Progress in Olefin Polymerization Catalysts and Polyolefin Materials, Proceedings of the First Asian Polyolefin Workshop PDF
Preview Progress in Olefin Polymerization Catalysts and Polyolefin Materials, Proceedings of the First Asian Polyolefin Workshop
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Hujita, Takashi (Toho Catalyst Co., Ltd.) Imuta, Jun-iehi (Mitsui Chemicals Inc.) Kuramoto, Masahiko (Idemitsu Kosan Co., Ltd.) Miyatake, Tatsuya (Sumitomo Chemical Co., Ltd.) Takahashi, Mitsuru (Tosoh Fineehem. Corp.) Tayano, Takao (Japan Polypropylene Corp.) Watanabe, Harumi (Asahi Kasei Chemicals Corp.) Organized by Catalysis Society of Japan, Polymerization Catalysis Division Coorganized by The Chemical Society of Japan The Japan Petroleum Institute The Society of Polymer Science, Japan Nara Convention Bureau This page intentionally left blank Contents Committee v Preface xv 1 Creation of New Polyolefm Hybrids on the Surface of Molded Polypropylene Sheet 1 S. Matsuo, T. Matsugi, J. Saito, N. Kawahara, H. Kaneko, N. Kashiwa (R&D Center, Mitsui Chemicals, Inc., Japan) 2 Japanese National Project for the Innovation of Industrial Polypropylene Process Technology 7 M. Terano", K. Suehiroh, T, Sagae", E. Tobitad ("Japan Advanced Institute of Science & Technology,l'Mitsui Chemicals, Inc., "Japan Polypropylene, Co., Asahi Denka Co., Ltd., Japan) 3 Novel Energy and Cost Saving Polypropylene Stabilization via addition of Antioxidant into Polymerization System 13 H. Yokotaa, K. Nomura", T. Horikoshi3, Y. Negishia, N. Kawamoto11, E. Tobitaa, M. Teranob ("Asahi Denka Co., Ltd., Japan Polypropylene, Co., Japan) 4 Polymerization Behavior with Metallocene Catalyst Supported by Clay Mineral Activator 19 H. Nakano, T, Takahashi, H. Uehino, T, Tayano, T. Sugano (Polymerization Technical Center, Japan Polypropylene Corporation, Japan) 5 Regulating the Structure of Ethylene-Propylene Copolymer for Polyolefin In-reactor Alloy with Improved Properties 25 Q. Dong, N. Li, X. Wang, Z. Fu, J. Xu, Z. Fan (The Institute of Polymer Science, Zhejiang University, China) VII viii Contents 6 Application of High Resolution FTIR Spectroscopy in Structural Characterization of Polyethylene and Ethylene Copolymers 31 Z. Sua, X. Zhanga, N. Kanga, Y. Xub, Y. Zhao", D. Wang,"" J. Wub, D. Xua ("State Key Laboratory of Polymer Physics and Chemistry, Institute of Chemistry, Chinese Academy of Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, China) 7 Microstructure Characterization of Polyolefins. TREF and CRYSTAF 35 B. Monrabal (Polymer Char, Spain) 8 Ultra-high Molecular Weight Polyethylene from Slurry INSITE™ Technology 43 Koichi Hasebe, Akio Fujiwara, Takashi Nozaki, Koichi Miyamoto, and Harumi Watanabe {Polyolefins Development Dept, Polyethylene Division, Asahi Kasei Chemicals Corporation, Japan) 9 Effects of Solvents in Living Polymerization of Propene with ^BuNSiMe (3,6-^Bu Flu)]TiMeMMAO Catalyst 47 2 2 r T. Shiono, Z. Cai, Y. Nakayama (Graduate School of Engineering, Hiroshima University, Japan) 10 Preparation of Ethylene/Polyhedral Oligomeric Silsesquioxane(POSS) Copolymers with rae-Et(Ind) ZrCl /MMAO 2 2 Catalyst System 53 D.-H Leea, K.-B. Yoona, M.-S. Junga, J.-K. Sungb, S. K. Nohc ("Department of Polymer Science, Kyungpook National University, Korea, bR&D Center, Korea Petrochemical Inc., Korea, cSchool of Chemical Engineering and Technology, Yeongnam University, Korea) 11 Norbomene and Ethylene Polymerization with Palladium and Nickel Complexes with Potentially Tri- or Tetradentate Ligands 59 D. W. Leea, C. Kimb, I.-M. Leea ("Department of Chemistry, Inha University, Korea, ^Department of Fine Chemistry, Seoul National University of Technology, Korea) 12 Effects of Bridge Nature of Dinuclear Half-Titanocenes on Polymerization Properties 69 Seok Kyun Noh\ Yong Rok Lee\ Won Seok Lyoob, Dong-Ho Leec ("School of Chemical Engineering and Technology, Yeungnam University, Korea, School of Textiles, Yeungnam University, Korea, ^'Department of Polymer Science, Kyungpook National University, Korea) Contents ix 13 Modification of Catalytic Properties of Homogeneous Metallocene Catalytic Systems in Propylene Polymerization under Action of Triisobutylaluminum and Lewis Bases 77 N.M. Bravaya, E.E. FalngoPd, EA. Sanginov, A.N. Panin, O.N. Babkina, S.L. Saratovskikh, O,N, Chukanova, A.G. Ryabenko, E.N. Ushakov {Institute of Problems of Chemical Physics, Russian Academy of Sciences, Russia) 14 Iron(II) Complexes Ligated with 2-Irnino-l,10-Phenanthroline for Ethylene Activation 87 W.-H. Sun, S. Jie, S. Zhang, W. Zhang (Key Laboratory of Engineering Plastics, Institute of Chemistry, Chinese Academy of Sciences, China) 15 Polymerization of 1 -Hexene and Copolymerization of Ethylene with 1-Hexene Catalyzed by Cationic Half-Sandwich Scandium Alkyls 95 Y. Luob, Z. Houa (fl Organometallic Chemistry Laboratory, RIKEN, Japan, bPRESTO, Japan Science and Technology Agency, Japan) 16 Stereoerrors Formation in the Polymerization of Deuterated Propylene 105 V. Volkis, A. Lisovskii, M, S. Eisen (Department of Chemistry and Institute of Catalysis Science and Technology, Technion Israel Institute of Technology, Israel) 17 Vinylic Polymerization of Norbornene with Neutral Nickel(IT) Complexes Bearing P-Diketiminato Chelate Ligands 113 Y.-Q. Duan, X.-F. Li, Y.-S. Li (State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, China, and Graduate School of the Chinese Academy of Sciences) 18 Effect of Anionic Ancillary Ligand in Ethylene Polymerization Catalyzed by (Arylimido)vanadium Complexes Containing Aryloxide, Ketimide Ligand 123 K. Nomura, W. Wang, J. Yamada (Graduate School of Materials Science, Mara Institute of Science and Technology, Japan) 19 Computational Approach on the Interaction between CrO and 3 Ethylene as a Model for the Understanding of Phillips Catalyst 129 B. Liu, W. Xia, M. Terano (School of Materials Science, Japan Advanced Institute of Science and Technology, Japan)
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