADOW, and JOHN F. LOVERING 12 Significance of Combined Vitrinite Reflectance and Fission-Track Studies in Evaluating Thermal History of Sedimentary Basins: An Example from Southern Israel .......... . . . . . . . . . . . .. 197 SHIMON FEINSTEIN, BARRY P. KOHN, and MOSHE EYAL 13 Estimating the Thickness of Sediment Removed at an Unconformity Using Vitrinite Reflectance Data. . . . . . . . . . .. 217 CHARLENE ARMAGNAC, JAMES BUCCI, CHRISTOPHER G. ST. C. KENDALL, and IAN LERCHE 14 A Finite Element Model of the Subsidence and Thermal Evolution of Extensional Basins: Application to the Labrador Continental Margin 239 DALE R. ISSLER and CHRISTOPHER BEAUMONT 15 A Simulator for the Computation of Paleotemperatures During Basin Evolution. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 269 A. E. McDONALD, D. U. VON ROSENBERG, W. R. JINES, W. H. BURKE, JR., and L. M. UHLER, JR. 16 Thermal Evolution of Laramide-Style Basins: Constraints from the Northern Bighorn Basin, Wyoming and Montana. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 277 E. SVEN HAGEN and RONALD C. SURDAM 17 Thermal and Hydrocarbon Maturation Modeling of the Pismo and Santa Maria Basins, Coastal California . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 297 HENRY P. HEASLER and RONALD C. SURDAM Index. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 311 Contributors CHARLENE ARMAGNAC Department of Geology, University of South Carolina, Columbia, South Carolina 29208, USA CHARLES E. BARKER United States Geological Survey, Denver, Colorado 80225, USA CHRISTOPHER BEAUMONT Oceanography Department, Dalhousie University, Halifax, Nova Scotia B3H 411, Canada DAVID D. BLACKWELL Department of Geological Sciences, Southern Methodist University, Dallas, Texas 75275, USA BRUCE W. BROMLEY Unocal Science and Technology Division, Unocal Corporation, Brea, California 92621, USA JAMES BUCCI Department of Geology, University of South Carolina, Columbia, South Carolina 29208, USA KEVIN BURKE Department of Geosciences, University of Houston , Houston, Texas 77004, USA W. H. BURKE, JR. Mobil Research and Development Corporation, Dallas, Texas 75381, USA ROBERT C. BURRUSS United States Geological Survey, Denver, Colorado 80225, USA STEPHEN CREANEY Esso Resources (Canada) Ltd., Calgary, Alberta T2P OH6, Canada xii Contributors JOSEPH A. CURIALE Unocal Science and Technology Division, Unocal Corporation, Brea, California 92621, USA IAN R. DUDDY Geotrack International, Department of Geology, University of Melbourne, Parkville, Victoria 3052, Australia MOSHE EYAL Department of Geology and Mineralogy, Ben Gurion University of the Negev, Beer Sheva 84105, Israel SHIMON FEINSTEIN Department of Geology and Mineralogy, Ben Gurion University of the Negev, Beer Sheva 84105, Israel ANDREW J.W. GLEADOW Department of Geology, La Trobe University, Bundoora, Victoria 3083, Australia PAUL F. GREEN Geotrack International, Department of Geology, University of Melbourne, Parkville, Victoria 3052, Australia E. SVEN HAGEN Pecten International Company, Houston, Texas 77001, USA T. MARK HARRISON Department of Geological Sciences, State University of New York at Albany, Albany, New York 12222, USA HENRY P. HEASLER Department of Geology and Geophysics, University of Wyoming, Laramie, Wyoming 82071, USA DALE R. ISSLER Institute of Sedimentary and Petroleum Geology, Calgary, Alberta T2L 2A7, Canada W. R. JINES Mobil Research and Development Corporation, Dallas, Texas 75381, USA CHRISTOPHER G. ST. C. KENDALL Department of Geology, University of South Carolina, Columbia, South Carolina 29208, USA YOUSIF K. KHARAKA United States Geological Survey, Menlo Park, California 94025, USA

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