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Physical properties of diamond and sapphire PDF

93 Pages·2019·4.553 MB·English
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Physical Properties of Diamond and Sapphire Physical Properties of Diamond and Sapphire Roshan L. Aggarwal Anant K. Ramdas CRC Press Taylor & Francis Group 6000 Broken Sound Parkway NW, Suite 300 Boca Raton, FL 33487-2742 © 2019 by Taylor & Francis Group, LLC CRC Press is an imprint of Taylor & Francis Group, an Informa business No claim to original U.S. Government works Printed on acid-free paper International Standard Book Number-13: 978-0-367-23508-6 (Hardback) This book contains information obtained from authentic and highly regarded sources. Rea- sonable efforts have been made to publish reliable data and information, but the author and publisher cannot assume responsibility for the validity of all materials or the consequences of their use. The authors and publishers have attempted to trace the copyright holders of all material reproduced in this publication and apologize to copyright holders if permission to publish in this form has not been obtained. If any copyright material has not been acknowl- edged, please write and let us know so we may rectify in any future reprint. Except as permitted under U.S. Copyright Law, no part of this book may be reprinted, reproduced, transmitted, or utilized in any form by any electronic, mechanical, or other means, now known or hereafter invented, including photocopying, microfilming, and recording, or in any information storage or retrieval system, without written permission from the publishers. For permission to photocopy or use material electronically from this work, please access www.copyright.com (http://www.copyright.com/) or contact the Copyright Clearance Center, Inc. (CCC), 222 Rosewood Drive, Danvers, MA 01923, 978-750-8400. CCC is a not- for-profit organization that provides licenses and registration for a variety of users. For organizations that have been granted a photocopy license by the CCC, a separate system of payment has been arranged. Trademark Notice: Product or corporate names may be trademarks or registered trade- marks, and are used only for identification and explanation without intent to infringe. Library of Congress Cataloging-in-Publication Data Names: Aggarwal, R. L. (Roshan Lal), 1937- author. | Ramdas, Anant K., author. Title: Physical properties of diamond and sapphire / Roshan L. Aggarwal and Anant K. Ramdas. Description: First edition. | Boca Raton, FL : CRC Press/Taylor & Francis Group, 2019. | Includes bibliographical references and index. Identifiers: LCCN 2019006297| ISBN 9780367235086 (hardback : acid-free paper) | ISBN 9780429283260 (ebook) Subjects: LCSH: Diamonds. | Sapphires. Classification: LCC QE393 .A384 2019 | DDC 549/.27--dc23 LC record available at https://lccn.loc.gov/2019006297 Visit the Taylor & Francis Web site at http://www.taylorandfrancis.com and the CRC Press Web site at http://www.crcpress.com This monograph is dedicated to our parents (Chet Ram Aggarwal and Lila Vati Aggarwal and Lakshminarayanapuram AnanthakrishnaIyer Ramdas and Kalyani Ramdas), our spouses (Pushap Lata Aggarwal and Vasanthalakshmi Ramdas), our children (Rajesh Aggarwal and Achal Aggarwal), and our grandchildren (Isha Aggarwal, Neena Aggarwal, Akash Aggarwal, and Ashok Aggarwal). Contents Preface, xi Acknowledgments, xiii Authors, xv Chapter 1 ◾ Introduction 1 1.1 DIAMOND 3 1.1.1 Color of Natural Diamonds 3 1.1.2 Physical Properties of Diamond 3 1.2 SAPPHIRE 6 1.2.1 Colors of Sapphire 6 1.2.2 Physical Properties of Sapphire 8 Chapter 2 ◾ Crystal Structure and Growth 9 2.1 DIAMOND 9 2.2 SAPPHIRE 12 Chapter 3 ◾ Mechanical Properties of Diamond 17 3.1 HARDNESS 17 3.2 TENSILE STRENGTH 17 3.3 COMPRESSIVE STRENGTH 18 3.4 YOUNG’S MODULUS 18 3.5 ELASTIC CONSTANTS 20 vii viii ◾ Contents Chapter 4 ◾ Mechanical Properties of Sapphire 21 4.1 HARDNESS 21 4.2 TENSILE STRENGTH 21 4.3 YOUNG’S MODULUS 23 4.4 ELASTIC CONSTANTS 24 Chapter 5 ◾ Thermal Properties of Diamond 25 5.1 THERMAL EXPANSION 25 5.2 SPECIFIC HEAT 27 5.3 THERMAL CONDUCTIVITY 30 Chapter 6 ◾ Thermal Properties of Sapphire 33 6.1 THERMAL EXPANSION 33 6.2 SPECIFIC HEAT 34 6.3 THERMAL CONDUCTIVITY 35 Chapter 7 ◾ Optical Properties of Diamond 37 7.1 TRANSMISSION RANGE 37 7.2 REFRACTIVE INDEX 38 7.3 ABSORPTION SPECTRUM 40 Chapter 8 ◾ Optical Properties of Sapphire 43 8.1 TRANSMISSION AND ABSORPTION 43 8.2 REFRACTIVE INDEX 44 Chapter 9 ◾ Light Scattering of Diamond 47 9.1 RAMAN SCATTERING 47 9.2 BRILLOUIN SCATTERING 52 Contents   ◾   ix Chapter 10 ◾ Light Scattering of Sapphire 55 10.1 RAMAN SCATTERING 55 10.2 BRILLOUIN SCATTERING 59 Chapter 11 ◾ Sapphire Lasers 63 11.1 CHROMIUM-DOPED SAPPHIRE LASER 63 11.2 TITANIUM-DOPED SAPPHIRE LASER 63 REFERENCES, 67 INDEX, 73

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