Plastics Additives PDF
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PLASTICS ADDITIVES AN INDUSTRIAL GUIDE Third Edition Volume I by Ernest W. Flick NOYES PUBLICATIONS WILLIAM ANDREW PUBLISHING, LLC Norwich, New York, U.S.A. Copyright Q 2001 by Ernest W. Flick No part of this book may be reproduced or utilized in any form or by any means, elec- tronic or mechanical, including photocopying, recording or by any information storage and retrieval system, without permission in writing from the Publisher. Library of Congress Catalog Card Number: 00-1081 17 ISBN: 0-8 155-1464-6 Printed in the United States Published in the United States of America by Noyes Publications / William Andrew Publishing, LLC Norwich, New York, U.S.A. I0987654321 Library of Congress Cataloging-in-Publication Data Flick, Ernest W. Plastics additives: an industrial guide / by Ernest W. Flick. -- 3rd ed. p. cm. Includes index. ISBN 0-8155-1464-6 1. Plastics--Additives. I. Title. TP 114 2.F58 2001 668.4’1 I--dc20 00-1081 17 CIP To Kaitlin Leeann Margarite Brown NOTICE To the best of our knowledge the information in this publication is accurate; however, the Publisher does not assume any responsibility for the accuracy or completeness of, or consequences arising from, such information. This industrial guide does not purport to contain detailed user instructions, and by its range and scope could not possibly do so. Mention of trade names or commercial products does not constitute endorsement or recommendation for use by the Publisher. In some cases plastics additives could be toxic, and therefore due caution should be exercised. Final determination ofthe suitability of any information or product for use contemplated by any user, and the manner of that use, is the sole responsibility of the user. We strongly recommend that users seek and adhere to amanufacturer’s or supplier’s current instructions for handling each material they use. The Author and Publisher have used their best efforts to include only the most recent data available. The reader is cautioned to consult the supplier in case of questions regarding current availability. Preface The Third Edition of this useful book is divided into three volumes. Volume I describes almost 1,000 plastics additives which are currently available to industry. It is the result of information received from 76 industrial companies and other organizations. The data represents selections from manufacturers’ descriptions made at no cost to, nor influence from, the makers or distributors of these materials. Only the most recent information has been included. It is believed that all of the products listed here are currently available, which will be of utmost interest to readers concerned with product discontinuances. Plastics additives, a complex and growing group of minerals and chemical derivatives, account for 15 to 20% by weight ofthe total volume of plastic products marketed. They are produced by a large number of companies for a wide variety of customers and needs. Growth of the use of these additives, which impart one or more desirable properties to resins, is relatively strong, about 3.5 to 4% per year. Environmental constraints, however, have imposed rigorous performance requirements on many products, thus placing added expenses on the development costs of these materials. Plastics additives are divided into logical sections in three volumes. Volume I: I. Adhesion Promoters 11. Anti-Fogging Agents vii viii Preface 111. Antioxidants IV. Anti-Static Agents V. Antibacterials/Fungicides/Mildewcides VI. Bonding, Blowing and Foaming Agents VII. Dispersants VIII. Fillers and Extenders IX. Fire and Flame RetardantdSmoke Suppressants Volume 11: X. Impact Modifiers XI. Initiators XII. Lubricants XIII. Micas XIV. Pigments, Colorants, and Dyes XV. Plasticizers and Esters XVI. Processing Aids XVII. Release Agents XVIII. Silanes, Titanates, and Zirconates XIX. Slip and Anti-Blocking Agents Volume 111: XX. Stabilizers XXI. Stearates XXII. UV Absorbers XXIII. Viscosity Regulators XXIV. Waxes XXV. Miscellaneous and Multipurpose Compounds The Table of Contents of each volume is organized to also serve as a subject index. Each raw material is located in the section which is most applicable. The reader seeking a specific raw material should check each section which could possibly apply. In addition to the Preface ix above, two further sections are included in each volume: a list of Suppliers’ Addresses and a Trade Name Index. These will be ex- tremely helpful to the reader. The following information is supplied for each product, as available, in the manufacturer’s own words: Company name and product category. Trade names and product numbers. Product description: a description of the product’s main features, as described by the supplier. The three volumes of this book will be of value to technical and managerial personnel involved in the preparation of products made with these plastics additives as well as to the suppliers of the basic raw materials. My fullest appreciation is expressed to the companies and organizations who supplied the data included in this book. November, 2000 Ernest W. Flick Contents and Subject Index SECTION I: ADHESION PROMOTERS ......................................................................... ADMTronicsU nlimited.Inc 3 PrimersIAdhesives ................................................................................ 3 ......................................................................... ChartweUInternational.Inc 6 CHARTWELLA dhesion Promoters ...................................................... 6 GeneralProperties .................................................................................. 6 General Properties for Higher Solid "H"P roducts ........................... 8 ........................................................................................ Dow CorningC orp 9 Dow Corning Coupling AgentdAdhesion Promoters ........................... 9 .................................................................................................... Sartomer 10 Adhesion Promoters ............................................................................ 10 UV Cure Applications ................................................................... 10 Peroxide Cure Applications ........................................................... 11 Metallic Monomers for Metal Adhesion .............................................. 12 NewToolsfor2000 .............................................................................. 13 New Acrylate Oligomers for Adhesives ....................................... 13 New Acrylate Oligomers for Inks .................................................. 13 New Acrylate Oligomers for Coatings .......................................... 13 ........................................................................ Uniroyal ChemicalCo.,Inc. 14 POLYBONDPolymerM odifiers ........................................................... 14 ROYALTLJFPolymer Modifiers ........................................................... 17 SECTION II: ANTI-FOGGING AGENTS .................................................................................................... LonzaInc 21 GLYCOLUBEAFA-1 Proprietary Anti-Fog .......................................... 21 ................................................................................................ Ch emax.1nc 22 CHEMSTATAntifogs ......................................................................... 22 ..................................................................................... MerixChemicalC o 23 MERJX Anti-Fog with Anti-Static ........................................................ 23 Xi xii Contents .......................................................................... Morton Plastics Additives 24 LUBRIOL AntifoggingA gents ............................................................ 24 ............................................................................. Patco AdditivesD ivision 25 PATIONIC Antifogging Agents .......................................................... 25 ................................................................................................. Witco Corp 30 Additives for Polyolefins. Recommended Uses ................................... 30 Antifog & Antistat ....................................................................... 30 SECTION 111: ANTIOXIDANTS ................................................................................................. Bayer Corp 33 VULCANOXNULCANOLA ntioxidantdAntiozonants ....................... 33 ........................................................................... Ciba Specialty Chemicals 37 Additives for Polyolefins ..................................................................... 37 Antioxidants (AO) & Processing Stabilizers .......... Antioxidants (AO) & Processing Stabilizer Blends ....................... 38 ................................................................................... Cytec Industries Inc 39 CYANOX Antioxidants ........................................ .............. 39 ., ...................................................................... Fairmount ChemicalCo Inc 41 MIXXIM AO-30 Antioxidant ............................................................... 41 ............................................................................. GE Specialty Chemicals 42 WESTON & ULTRANOX Antioxidants ............................................. 42 .................................................................................... GoodyearC hemical 47 WINGSTAY Antioxidants ............................................ .................................................................... Great Lakes Chemical Corp 49 Antioxidants ........................................................................................ 49 ........................................................................................................ Mayzo 52 Antioxidants ........................................................................................ 52 Antioxidants and Thermal Stabilizers ................................................. 53 BENEFOS 1680 Phosphite Type Antioxidant .................................... 54 ................................................................................. Neville Chemical Co 55 NEVASTAIN 2 1 Nonstaining Antioxidant ......................................... 55 ............................................................................................. Raschig Corp 56 RALOX Antioxidants .......................................................................... 56 ......................................................................................................... 3V Inc 59 ALVINOX Antioxidants ..................................................................... 59 ALVIPACK Antioxidant Blends ............................ .................... 61 ...................................................................... Uniroyal Chemical Co., Inc 63 NAUGARD Antioxidants ....................................... NAUGARDWTOX Antioxidants ....................... POLYGARD Antioxidants ................................................... ................................................................................................ Witco Corp 73 Additives for Polyolefins, Recommended Uses .................................. 73 Antioxidants ................................................................................ 73 Contents xiii SECTION IV: ANTI-STATIC AGENTS ............................................................................................. ACLStaticide 79 STATICIDETopicalA nti-Stats ........................................................... 79 ......................................................................... Akzo Nobel Chemicals Inc 81 ARMOSTAT Antistatic Additives ...................................................... 81 Concentrates ................................................................................. 83 ................................................................................ Amstat 1ndustries.Inc 84 Anti-static Chemicals ........................................................................... 84 ................................................................................................. BASFCorp 85 LAROSTAT Antistats ......................................................................... 85 LAROSTAT Antistatic Additives ........................................................ 86 LAROSTAT FPE-S Food Grade Antistat ............................................ 87 LAROSTAT HTS 905 Antistat ............................................................. 88 ................................................................................................ Chemax.Inc 89 CHEMSTAT Antistats ........................................................................ 89 ................................................................................... CytecIndustriesInc 92 CYASTAT Antistatic Agents .............................................................. 92 .................................................................... Eastern Color & Chemical Co 94 ECCOSTAT ASP Anti-Static Agent .................................................... 94 ................................................................................................ JacksonLea 95 LEA Antistat Anti-Static Solution ....................................................... 95 .................................................................................................... LonzaInc 96 GLYCOSTATand GLYCOLUBEA ntistaticA gents ............................. % .................................................................................... MerixChemical. Co 97 MERIX Anti-Static #79 Concentrate .................................................... 97 ............................................................................. Patco AdditivesDivision 98 PATIONIC Antistatic Agents .............................................................. 98 ..................................................................................................... 3VInc 102 ANTISTATIC0 KN Antistatic Agent ................................................ 102 ................................................................................ TomahProducts.Inc 103 E-Series EthoxylatedA mines ............................................................. 103 Anti-Static Agent Use ................................................................ 103 Q-Series QuaternaryA mines .............................................................. 104 Anti-static Agent Use ................................................................. 104 SECTION V: ANTIBACTERIALS/FUNGICIDES/ MILDEWCIDES ............................................................................................... FerroCorp 107 MICRO-CHEKAntimicrobials. .......................................................... 107 ............................................................................. MicrobanProductsCo 108 Microban Antibacterial ...................................................................... 108
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