Challa S. S. R. Kumar Editor Surface Science Tools for Nanomaterials Characterization Surface Science Tools for Nanomaterials Characterization Challa S. S. R. Kumar Editor Surface Science Tools for Nanomaterials Characterization With293Figuresand10Tables Editor ChallaS.S.R.Kumar CenterforAdvancedMicrostructuresandDevices BatonRouge,LA,USA ISBN978-3-662-44550-1 ISBN978-3-662-44551-8(eBook) DOI10.1007/978-3-662-44551-8 SpringerHeidelbergNewYorkDordrechtLondon LibraryofCongressControlNumber:2015930198 #Springer-VerlagBerlinHeidelberg2015 Thisworkissubjecttocopyright.AllrightsarereservedbythePublisher,whetherthewholeorpartof the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation,broadcasting,reproductiononmicrofilmsorinanyotherphysicalway,andtransmissionor informationstorageandretrieval,electronicadaptation,computersoftware,orbysimilarordissimilar methodologynowknownorhereafterdeveloped.Exemptedfromthislegalreservationarebriefexcerpts inconnectionwithreviewsorscholarlyanalysisormaterialsuppliedspecificallyforthepurposeofbeing enteredandexecutedonacomputersystem,forexclusiveusebythepurchaserofthework.Duplication ofthispublicationorpartsthereofispermittedonlyundertheprovisionsoftheCopyrightLawofthe Publisher’s location, in its current version, and permission for use must always be obtained from Springer.PermissionsforusemaybeobtainedthroughRightsLinkattheCopyrightClearanceCenter. 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Printedonacid-freepaper SpringerispartofSpringerScience+BusinessMedia(www.springer.com) Contents 1 ScanningElectrochemicalPotentialMicroscopy(SECPM)and ElectrochemicalSTM(EC-STM) .......................... 1 MaxHerpich,JochenFriedl,andUlrichStimming 2 RecoveringTime-ResolvedImagingForcesinSolutionby ScanningProbeAccelerationMicroscopy: TheoryandApplication ................................. 69 MaxmoreChaibva,NicoleShamitko-Klingensmith,and JustinLegleiter 3 ScanningProbeMicroscopyforNanolithography ............. 91 C.B.Samantaray 4 KelvinProbeForceMicroscopyinNanoscienceand Nanotechnology ........................................ 117 DaLuo,HaoSun,andYanLi 5 FieldIonMicroscopyfortheCharacterizationof ScanningProbes ....................................... 159 WilliamPaulandPeterGr€utter 6 ScanningConductiveTorsionModeMicroscopy ............. 199 LingSunandElmarBonaccurso 7 FieldIonandFieldDesorptionMicroscopy:Principlesand Applications .......................................... 227 YuriSuchorski 8 NoncontactAtomicForceMicroscopyforAtomic-Scale CharacterizationofMaterialSurfaces ...................... 273 MehmetZ.Baykara 9 ApplicationsofSynchrotron-BasedX-RayPhotoelectron SpectroscopyintheCharacterizationofNanomaterials ........ 317 W.H.Doh,V.Papaefthimiou,andS.Zafeiratos v vi Contents 10 ExplorationintotheValenceBandStructuresofOrganic SemiconductorsbyAngle-ResolvedPhotoelectron Spectroscopy .......................................... 367 YasuoNakayamaandHisaoIshii 11 BandBendingatMetal-SemiconductorInterfaces,Ferroelectric SurfacesandMetal-FerroelectricInterfacesInvestigatedby PhotoelectronSpectroscopy .............................. 405 NicoletaGeorgianaApostolandCristian-MihailTeodorescu 12 HigherResolutionScanningProbeMethodsfor MagneticImaging ...................................... 463 S.N.PiramanayagamandBinniVarghese 13 ImagingandCharacterizationofMagneticMicro-and NanostructuresUsingForceMicroscopy .................... 489 StephanBlock 14 CombiningMicromanipulation,KerrMagnetometryand MagneticForceMicroscopyforCharacterizationof Three-DimensionalMagneticNanostructures ................ 531 AmalioFernández-Pacheco,RussellP.Cowburn, LuisE.Serrano-Ramo´n,M.RicardoIbarra,andJose´ M.DeTeresa 15 HighResolutionSTMImaging ............................ 561 AlexanderN.Chaika 16 NumericalandFiniteElementSimulationsofNanotipsfor FIM/FEM ............................................ 621 Moh’dRezeq,AhmedE.Ali,andDirarHomouz Index ................................................ 645 Contributors Ahmed E. Ali Department of Electrical and Computer Engineering, KhalifaUniversityofScience,TechnologyandResearch(KUSTAR),AbuDhabi, UAE Nicoleta Georgiana Apostol National Institute of Materials Physics, Magurele-Ilfov,Romania Mehmet Z. Baykara Department of Mechanical Engineering and UNAM (cid:1) Institute of Materials Science and Nanotechnology, Bilkent University, Ankara, Turkey Stephan Block Department of Physics, Ernst–Moritz–Arndt University of Greifswald,Greifswald,Germany AppliedPhysics,ChalmersUniversityofTechnology,Gothenburg,Sweden Elmar Bonaccurso Center of Smart Interfaces, Technische Universit€at Darmstadt,Darmstadt,Germany AirbusGroupInnovations,MetallicTechnologiesandSurfaceEngineering–TX2, Munich,Germany MaxmoreChaibva TheC.EugeneBennettDepartmentofChemistry,WestVirginia University,Morgantown,WV,USA WVNanoSAFE,WestVirginiaUniversity,Morgantown,WV,USA Alexander N. Chaika Institute of Solid State Physics, Russian Academy of Sciences,Chernogolovka,MoscowDistrict,Russia Centre for Research on Adaptive Nanostructures and Nanodevices (CRANN), SchoolofPhysics,TrinityCollegeDublin,Dublin,Ireland Russell P. Cowburn Cavendish Laboratory, University of Cambridge, Cambridge,UK vii viii Contributors Jose´ M. De Teresa Instituto de Ciencia de Materiales de Arago´n (ICMA), Departamento de F´ısica de la Materia Condensada, Universidad de Zaragoza– CSIC,Zaragoza,Spain Laboratorio de Microscopias Avanzadas (LMA), Instituto de Nanociencia de Arago´n(INA),UniversidaddeZaragoza,Zaragoza,Spain W. H. Doh Institut de chimie et proce´de´s pour l’e´nergie, l’environnement et la sante´ (ICPEES), UMR 7515 du CNRS-Universite´ de Strasbourg, ECPM, Strasbourg,France Amalio Fernández-Pacheco Cavendish Laboratory, University of Cambridge, Cambridge,UK Jochen Friedl TUM CREATE, 1 CREATE Way, CREATE Tower, Singapore, Singapore DepartmentofPhysicsE19,TechnischeUniversit€atM€unchen,Garching,Germany PeterGru€tter PhysicsDepartment,McGillUniversity,Montre´al,QC,Canada Max Herpich TUM CREATE, 1 CREATE Way, CREATE Tower, Singapore, Singapore DepartmentofPhysicsE19,TechnischeUniversit€atM€unchen,Garching,Germany Dirar Homouz Department of Applied Mathematics and Sciences, Khalifa UniversityofScience,TechnologyandResearch(KUSTAR),AbuDhabi,UAE M. Ricardo Ibarra Departamento de F´ısica de la Materia Condensada, UniversidaddeZaragoza,Zaragoza,Spain Laboratorio de Microscopias Avanzadas (LMA), Instituto de Nanociencia de Arago´n(INA),UniversidaddeZaragoza,Zaragoza,Spain HisaoIshii GraduateSchoolofAdvancedIntegrationScience,ChibaUniversity, Chiba,Japan CenterforFrontierScience,ChibaUniversity,Chiba,Japan JustinLegleiter TheC.EugeneBennettDepartmentofChemistry,WestVirginia University,Morgantown,WV,USA WVNanoSAFE,WestVirginiaUniversity,Morgantown,WV,USA TheCenterforNeurosciences,WestVirginiaUniversity,Morgantown,WV,USA Yan Li Beijing National Laboratoryfor Molecular Sciences, Key Laboratory for the Physics and Chemistry of Nanodevices, College of Chemistry and Molecular Engineering,PekingUniversity,Beijing,China Contributors ix DaLuo BeijingNationalLaboratoryforMolecularSciences,KeyLaboratoryfor the Physics and Chemistry of Nanodevices, College of Chemistry and Molecular Engineering,PekingUniversity,Beijing,China Yasuo Nakayama Graduate School of Advanced Integration Science, Chiba University,Chiba,Japan V.Papaefthimiou Institutdechimieetproce´de´spourl’e´nergie,l’environnement et la sante´ (ICPEES), UMR 7515 du CNRS-Universite´ de Strasbourg, ECPM, Strasbourg,France William Paul IBM Research Division, Almaden Research Center, San Jose, CA,USA S. N. Piramanayagam Data Storage Institute, A*STAR (Agency for Science, TechnologyandResearch),Singapore,Singapore Moh’dRezeq DepartmentofAppliedMathematicsandSciencesandDepartment of Electrical and Computer Engineering, Khalifa University of Science, Technol- ogyandResearch(KUSTAR),AbuDhabi,UAE C.B.Samantaray CollegeofEngineering&Technology,VirginiaStateUniver- sity,Petersburg,VA,USA Luis E. Serrano-Ramo´n Instituto de Ciencia de Materiales de Arago´n (ICMA), DepartamentodeF´ısicadelaMateriaCondensada,UniversidaddeZaragoza-CSIC, Zaragoza,Spain NicoleShamitko-Klingensmith TheC.EugeneBennettDepartmentofChemistry, WestVirginiaUniversity,Morgantown,WV,USA WVNanoSAFE,WestVirginiaUniversity,Morgantown,WV,USA Ulrich Stimming School of Chemistry, Bedson Building, Newcastle University, NewcastleuponTyne,UK FakultaetfuerInformatik,TechnischeUniversit€atM€unchen,Garching,Germany YuriSuchorski InstituteofMaterialsChemistry,ViennaUniversityofTechnology, Vienna,Austria Hao Sun Nano Surfaces Division, Bruker (Beijing) Scientific Technology Co., Ltd,Beijing,China Ling Sun Department of Micro- and Nanotechnology, Technical University of Denmark,Kgs.Lyngby,Denmark Cristian-Mihail Teodorescu National Institute of Materials Physics, Magurele-Ilfov,Romania