Progress in Nanotechnology PDF
Preview Progress in Nanotechnology
Progress in Published by The American Ceramic Society 735 Ceramic Place Westerville, Ohio 4308 I USA www. c e ram i c s. o rg Copyright 2002,The American Ceramic Society, All rights reserved. Statements of fact and opinion are the responsibility of the authors alone and do not imply an opinion on the part of the officers, staff, or mem- bers ofThe American Ceramic SocietyThe American Ceramic Society assumes no responsibility for the statements and opinions advanced by the contributors to i ts publications or by the speakers at i ts programs. Errors of fact or omission are the sole responsibility of the authors. Registered names and trademarks, etc., used in this publication, even without specific indication thereot are not to be considered unprotected by the law. 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Box 6 I 36, Westerville, Ohio 43086-6 136, USA. COVER PH0TOS:Top right:“SEM micrograph of Sic-based fibers, prepared from a (TEOS/phenoIic)-based sol, after pyrolysis at I I O O O C ’ is cour- tesy of Chang-An Wang, Michael D. Sacks, Greg A. Staab, and Zhe Cheng, and appears as figure 4 in their paper “Solution-Based Processing of Nanocrystalline Sic,’’ which begins on page 283. Left center: “Secondary electron images of a) Aulacoseira diatom frustule after reactive conversion (9OO0C, 4 h, Mg(g) into MgO” is courtesy of Ken H. Sandhage, Matthew B. Dickerson, philip M. Huseman, Frank M. Zalar; Mark C. Carroll, Michelle R Rondon, and Eryn C. Sandhage, and appears as figure 2a in their paper “A Novel Hybrid Route to Chemically-Tailored,Three-DimensionalO xide Nanostructures:T he Basic (Bioclastic and Shape-Preserving Inorganic Conversion) Process,” which begins on page 255. Bottom right:“Sintered zirconia tube shaped by EPD of a powder mixture of nanosized and micrometer-sizedz irconia particles from an aqueous suspension” is courtesy of JanT abellion and Rolf Clasen, and appears as figure 8 in their paper “Advanced Ceramic or Glass Components and Composites by Electrophoretic Deposition/lmpregnation Using Nanosized Particles,” which begins on page 227. l3ackground:”Silica green body with functionally graded density and pore size ...(l eft) with nanosized fumed silica particles” is courtesy of jan Tabellion and Rolf Clasen, and appears as figure 9 in their paper “Advanced Ceramic or Glass Components and Composites by Electrophoretic Deposition/lmpregnation Using Nanosized Particles,” which begins on page 227. For information on ordering titles published by The American Ceramic Society, or to request a publications catalog, please contact our Customer Service Department at 6 1 4-794-5890 (phone), 6 I 4-794-5892 (fax),< CONTENT8 Introduction , , , , , . , , . . , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , ,vii AMERICANC ERAMISCO CIETY BULLETIN Market Analysis of Nanostructured Materials ...................... .3 Mindy N. Rittner Vol. 8 I , No. 3, 2002 PbTiO, Nanosized Ceramics .................................. .7 D.S.Yu, J.C.H an, and Liu Ba Vol. 81, No. 9,2002 Nanosized Alumina Fibers ................................... .9 FrederickT epper, Marat Lerner, and David Ginley Vol. 80, No. 6,2001 A New Flame Process for Producing Nanopowders ................... I3 G.S Tompa, G. Skandan, N. Glumac, and B.H. Kear Vol. 78, No. 10, I999 IOURNAL OF THE AMERICAN CERAMIC SOCIETY Carbon Nitride-Related Nanomaterials from Chemical Vapor Deposition: Structure and Properties ...................... .21 E. G. Wang Vol. 85, No. I , 2002 Effect of Ammonia Treatment on the Crystallization of Amorphous Silicon-Carbon-Nitrogen Ceramics Derived from Polymer Precursor Pyrolysis ............................ .25 JulinW an, Matthew J. Gasch, and Amiya K. Mukherjee Vol. 85, No. 3,2002 Novel Method to Prepare Electroconductive Titanium Nitride-Aluminum Oxide Nanocomposites ........................ 37 Jingguo Li, Lian Gao, Jingkun Guo, and Dongsheng Yan Vol. 85, No. 3,2002 Near-Field Optical Characterization of Nanocomposite Materials ........ .41 Lukas Novotny Vol. as, No. 5,2002 Morphological Control of Zirconia Nanoparticles through Combustion Aerosol Synthesis ............................... .45 Amit U. Limaye and Joseph J. Helble Vol. 85, No. 5,2002 Preparation of a Bioactive Poly(methy1 methacrylate)/ Silica Nanocomposite ..................................... .51 Sang-Hoon Rhee and Je-Yong Choi Vol. 85, No. 5,2002 Synthesis of Platinum/Silica Nanocomposite Particles by Reverse Micelle and Sol-Gel Processing ....................... .55 Dong-Sik Bae, Kyong-Sop Han, and lames H.Adair Vol. 85, No. 5,2002 Synthesis of a Hydroxyapatite/Collagen/Chondroitin Sulfate Nanocomposite by a Novel Precipitation Method ................... 59 Sang-Hoon Rhee and JunzoT anaka Vol. 84, No. 2,2001 Evidence for Bulk Residual Stress Strengthening in AI,O,/SiC Nanocomposites ........................................ .63 Luca Paolo Ferroni and Giuseppe Peuotti Vol. 85, No. 8,2002 Synthesis of Dense TiB,-TiN Nanocrystalline Composites through Mechanical and Field Activation ........................ .69 Jae Won Lee, Zuhair A. Munir, Masachika Shibuya, and Manshi Ohyanagi Vol. 84, No. 4,2001 Nanofiber Formation in the Fabrication of Carbon/Silicon Carbide Ceramic Matrix Nanocomposites by Slurry Impregnation and Pulse Chemical Vapor Infiltration ................. 77 Nyan-HwaTai and Che-Fu Chen Vol. 84, No. 8,2001 Single-Source Sol-Gel Synthesis of Nanocrystalline ZnAl,O,: Structural and Optical Properties ............................ A3 Sanjay Mathur, Michael Veith, Michel Haas, Hao Shen, Nicolas Lecerf,Volker Huch, Stefan Hufner, Robert Haberkorn, Horst f? Beck, and Mohammad Jilavi Vol. 84, No. 9,2001 Strengthening of Porous Alumina by Pulse Electric Current Sintering and Nanocomposite Processing ........................ .91 Sung-Tag Oh, Ken-ichi Tajima, Motohide Ando, and Tatsuki Ohji Vol. 83, No. 5,2000 Reaction-Bonded and Superplastically Sinter-Forged Silicon Nitride-Silicon Carbide Nanocomposites ........................ .95 Naoki Kondo,Yoshikazu Suzuki, and Tatsuki Ohji Vol. 83, No. 7,2000 Nonisothermal Synthesis of Yttria-Stabilized Zirconia Nanopowder through Oxalate Processing: I, Characteristics of Y-Zr Oxalate Synthesis and I t s Decomposition .................... 99 Oleg Vasylkiv and Yoshio Sakka Vol. 83, No. 9,2000 iv Calcium- and Lanthanum=Modified Lead Titanate (PCLT) Ceramic and PCLTlVinylidene Fluoride-Trifluoroethylene 0-3 Nanocomposites ........ .I07 Q. Q. Zhang, H. L.W. Chan, Q. F . Zhou, and C. L. Choy Vol. 83, No. 9,2000 CERAMIC TRANSACTIONS Preparation and Characterization of Iron Oxide-Zirconia Nanopowder for I t s Use as an Ethanol Sensor Material ............. .I 13 C.V. Gopal Reddy, S.A.Akbar,W. Cao, O.K.Tan, and W. Zhu Vol. 130, Chemical Sensors for Hostile Environments, 2002 Investigation of N-Cu-Zn Ferrite with High Performance Derived from Nanoferrite Powders ........................... .I25 Xiaohui Wang, Weiguo Qu, Longtu Li, Zhilun Gui, and JiZ hou Vol. I 29, Innovative Processing and Synthesis of Ceramics, Glasses, and Composites V, 2002 Crack Healing and Strength Recovery in Thermally-Shocked Sintered Alumina=SiC Nanocomposite ......................... .I33 S. Maensiri and Steve G. Roberts Vol. 128, Advances in Ceramic Matrix Composites Vll, 2002 Microstructure-Electrical Property Relationship in Nanocrystalline Ce0,Thin Films ............................. .I45 V. Petrovsky, 6.E Gorman, H.U. Anderson, and T. Petrovsky Vol. I 27 , Materials for Eledmchernical Energy Conversion and Storage, 2002 New Nanostructured Silicon and Titanium Nitride Composite Anodes for Li4on Batteries ................................ . I55 It-seok Kim, Prashant N. Kumta, and G.E. Blomgren Vol. / 2 7, Materials for Ekdrochemical Energy Conversion and Storage, 2002 CERAMIC ENGINEERINGA ND SCIENCE PROCEEDINGS (CESP) SinglelStep Preparation of Nanosized Ceramics and Composites from Metal-Organic Precursors ............................. .I67 Sanjay Mathur, Michael Veith, Hao Shen, and Stefan Hufner Vol. 23, Issue 4,2002 Preparation and Characterization of Nanocrystalline Nasicon Powders andThin Films .................................. ,179 S.V. Kesapragada, S. Bhaduri, S.B. Bhaduri, E.G. Baburaj, and P.A. Lessing Vol. 23, Issue 4,2002 Manufacturing of Glass and Ceramic Matrix Composites by Electrophoretic Impregnation with Nanosized Powders ............... I87 Jan Tabellion, Christian Oetzel, and Rolf Clasen Vol. 23, Issue 4,2002 Comparative Investigation of AI,O, and ZrO, Nanopowders Synthesized by Different Methods ............................ .I95 Stephan Appel, Rolf Clasen, Andrei Chkourankov, Harald Natter, Rolf Hempelmann, Sabine Schlabach, Bin Xu, and Dieter Vollath Vol. 23, Issue 4,2002 V Characterization of Doped Glasses Manufactured by Sintering of Nanoparticles ................................. .203 Karsten Smeets and Rolf Clasen Vol. 23, Issue 4,2002 Preparation of PLZT Powders from Nanosized Oxides ............... .21 I Erik Bartscherer, Kathy Sahner, and Rolf Clasen Vol. 23, Issue 4,2002 Sintering Behavior and Grain Structure Development of Zr0,- and AI,O,-Compacts Fabricated from Different Nanosized Powders ......... .219 Stephan Appel, Rolf Clasen, Sabine Schlabach, Bin Xu, and Dieter Vollath Vol. 23, Issue 4,2002 Advanced Ceramic or Glass Components and Composites by Electrophoretic Deposition/lmpregnation Using Nanosized Particles ..... ,227 Jan Tabellion and Rolf Clasen Vol. 23, Issue 4,2002 Physical and Mechanical Properties of Microwave Sintered Nano-Crystalline Hydroxyapatite ............................ ,239 M.G. Kutty, JJ?O lberding, S. Bhaduri, J.R. Jokisaari, and S.B. Bhaduri Vol. 23, Issue 4,2002 Properties and Microstructure of Alumina-Niobium and Alumina-Neodymium Titanate Nanocomposites Made by Novel Processing Methods ......... . 247 Joshua D. Kuntz, Guo-Dong Zhan, JulinW an, and Amiya K. Mukherjee Vol. 23, Issue 4,2002 A Novel Hybrid Route to Chemically-Tailored, Three-Dimensional Oxide Nanostructures: The Basic (Bioclastic and Shape-Preserving Inorganic Conversion) Process .............................. .255 Ken H. Sandhage, Matthew B. Dickerson, Philip M. Huseman, Frank M. Zalar, Mark C. Carroll, Michelle R. Rondon, and Eryn C. Sandhage Vol. 23, Issue 4,2002 Silicon NitridelSilicon Carbide Nanocomposites from Polymer Precursor . . ,267 JulinW an, Matthew J. Gasch, and Amiya K. Mukherjee Vol. 23, Issue 4,2002 Properties of Si,N,-MoSi, Composites with a Nanostructured Matrix ...... 275 D. Sciti, S. Guicciardi, and A. Bellosi Vol. 23, Issue 4,2002 Solution-Based Processing of Nanocrystalline SIC ................... 283 Chang-An Wang, Michael D. Sacks, Greg A Staab, and Zhe Cheng Vol. 23, Issue 4,2002 Solution-Based Processing of Nanocrystalline ZrC . ................. 293 Zeshan Hu, Michael D. Sacks, Greg A. Staab, Chang-An Wang, and Anubhav lain Vol. 23, Issue 4,2002 vi t 1NTRODUCTION he fields of nanoscale science, engineering, and technology, more widely known as nano- technology, have experienced quite an explosion of interest, both scientific and industrial, over Tt he past decade. Many believe nanotechnology has the potential for becoming the next materials revolution. The U.S. National Science and Technology Council created the National Nanotechnology Initiative ("1) in 2000. NNI became the top science and technology priority for the U.S. government with an initial 2001 budget of $495 million. For FY2003, the President's budget requested about $710 million for federal investment in nanotechnology, a 17% increase over FY2002. According to one market analysis*, the world market for nanoparticles reached $492.5 million in 2000 and is expected to climb to $900.1 million in 2005. The ceramics/materials community's interest in nanotechnology is fueled by the unique properties that can be obtained. Nanostructured materials with enhanced electrical, mechanical, magnetic, and optical properties have been developed. These enhanced properties open the door for many exciting applications. Current applications of nanomaterials include abrasives, catalysts, coatings, magnetic recording media, magnetic fluid seals, ceramic membranes, sunscreens, adhesives, MRI contrast agents, and reinforce- ments/fillers. Applications in biomaterials, cutting tools, gas sensors, solid oxide fuel cells, structural ceramics, thick films, wear-resistant coatings, FED phosphors and emitters, and transparent functional films will likely become common. The American Ceramic Society (ACerS) proudly contributes to the "nano-revolution" by organizing and sponsoring forums for information exchange and disseminating information through its various periodicals and books. This new book is a compilation of articles and papers previously published by ACerS. The articles orig- inated from the Journal of the American Ceramic Society, the American Ceramic Society Bulletin, Ceramic Engineering and Science Proceedings, and Ceramic Transactions. We hope this collection of papers on current research and development, manufacturing, and marketing data will provide a refer- ence resource for those involved in this new and exciting field of nanotechnology. ~~ *Business Contmuriication Co. Inc., Norwalk, Conn. vii This page intentionally left blank
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