NIMS Monographs Yutaka Wakayama Katsuhiko Ariga Editors System-Materials Nanoarchitectonics NIMS Monographs SeriesEditor NaokiOHASHI,NationalInstituteforMaterialsScience,Tsukuba,Ibaraki,Japan EditorialBoard MikikoTANIFUJI,NationalInstituteforMaterialsScience,Tsukuba,Japan TakahitoOHMURA,NationalInstituteforMaterialsScience,Tsukuba,Ibaraki, Japan YoshitakaTATEYAMA,NationalInstituteforMaterialsScience,Tsukuba,Ibaraki, Japan TakashiTANIGUCHI,NationalInstituteforMaterialsScience,Tsukuba,Ibaraki, Japan KazuyaTERABE,NationalInstituteforMaterialsScience,Tsukuba,Ibaraki,Japan MasanobuNAITO,NationalInstituteforMaterialsScience,Tsukuba,Ibaraki, Japan NobutakaHANAGATA,NationalInstituteforMaterialsScience,Tsukuba,Ibaraki, Japan KenjiroMIYANO,NationalInstituteforMaterialsScience,Tsukuba,Ibaraki,Japan NIMSpublishesspecializedbooksinEnglishcoveringfromprinciple,theoryandall recentapplicationexamplesasNIMSMonographsseries.NIMSplacesaunityofone studythemeasaspecializedbookwhichwasspecializedineachparticularfield,and wetryforpublishingthemasaserieswiththecharacteristic(production,application) ofNIMS.AuthorsoftheseriesarelimitedtoNIMSresearchers.Ourworldismade upofvarious“substances”andinthese“materials”thebasisofoureverydaylives can be found. Materials fall into two major categories such as organic/polymeric materials and inorganic materials, the latter in turn being divided into metals and ceramics.FromtheStoneAges-bywayoftheIndustrialRevolution-uptotoday, theadvanceinmaterialshascontributedtothedevelopmentofhumankindandnow itisbeingfocuseduponasofferingasolutionforglobalproblems.NIMSspecializes incarryingoutresearchconcerningthesematerials.NIMS:http://www.nims.go.jp/ eng/index.html Moreinformationaboutthisseriesathttps://link.springer.com/bookseries/11599 · Yutaka Wakayama Katsuhiko Ariga Editors System-Materials Nanoarchitectonics Editors YutakaWakayama KatsuhikoAriga NationalInstituteforMaterialsScience NationalInstituteforMaterialsScience Tsukuba,Ibaraki,Japan Tsukuba,Ibaraki,Japan ISSN2197-8891 ISSN2197-9502 (electronic) NIMSMonographs ISBN978-4-431-56911-4 ISBN978-4-431-56912-1 (eBook) https://doi.org/10.1007/978-4-431-56912-1 ©NationalInstituteforMaterialsScience,Japan2022 Thisworkissubjecttocopyright.AllrightsarereservedbytheNationalInstituteforMaterialsScience, Japan(NIMS),whetherthewholeorpartofthematerialisconcerned,specificallytherightsoftranslation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilms or in any other physical way, and transmission or information storage and retrieval, electronic adaptation, computer software,orbysimilarordissimilarmethodologynowknownorhereafterdeveloped.Exemptedfromthis legalreservationarebriefexcerptsinconnectionwithreviewsorscholarlyanalysisormaterialsupplied specificallyforthepurposeofbeingenteredandexecutedonacomputersystem,forexclusiveuseby thepurchaserofthework.Duplicationofthispublicationorpartsthereofispermittedonlyunderthe provisionsofapplicablecopyrightlawsandapplicabletreaties,andpermissionforusemustalwaysbe obtainedfromNIMS.Violationsareliabletoprosecutionundertherespectivecopyrightlawsandtreaties. Theuseofgeneraldescriptivenames,registerednames,trademarks,servicemarks,etc.inthispublication doesnotimply,evenintheabsenceofaspecificstatement,thatsuchnamesareexemptfromtherelevant protectivelawsandregulationsandthereforefreeforgeneraluse. Whiletheadviceandinformationinthisbookarebelievedtobetrueandaccurateatthedateofpublication, neithertheauthorsnortheeditorsnorthepublishercanacceptanylegalresponsibilityforanyerrorsor omissionsthatmaybemade.NIMSandthepublishermakenowarranty,expressorimplied,withrespect tothematerialcontainedherein. ThisSpringerimprintispublishedbytheregisteredcompanySpringerJapanKKpartofSpringerNature. Theregisteredcompanyaddressis:ShiroyamaTrustTower,4-3-1Toranomon,Minato-ku,Tokyo105- 6005,Japan Preface Nanoarchitectonics is a new term for a new concept beyond nanotechnology. In nanoarchitectonics,nanoscalematerialsareassembledinsystematicwaystogenerate newfunctionalities,whichcannotbeattainedsolelybyeachmaterial.Thematerials are well designed and synthesized. However, synergetic effects are key factors for deviceperformanceratherthanthepropertiesofindividualmaterials.Thatis,each materialworksasabuildingblockasamemberofananoscalearchitecture.Werefer tosuchresearchconceptas“nanoarchitectonics.” Toexplorethisnewresearchfield,theInternationalCenterforMaterialsNanoar- chitectonics (WPI-MANA) was founded in 2007 as one of the first five research centers within the framework of the World Premier International Research Center Initiative (WPI), which is sponsored by Japan’s Ministry of Education, Culture, Sports,ScienceandTechnology.Inthisproject,wehaveproducednanoscalecompo- nentsandintegratedthemintovariousdimensionalsystemsthatexhibitcutting-edge functions.Here,weexpectthattheseeffortswillleadtoscientificbreakthroughsand technologicalinnovations. Inthisbook,wepresentthestate-of-the-artachievements ofthematerialarchi- tects in MANA, including supramolecules, one- or two-dimensionally controlled semiconductors, optically and catalytically active nanomaterials, atomic switches, and molecular assemblies for electronic applications. We hope that this book will arouseafeelingofcuriosityandprovideanexcellentspringboardforyoungmaterials scientistsinparticular. Tsukuba,Japan YutakaWakayama v Contents WhatisNanoarchitectonics? WhatisNanoarchitectonics? ....................................... 3 KatsuhikoArigaandMasakazuAono NanostructuredMaterialsandTheirConstruction SynthesisofSemiconductorNanowires .............................. 9 KenC.PradelandNaokiFukata NanoparticleBiomarkersAdaptedforNear-InfraredFluorescence Imaging .......................................................... 27 NaotoShirahata FrontiersinMesoscaleMaterialsDesign ............................. 51 YusukeIde,JoelHenzie,KenyaKani,andYusukeYamauchi Wavelength-SelectivePhotothermalInfraredSensors ................. 71 TadaakiNagao, DaoDuyThang, DoanTungAnh, SatoshiIshii, andToshihideNabatame FunctionalMolecularLiquids ...................................... 93 EdwardA.NealandTakashiNakanishi DevicesandComputationbyNanoarchitectonics Ionic Nanoarchitectonics: Creation of Polymer-Based Atomic SwitchandDecision-MakingDevice ................................. 113 KazuyaTerabe,TohruTsuruoka,andTakashiTsuchiya Oxoporphyrinogens: Novel Dyes Based on the Fusion ofCalix[4]pyrrole,QuinonoidsandPorphyrins ....................... 127 JonathanP.HillandJanLabuta vii viii Contents GrowthandElectronicandOptoelectronicApplicationsofSurface OxidesonAtomicallyThinWSe ................................... 149 2 MahitoYamamotoandKazuhitoTsukagoshi Portable Toxic Gas Sensors Based on Functionalized Carbon Nanotubes ........................................................ 161 ShinsukeIshihara AdvancedNanomechanicalSensorforArtificialOlfactorySystem: Membrane-TypeSurfaceStressSensor(MSS) ........................ 169 HuynhThienNgo,KosukeMinami,KotaShiba,andGenkiYoshikawa QuantumMolecularDevicesTowardLarge-ScaleIntegration ......... 181 RyomaHayakawa,ToyohiroChikyow,andYutakaWakayama EnergyandLifewithNanoarchiteconics Nanostructured Bulk Thermoelectric Materials for Energy Harvesting ........................................................ 199 ZihangLiuandTakaoMori Artificial Photosynthesis: Fundamentals, Challenges, andStrategies ..................................................... 233 DavinPhilo, HamzaEl-Hosainy, ShunqinLuo, HaoHuang, FumihikoIchihara,andJinhuaYe SmartPolymersforBiomedicalApplications ......................... 265 MitsuhiroEbara GeometricalandMechanicalNanoarchitectonicsatInterfaces BridgingMoleculeswithCellPhenotypes ............................ 275 JunNakanishiandShotaYamamoto EmergingMethods Electrical Measurement by Multiple-Probe Scanning Probe Microscope ....................................................... 289 YoshitakaShingayaandTomonobuNakayama Large-Scale First-Principles Calculation Technique for Nanoarchitectonics: Local Orbital and Linear-Scaling DFTMethodswiththeCONQUESTCode ........................... 303 TsuyoshiMiyazaki,AyakoNakata,andDavidR.Bowler MachineLearningApproachesinNanoarchitectonics ................. 319 RyoTamuraandGakuImamura Epilogue:Today’sNanotechnology,FutureNanoarchitectonics ........ 337 What is Nanoarchitectonics? What is Nanoarchitectonics? KatsuhikoArigaandMasakazuAono 1 InitiationofNanoarchitectonics Thesedays,scientistsandengineersarerequestedtosolvemanyproblemsincluding howtosaveresources,howtocreateenergy,howtoreduceemissions,howtoreduce environmentalimpact,andhowtoefficientlyhandleinformation.Alltheseproblems canbesolvedwithonecommonconcept,controlofNANOandtherelatedfunctional structures. Developing functional materials and systems rationally fabricated with nanoscalestructuralprecisioncansaveresources,createenergy,reduceemissions, reduceenvironmentalimpact,andefficientlyhandleinformation.Inthecomingdays, human society will be supported by science and technology capable of regulating nanoscalestructures.Thecorrespondingmethodologystartedasnanotechnologyand hasnowevolvedtonanoarchitectonics. ItissaidthatthetermnanotechnologywasinitiallyproposedbyRichardFeynman, whoforesawhugepossibilitiesforscienceandtechnologyinnanoscalespaces[1]. Thesocialimpactsofnanotechnologywereagainbroughtupinthe2001declaration, the National Nanotechnology Initiative, made by the US president Bill Clinton, in ordertopromotethenanotechnologicalapproachinindustrialdevelopments.Such social and political flows have, of course, been supported by various innovations in instrumental developments for nanoscale observation, such as the invention of thescanningtunnelingmicroscope(STM)andotherscanningprobemicroscopes,as wellasrapiddevelopmentsinmicro-andnanofabrication.Scientistsarenowcapable ofdirectlywatchingandhandlingnanoscaleobjects. B K.Ariga( )·M.Aono InternationalCenterforMaterialsNanoarchitectonics(WPI-MANA),NationalInstitutefor MaterialsScience(NIMS),1–1Namiki,Tsukuba305-0044,Ibaraki,Japan e-mail:[email protected] K.Ariga GraduateSchoolofFrontierSciences,TheUniversityofTokyo,5-1-5Kashiwanoha,Kashiwa 277-8561,Chiba,Japan ©NationalInstituteforMaterialsScience,Japan2022 3 Y.WakayamaandK.Ariga(eds.),System-MaterialsNanoarchitectonics, NIMSMonographs,https://doi.org/10.1007/978-4-431-56912-1_1