Silanes and Other Coupling Agents, Volume 3

265 Pages·2004·4.31 MB·English

by  K L Mittal

Silanes and Other Coupling Agents, Volume 3
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Silanes and
Other
CouplingAgents
VOLUME 3
Editor: K.L. Mittal
///VSP///
UTRECHT • BOSTON
2004
CRC Press
Taylor & Francis Group
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Version Date: 20120727
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CONTENTS
Preface vii
Part 1: Silane Coupling Agents
Sterically hindered silanes for waterborne systems: A model study
of silane hydrolysis
E. R. Pohl and A. Chaves 3
Silane oligomers: A class of their own
H.Mack 11
FTIR and XPS surface characterization of allyltrimethoxysilane and
3-methacryloxypropyltrimethoxysilane mixture adsorbed onto titanium
substrate
/. R Matinlinna, K. Laajalehto, L. V 7. Lassila, A. Yli-Urpo and R K. Vallittu 21
Effect of bridging group on the structure of bis-silane water-barrier films
G. Pan, H. Kim, M. S. Kent, J. Majewski and D. W. Schaefer 39
Amino- and bis-silane pre-treatments for adhesive bonding of aluminum
B. G Tilset, R Lapique, A, Bj0rgum and C. 7. Simensen 51
y-APS as a durability enhancer of elastomer-to-metal adhesive bonds
R, R Hamade 69
Silane coupling agents for silica-filled tire-tread compounds:
The link between chemistry and performance
W. K. Dierkes, L. A. E, M. Reuvekamp, A. J. W. ten Brinke
and 7. W. M. Noordermeer 89
Electrodeposition of organofuncational bis-silanes and their effectiveness
in prodiving corrosion resistance of metals
/. S. Gandhi and W. J. van Ooij 105
Silane coupling agents as corrosion fatigue inhibitors
A. Seth and W. J. van Ooij 119
Modified silane coatings as an alternative to chromates for corrosion
protection of aluminum alloys
V Palanivel and W. J. van Ooij 135
VI Contents
Musical instrument strings and corrosion: A comparative study
of aminosilane and benzotriazole surface treatments
A.A.Parker 161
Part 2: Other Coupling Agents / Adhesion Promoters
Cyclic azasilanes: Volatile coupling agents for nanotechnology
B. Arkles, Y Pan, G. L. Larson and D. H. Berry 179
Inorganic-organic hybrid polymers based on silanes for coating textile
substrates
T. Textor, D. Knittel, T. Bahners andE. Schollmeyer 193
Optimising the adhesion of glass fibres to an epoxy resin using plasma
copolymers
D. J. Marks and F. R. Jones 205
Organophosphate adsorption on metal oxide surfaces
M. J. Shepard, J. R. Comer, T. L. Young, J. 5. McNatt, M. P. Espe,
R. D. Ramsier, T. R. Robinson and L. Y. Nelson 225
Manufacture of resin-free fiberboards from wood fibers activated
with Fenton's reagent (H202/Fe2+)
P. Widsten and J. E. Laine 241
Silanes and Other Coupling Agents, Vol. 3, pp. vii-viii
Ed. K. L. Mittal
© VSP 2004
Preface
This book chronicles the proceedings of the Fourth International Symposium on
Silanes and Other Coupling Agents held under the aegis of MST Conferences, LLC
in Orlando, FL, June 11-13, 2003. The premier symposium on this topic was held
in honor of the 75th birthday of Dr. Edwin P. Plueddemann in Midland, MI, April
3-5, 1991 the proceedings of which were properly documented in a hard-bound
book [1]. The second symposium in this series (with a slightly different title) was
held under the auspices of C4 Technologies, Inc. in Newark, NJ, October 21-23,
1998 and the proceedings were also chronicled in a book form [2]. Apropos, it
should be recorded that the third symposium in this vein was organized by MST
Conferences, LLC in Newark, NJ, June 18-20, 2001 but, for a variety of reasons,
the proceedings of this event were not documented in the form of a hard-bound
book.
Silanes have been used for about half a century as coupling agents/adhesion pro
moters to promote adhesion between dissimilar materials in a variety of situations,
e.g., coating technology, adhesive bonding, and reinforced composites. However,
recently silanes have found other applications, for example, as corrosion inhibitors.
Currently, there has been tremendous R&D activity in unravelling the mechanisms
by which silanes work as well as in devising new and improved silanes.
The technical program for this symposium was comprised of 22 papers reflecting
both overviews and original research contributions. These presentations discussed
a number of topics including new applications of silanes, and both fundamental and
applied aspects were accorded due coverage.
Now turning to this volume, it contains a total of 16 papers which were properly
peer reviewed, revised and edited. So this book is not a mere collection of papers,
rather represents the highest standard of publication. The book is divided into two
parts: 1. Silane Coupling Agents; and 2. Other Coupling Agents/Adhesion Pro
moters. The topics covered include: sterically hindered silanes; silane hydrolysis;
silane oligomers; adsorption of silanes and their surface characterization; structure
of bis-silane water-barrier films; silanes for improving adhesive bonding of alu
minum, elastomer-to-metal adhesive bonds, and adhesion in silica-filler tire-tread
compounds; electrodeposition of bis-silanes; silanes to provide corrosion resistance
and as corrosion fatigue inhibitors; silane and other treatments for musical instru
ment strings; cyclic azasilanes as coupling agents for nanotechnology; hybrid poly
mers based on silanes for coating textile fabrics; plasma copolymers as adhesion
promoters; organophosphate adsorption; and activation of wood fibers.
Vlll Preface
This volume and its predecessors [1,2] containing bountiful information should
serve as a reference source for the latest R&D activity in the arena of coupling
agents. Anyone interested or involved in promoting adhesion between dissimilar
materials for any application should find this volume of great use and value.
Acknowledgements
First, my sincere thanks are due to my colleague and friend, Dr. Robert H. Lacombe,
for taking care of myriad details entailed in organizing this symposium. Second, all
authors are thanked for their interest, enthusiasm and contribution without which
this book would not have been possible. Special thanks are conveyed to unsung
heroes (reviewers, working behind the scene) for their many valuable comments.
Last, but not least, my appreciation goes to the staff of VSP (publisher) for doing an
excellent job in producing this book.
K. L. Mittal
P.O. Box 1280
Hopewell Jet., NY 12533
REFERENCES
1. K. L. Mittal (Ed.), Silanes and Other Coupling Agents. VSP, Utrecht, The Netherlands (1992).
2. K. L. Mittal (Ed.), Silanes and Other Coupling Agents, Vol. 2. VSP, Utrecht, The Netherlands
(2000).
Parti
Silane Coupling Agents