PREVENTION OF FIRES AND EXPLOSIONS IN DRYERS - A USER GUIDE J. A. Abbott (Technical Editor) Second Edition THE INSTITUTION OF CHEMICAL ENGINEERS The information in this Guide is given in good faith and belief in its accuracy, but does not imply the acceptance of any legal liability or responsibility whatsoever, by the Institution, the Technical Editor or by individual members of the Working Party for the consequences of its use or misuse in any particular circumstances. Published by The Institution of Chemical Engineers Davis Building 165-171 Railway Terrace Rugby, Warwickshire, CV21 3HQ, England Copyright 0 1977 and 1990 The Institution of Chemical Engineers All rights reserved. No part of this publication may be reproduced, stored in a retrieval system, or transmitted, in any form or by any means, electronic, mechanical, photocopying, recording or otherwise, without the prior permission of the copyright owner. ISBN 0 85295 257 0 First Edition 1977 Second Edition 1990 Printed and bound by Antony Rowe Ltd, Eastbourne Cover phutograph by kind permission of APV Pasilac Umited .. I1 PREFACE In 1977 the Institution of Chemical Engineers published the User guide to fire and explosion hazards in the drying of particulate materials. This Guide has now been updated to take account of recent developments in process safety. This User Guide has been prepared by a working party of the Engineering Practice Committee of the Institution of Chemical Engineers. Its aims are to help those responsible for the design, installation, operation and maintenance of dryers to: 0 recognise and assess the potential fire and explosion hazards; 0 specify systems, equipment and operating procedures which will elimi- nate or reduce these hazards as far as is reasonably practicable; 0 provide adequate protection for personnel and equipment when required. The dryer is defined to include the associated heating system, dust recovery system, feeding system and product collection system, as well as the drying enclosure. The scope of the guide is restricted to dryers handling a particulate or granular product. It does not cover the drying of materials commonly classed as explosives or as having explosive properties. The information given in this guide should assist suppliers and users of drying equipment to comply with current relevant legislation. It is not a Code of Practice as defined in the 1974 Health and Safety at Work, etc Act. The recommendations in this guide will provide a basis for good practice in most situations, but it must be recognised that from time to time there will be situations and materials where strict adherence to its recom- mendations will be inappropriate. The Working Party which carried out the revision is listed overleaf. iii CONTENTS PART 1: GENERAL PRINCIPLES 1 INTRODUCTION 1 2 HAZARDS WHEN POWDERS ARE HEATED 4 2.1 INTRODUCI'ION 4 2.2 IGNITION OF DUST CLoUDS 6 2.3 IGNITION OF DUST LAYERS, DEPOSITS AND MATERIAL IN BULK 14 2.4 PRODUCT QUALITY CONSIDERATIONS 24 3 HAZARDS WITH FLAMMABLE VAPOURS 26 3.1 CHARA~sIlcOsF VAPOUR EXPLoSONS 26 3.2 HYBRID MIXTURES 28 4 EXPLOSION PRECAUTIONS 30 4.1 INTRODUCXON 30 4.2 EXPLosIoN PREVENTION 30 4.3 EXPLOSION PROTECTION 33 5 REDUCING THE IGNITION RISK 40 5.1 SELF-IGNITION 40 5.2 DIRECT HEATING SYSI'EMS 41 5.3 ELECTRWATIC DISCHARGES 41 5.4 ELECTRICAL EoUIPMENT AND bWI'RUMENTS 42 5.5 FRICTIONS PARKS AND FRICXONAL HEATING 43 5.6 WELDING, (IvTI1NG AND SIMILAR OPERATIONS 44 6 COMMON EQUIPMENT 45 6.1 HEATING SYSI'EMS 45 6.2 FEEDING SYSlEMS 46 6.3 DUSC OMYING AND RECOVERY 47 6.4 PRODUCr STORAGE VJSSZIS 53 7 COMMON OPERATING AND MAINTENANCE PRECAUTIONS 55 7.1 PLANT OPERATION 55 7.2 PLANT MAINTENANCE 61 V PREVENTlON OF FIRES AND EXPLOSIONS IN DRYERS PART 2: APPLICATION TO SOME COMMON TYPES OF DRYER 8 SPRAY DRYERS 63 8.1 b4TRODUCnON 63 8.2 HAZARDS 64 8.3 POTENTIAL IGNITION SOURCES 65 8.4 SAPETY FROM EXPLOSIONS 66 8.5 PROCESS SPECIFICATION 67 8.6 EQUlPMENT SPECIFICATION 69 8.7 OPERATION AND bhU"ANCE 69 9 PNEUMATIC CONVEYING DRYERS 71 9.1 INTRODUCI'ION 71 9.2 HAZARDS 72 9.3 POTENTIAL IGNITION SOURCES 73 9.4 SAPETY FROM -0NS 74 9.5 PROCESS SPECIFICATION 75 9.6 EQUIPMENT SPECIFICATION 76 9.7 OPERATION AND MAINTENANCE 77 10 FLUID BED DRYERS 78 10.1 h4l"TODUCI'ION 78 10.2 HAZARDS 79 10.3 POTENnAL IGNITION SOURCES 81 10.4 SAFETY FROM EXPLOSIONS 81 10.5 PROCESS SPECIFICATION 84 10.6 EQUIPMENT SPECIFICATION 85 10.7 OPERATION AND bhU"ANCE 86 11 ROTARY DRYERS 88 11.1 bJl"TODUCI'I0N 88 11.2 HAZARDS 89 11.3 POTENTIAL IGNITION SOURCES 90 11.4 SAPETY FROM EXPLOSIONS 90 11.5 PROCESS SPECIPICATION 91 11.6 EQUIPMENT SPECIFICATION 92 11.7 OPERATION AND MAINTENANCE 92 12 BAND DRYER5 93 12.1 b4TRODUCI'ION 93 12.2 HAZARDS 94 12.3 POTENnAL IGNITION SOURCES 95 vi CONTENTS 12.4 SAFElT FROM EXPUXIONS 95 12.5 PROCESS SpECrmcAnON % 12.6 EQUIPMENT SPECIFICATION % 12.7 OPERAlTON AND h4AINTMANCE 97 13 BATCH ATMOSPHERIC TRAY OVENS 98 13.1 INTRODUCIION 98 13.2 HAZARDS 98 13.3 POIENTIAL IGNITION SOURCES 99 13.4 SAFETY FROM EXPLOSIONS 99 13.5 PROCESS SPECIFICATION 101 13.6 EQUIPMENT SPECIFICATION 101 13.7 OPERATION AND bfAINTENANCE 102 14 BATCH VACUUM DRYERS 103 14.1 blTRODUCllON 103 14.2 HAZARDS 104 14.3 POTENTIAL IGNITION SOURCES 104 14.4 SAFElT FROM EXPIAXIONS 105 14.5 PROCESS SPECIFICATION 105 14.6 EQUIPMENT SPECIFICATION 106 14.7 OPERATION AND MAl”ANCE 107 15 TROUGH DRYERS 108 15.1 INTRODUCX~ON 108 15.2 HAZARDS 108 15.3 POIENTIAL IGNITION SOURCES 109 15.4 SAFETY FROM EXPUXIONS 109 15.5 PROCESS SPECIPICATION 110 15.6 EQUIPMENT SPECIFICATION 110 15.7 OPERATION AND MAl”ANU3 111 REFERENCES 113 APPENDIX A INITIAL SCREENING PROCEDURE TO ISOLATE DEFLAGRATING OR DETONATING EXPLOSIVES 117 APPENDIX B: TEST TO DETERMINE FIRE AND COMBUSTION PROPERTIES OF POWDERS 121 vii PART 1: GENERAL PRINCIPLES 1. INTRODUCTION One of the most common unit operations in chemical engineering is heating a solution, slurry, paste, or wet powder to drive off moisture and give a dry particulate product. In recent years in Britain this operation has resulted in an average of one explosion per year and over 30 fires per year serious enough for a local authority fire brigade to be called. Most natural produds of animal or vegetable origin are combustible. So are most synthetic organic powders, and also some oxidisable inorganic compounds such as iron pyrites. The risk is increased substantially if a flam- mable solvent is being evaporated from the material. Maloperation of an oil- or gas-fired heater is potentially another source of flammable vapour or gas. If combustible, dusty materials are handled there is a statutory requirement (in the UK) to take practicable precautions. These requirements are embodied in the Factories Act 1961. Sub-sections 31(1), (2) and (4) provide as follows: ‘(1) Where, in connection with any grinding, sieving, or other process giving rise to dust, there may escape dust of such a character and to such an extent as to be liable to explode on ignition, all practicable steps shall be taken to prevent such an explosion by enclosure of the plant used in the process, and by removal or prevention of accumulation of any dust that may escape in spite of the enclosure, and by exclusion or effective enclosure of possible sources of ignition.’ ‘(2) Where there is present in any plant used in any such process as aforesaid dust of such a character and to such an extent as to be liable to explode on ignition, then, unless the plant is so constructed as to withstand the pressure likely to be produced by any such explosion, all practicable steps shall be taken to restrict the spread and effects of such an explosion by the provision, in connection with the plant, of chokes, baffles and vents, or other equally effective appliances.’ ‘(4) No plant, tank or vessel which contains or has contained any explosive or inflammable substance shall be subjected: PREVENllON OF FIRES AND EXPLOSIONS IN DRYERS (a) to any welding, brazing or soldering operation; (b) to any cutting operation which involves the application of heat; or (c) to any operation involving the application of heat for the purpose of taking apart or removing the plant, tank or vessel or any part of it; until all practicable steps have been taken to remove the substance and any fumes arising from it, or to render them non-explosive or non-in- flammable; and if any plant, tank or vessel has been subjected to any such operation, no explosive or inflammable substance shall be allowed to enter the plant, tank or vessel until the metal has cooled sufficiently to prevent any risk of igniting the substance.’ Furthermore there are obligations under the Health and Safety at Work Act 1974, Part 1. Sections 2, 3 and 6 are particularly relevant. It is the responsibility of the Health and Safety Executive to enforce these legal requirements. Ignition sources which may be present in dryers and which could ignite flammable vapours and dusts, both as dispersions and in layers, in- clude electric sparks, electrical heating, frictional sparks, frictional heating and particles ignited in the burners of heating systems. If dust clouds, layers or bulk accumulations of combustible powders are exposed to elevated temperatures in air, they may self-heat and ignite spontaneously; some may undergo exothermic decomposition and this may sometimes be followed by ignition of the decomposition products. It is possible to determine specific temperatures at which these processes will occur. The basis of safety from explosions may be either (i) explosion prevention, or (E) acceptance of the possibility of an explosion and provision of a method of protecting personnel and equipment from its consequences. Explosions may be prevented by drying in an inert atmosphere, avoid- ing the formation of a dust cloud (provided no flammable vapour is present) or rigorously excluding all passible ignition sources. The last is difficult to guarantee and should only be used as the basis of safety when no other method is reasonably practicable. Protection from explosions can be achieved by pro- viding vents to relieve an explosion to a safe area, suppressing an explosion by rapid release of inerting chemicals or making plant strong enough to contain an explosion without damage. Whatever the basis of safety, all reasonably practicable steps to avoid ignition should be taken. 2 GENERAL PRINCIPLES Methods of dust explosion prevention and protection are described in three IChemE guides1t2J. The great diversity of industrial dryers and materials makes it im- possible to give detailed recommendations for every type in a guide of modest size. Moreover, this is a field where each situation must be judged individually. What this guide presents, therefore, is an account of the general principles of fire and explosion hazard assessment and control in the context of drying particulate materials, followed by examples of their application to some common types of dryer and ancillary equipment. In any case of doubt concerning explosion hazard and precautions in a given process the Health and Safety Executive lnspectors should be consulted in addition to obtaining other expert advice. 3