Still Only One Earth Progressinthe40YearsSincetheFirstUNConferenceontheEnvironment ISSUES IN ENVIRONMENTAL SCIENCE AND TECHNOLOGY SERIESEDITORS: ProfessorR.E.Hester,UniversityofYork,UK ProfessorR.M.Harrison,UniversityofBirmingham,UK EDITORIALADVISORYBOARD: Professor P. Crutzen, Max-Planck-Institut fu¨r Chemie, Germany, Professor S. J. de Mora, Ply- mouth Marine Laboratory, UK, Dr G. Eduljee, SITA, UK, Professor L. Heathwaite, Lancaster University, UK, Professor S. Holgate, University of Southampton, UK, Professor P. K. Hopke, ClarksonUniversity,USA,SirJohnHoughton,MeteorologicalOffice,UK,ProfessorP.Leinster, Environment Agency, UK, Professor J. Lester, Imperial College of Science, Technology and Medicine,UK,ProfessorP.S.Liss,SchoolofEnvironmentalSciences,UniversityofEastAnglia, UK, Professor D. Mackay, Trent University, Canada, Professor A. Proctor, Food Science De- partment,UniversityofArkansas,USA,DrD.Taylor,AstraZenecaplc,UK. TITLESINTHESERIES: 1:MininganditsEnvironmentalImpact 20:TransportandtheEnvironment 2:WasteIncinerationandtheEnvironment 21:SustainabilityinAgriculture 3:WasteTreatmentandDisposal 22:ChemicalsintheEnvironment:Assessing 4:VolatileOrganicCompoundsinthe andManagingRisk Atmosphere 23:AlternativestoAnimalTesting 5:AgriculturalChemicalsandthe 24:Nanotechnology Environment 25:BiodiversityUnderThreat 6:ChlorinatedOrganicMicropollutants 26:EnvironmentalForensics 7:ContaminatedLandanditsReclamation 27:ElectronicWasteManagement 8:AirQualityManagement 28:AirQualityinUrbanEnvironments 9:RiskAssessmentandRiskManagement 29:CarbonCapture 10:AirPollutionandHealth 30:EcosystemServices 11:EnvironmentalImpactofPowerGeneration 31:SustainableWater 12:EndocrineDisruptingChemicals 32:NuclearPowerandtheEnvironment 13:ChemistryintheMarineEnvironment 33:MarinePollutionandHumanHealth 14:CausesandEnvironmentalImplications 34:EnvironmentalImpactsofModern ofIncreasedUV-BRadiation Agriculture 15:FoodSafetyandFoodQuality 35:SoilsandFoodSecurity 16:AssessmentandReclamationof 36:ChemicalAlternativesAssessments ContaminatedLand 37:WasteasaResource 17:GlobalEnvironmentalChange 38:GeoengineeringoftheClimateSystem 18:EnvironmentalandHealthImpactof 39:Fracking SolidWasteManagementActivities 40:StillOnlyOneEarth:Progressinthe 19:SustainabilityandEnvironmentalImpact 40YearsSincetheFirstUNConference ofRenewableEnergySources ontheEnvironment Howtoobtainfuturetitlesonpublication: Asubscriptionisavailableforthisseries.Thiswillbringdeliveryofeachnewvolumeimme- diatelyonpublicationandalsoprovideyouwithonlineaccesstoeachtitleviatheInternet.For furtherinformationvisithttp://www.rsc.org/issuesorwritetotheaddressbelow. Forfurtherinformationpleasecontact: Sales and Customer Care, Royal Societyof Chemistry, Thomas GrahamHouse, Science Park, MiltonRoad,Cambridge,CB40WF,UK Telephone: þ44(0)1223432360,Fax: þ44(0)1223426017,Email:[email protected] Visitourwebsiteatwww.rsc.org/books ISSUES IN ENVIRONMENTAL SCIENCE AND TECHNOLOGY EDITORS:R.E.HESTERANDR.M.HARRISON 40 Still Only One Earth Progress in the 40 Years Since the First UN Conference on the Environment IssuesinEnvironmentalScienceandTechnologyNo.40 PrintISBN:978-1-78262-076-1 PDFeISBN:978-1-78262-217-8 ISSN1350-7583 AcataloguerecordforthisbookisavailablefromtheBritishLibrary rTheRoyalSocietyofChemistry2015 Allrightsreserved Apartfromfairdealingforthepurposesofresearchfornon-commercialpurposesorfor privatestudy,criticismorreview,aspermittedundertheCopyright,DesignsandPatents Act1988andtheCopyrightandRelatedRightsRegulations2003,thispublicationmaynot bereproduced,storedortransmitted,inanyformorbyanymeans,withouttheprior permissioninwritingofTheRoyalSocietyofChemistryorthecopyrightowner,orinthe caseofreproductioninaccordancewiththetermsoflicencesissuedbytheCopyright LicensingAgencyintheUK,orinaccordancewiththetermsofthelicencesissuedbythe appropriateReproductionRightsOrganizationoutsidetheUK.Enquiriesconcerning reproductionoutsidethetermsstatedhereshouldbesenttoTheRoyalSocietyof Chemistryattheaddressprintedonthispage. TheRSCisnotresponsibleforindividualopinionsexpressedinthiswork. Theauthorshavesoughttolocateownersofallreproducedmaterialnotintheirown possessionandtrustthatnocopyrightshavebeeninadvertentlyinfringed. PublishedbyTheRoyalSocietyofChemistry, ThomasGrahamHouse,SciencePark,MiltonRoad, CambridgeCB40WF,UK RegisteredCharityNumber207890 Forfurtherinformationseeourwebsiteatwww.rsc.org Preface ThefirstUnitedNationsConferenceontheHumanEnvironmenttookplace inStockholmfrom5–16June1972.Itreceivedhugeattentioninternationally and produced a final declaration which ‘‘having considered the need for a common outlook and for common principles to inspire and guide the peo- ples of the world in the preservation and enhancement of the human environment’’ proclaimed 26 principles. These were carefully considered high-level objectives which have undoubtedly influenced policy on the en- vironmentinternationally,but–insomeaspectsandbysomeUNmembers – have been substantially ignored. Noting that this is the 40th volume of IssuesinEnvironmentalScienceandTechnology,weconsidereditappropriate to look back over the past 40 years to evaluate progress in environmental management in the context of the bold vision set out by the proclamation from the 1972 conference. In more recent years, high-level United Nations activity on the environ- ment has focussed very much on theatmosphere. Topics affecting the glo- balatmosphere, and therefore requiring major international agreements, have been depletion of stratospheric ozone (the ozone hole) and global warming.Inthefirstchapter,MartynChipperfieldoftheUniversityofLeeds outlinesprogressinrelationtotheformertopic,explainingtheevidencefor depletion of ozone in the Antarctic and at other latitudes, reviewing the international actions on regulation and control, and considering the future outlookforstratosphericozone.Regardinggreenhousegases,JohnSottong, Mark Broomfield, Joanna MacCarthy, Anne Misra, Glen Thistlethwaite and John Watterson of Ricardo-AEA in the second chapter providea perspective on climate change, emissions andatmospheric concentrations of major greenhouse gases, and the related international policy actions and chal- lenges. These two chapters provide a distinct contrast in that on the one hand the Montreal Protocol and subsequent international agreements have led to major action which is already showing benefits for the stratosphere, while on the other hand progress has been much slower in relation to the IssuesinEnvironmentalScienceandTechnologyNo.40 StillOnlyOneEarth:Progressinthe40YearsSincetheFirstUNConferenceontheEnvironment EditedbyR.E.HesterandR.M.Harrison rTheRoyalSocietyofChemistry2015 PublishedbytheRoyalSocietyofChemistry,www.rsc.org v vi Preface mitigation of global warming through reductions in greenhouse gas emissions. Local air quality has been a major issue throughout the past 40 years. In developedcountries,hugeprogresshadbeenmadeinimprovingairquality prior to 1972 but subsequent improvements in epidemiological methods showed clearly that there were still major adverse effects on human health. In the third chapter, on Trends in Local Air Quality, Roy Harrison, Francis PopeandZongboShioftheUniversityofBirminghamreviewprogresssince 1970, both in developed countries and in less-developed parts of the world, suchasIndiaandChina,whereairqualityremainsverypoorandimpactson humanhealtharesubstantial.Oneoftheverycontroversialpollutionissues in 1972 was that of the use of lead as a motor fuel additive which led to substantiallocalairpollutionissues,whichhavenowbeenresolvedinmost parts of the world through the cessation of use of lead additives. In the fourthchapter,RobertMasonoftheUniversityofConnecticutexaminesthe environmental presence and behaviour of two toxic metals: lead and mer- cury. Mercury was a major source of concern as early as the 1950s through contaminationofthemarineenvironmentandthetoxicityofcontaminated fish.Mercurypollutionremainsaconcern,althoughnowmoreinrelationto emissions to theatmosphere from sources such as coal combustion. The chapter makes it clear how regulation has tightened substantially over the period considered. Some of the most recognised environmental problems at the time of the 1972 Stockholm Conference related to the presence of persistent organic pollutants, such as the organochlorine pesticides, as residues in the en- vironment. The phenomenon of eggshell thinning and chick mortality in raptors and oceanic birds was brought to public attention by Rachel Carson’s classic book Silent Spring published in 1962. In the fifth chapter, MohamedAbdallahoftheUniversitiesofBirminghamandAssiutdescribes the most important persistent organic pollutants, their behaviour in the environment,temporaltrendsandfuturescenarios.Thisisclearlyanareain which international action has been quite effective, but because of the very long environmental lifetimes of the compounds, many problems still re- main. In the sixth chapter, Shane Snyder and Tarun Anumol of the Uni- versity of Arizona consider emerging chemical contaminants. This classificationincludesbothnewindustrialchemicalsandsubstanceswhich have been in use for many years but for which problems have only recently been recognised. The chapter considers, in particular, pharmaceutical and personal care products, perfluorinated compounds and endocrine dis- rupting chemicals. The importance of ever-improving analytical techniques is highlighted and consideration given to the implications for water sustainability. One of the other major changes over the past 40 years has related to the managementofsolidwaste.Fromasituationinwhichsolidwastewasseen asmaterialtodisposeof(andforget), the emphasis hasnow changedto re- use, recycling and waste-derived products. In the seventh chapter, Ian Preface vii Williams of the University of Southampton explains the trends in waste managementandexaminessomeofthecurrentpracticesdesignedtomake optimaluseofmaterialspreviouslyconsideredsimplyaswastefordisposal. InthefinalchapterbyDavidTaylorofWCA,progressinthemanagementof effluent discharges to the aquatic environment is considered. In the 1970s, the quantities of effluents discharged to water courses frequently far ex- ceeded the natural purification capacity of the waters; this chapter explores someoftheassociatedproblemsandthesolutionsthathavebeenarrivedat through improved effluent management. In its totality, this volume tracks much of the progress in management and enhancement of the human environment over the past 40 years. It is a verymixedstory,withmanysuccessesbutalsosomenotablefailures.There areundoubtedlylessonsforthefuture.Wearegratefultoourdistinguished group of authors for their contributions and commend the volume to both studentsandpractitionersinenvironmentalscience,engineeringandpolicy as a valuable record of the progress made in many of the most important areas of environmental pollution, and as a key reference on environmental management. Ronald E. Hester Roy M. Harrison Contents Editors xv List of Contributors xvii Global Atmosphere – The Antarctic Ozone Hole 1 Martyn P. Chipperfield 1 Introduction 1 2 Observations of Antarctic Ozone 3 3 Causes of Antarctic Ozone Depletion 5 3.1 Dynamical Preconditioning 7 3.2 Polar Stratospheric Clouds 8 3.3 Catalytic Ozone Loss Cycles 10 3.4 Modelling of Polar Ozone Depletion 13 4 Ozone Depletion at Other Latitudes 16 4.1 Arctic 16 4.2 Mid-latitudes 16 4.3 Tropics 16 5 Regulation and Control: The Montreal Protocol 17 5.1 Chlorine and Bromine Source Gases 17 5.2 The Montreal Protocol 19 5.3 Reasons for Success of the Montreal Protocol 23 5.4 Climate Benefit of the Montreal Protocol 23 6 Outlook 24 6.1 Very Short-lived Species 24 6.2 Recovery of the Ozone Layer 25 6.3 Impact of Ozone Depletion on Surface Climate 28 7 Summary 30 References 30 IssuesinEnvironmentalScienceandTechnologyNo.40 StillOnlyOneEarth:Progressinthe40YearsSincetheFirstUNConferenceontheEnvironment EditedbyR.E.HesterandR.M.Harrison rTheRoyalSocietyofChemistry2015 PublishedbytheRoyalSocietyofChemistry,www.rsc.org ix x Contents Global Atmosphere – Greenhouse Gases 34 John Sottong, Mark Broomfield, Joanna MacCarthy, Anne Misra, Glen Thistlethwaite and John Watterson 1 The Greenhouse Effect 35 1.1 What is the Greenhouse Effect? 35 1.2 Radiative Forcing 35 1.3 Uncertainty 36 1.4 Greenhouse Gas Emissions 37 1.5 Atmospheric CO Concentrations 37 2 1.6 The Consequences of Climate Forcing 38 2 The International Response to Climate Change 40 2.1 TheUnitedNationsFrameworkConventiononClimateChange 40 2.2 Industrialised and Developing Countries 41 2.3 The Kyoto Protocol 41 2.4 Post-Kyoto Protocol 42 2.5 Unilateral and Bilateral Initiatives 42 2.6 Mobilizing Climate Finance 44 3 GHG Emissions Data: Measurement, Reporting and Verification 45 3.1 Role of Emissions Inventories 45 3.2 Policy and Inventories 46 3.3 Sub-national and City Inventories 46 3.4 Inventory Verification 47 4 Science and Policy Challenges 47 4.1 Benchmarks 47 4.2 Growth 48 4.3 Short-lived Climate Forcing Agents 48 4.4 Credibility 49 4.5 Political Economy 49 4.6 Outsourcing Emissions 49 5 The Energy Sector and Technology 49 5.1 Technology Types 50 5.2 Market Potential and Challenges 50 6 What does the Future Hold? 51 6.1 GHG Emissions 51 6.2 The Global Environment 51 6.3 Overcoming the Barriers to Effective Action 52 References 54 Trends in Local Air Quality 1970–2014 58 Roy M. Harrison, Francis D. Pope and Zongbo Shi 1 Introduction 58