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Optically stimulated luminescence : fundamentals and applications PDF

388 Pages·2009·5.257 MB·English
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Optically Stimulated Luminescence FUNDAMENTALS AND APPLICATIONS EDUARDO G. YUKIHARA | STEPHEN W. S. McKEEVER Optically Stimulated Luminescence Optically Stimulated Luminescence Fundamentals and Applications EDUARDO G. YUKIHARA and STEPHEN W. S. McKEEVER PhysicsDepartment, OklahomaState University Oklahoma,USA A John Wiley and Sons, Ltd., Publication This edition first published 2011 (cid:1)C 2011 John Wiley & Sons Ltd Registered office John Wiley & Sons Ltd, The Atrium, Southern Gate, Chichester, West Sussex, PO19 8SQ, United Kingdom For details of our global editorial offices, for customer services and for information about how to apply for permission to reuse the copyright material in this book please see our website at www.wiley.com. Therightoftheauthortobeidentifiedastheauthorofthisworkhasbeenassertedinaccordancewiththe Copyright,DesignsandPatentsAct1988. Allrightsreserved.Nopartofthispublicationmaybereproduced,storedinaretrievalsystem,ortransmitted,in anyformorbyanymeans,electronic,mechanical,photocopying,recordingorotherwise,exceptaspermitted bytheUKCopyright,DesignsandPatentsAct1988,withoutthepriorpermissionofthepublisher. Wileyalsopublishesitsbooksinavarietyofelectronicformats.Somecontentthatappearsinprintmaynotbe availableinelectronicbooks. Designationsusedbycompaniestodistinguishtheirproductsareoftenclaimedastrademarks.Allbrandnames andproductnamesusedinthisbookaretradenames,servicemarks,trademarksorregisteredtrademarksof theirrespectiveowners.Thepublisherisnotassociatedwithanyproductorvendormentionedinthisbook.This publicationisdesignedtoprovideaccurateandauthoritativeinformationinregardtothesubjectmattercovered. Itissoldontheunderstandingthatthepublisherisnotengagedinrenderingprofessionalservices.If professionaladviceorotherexpertassistanceisrequired,theservicesofacompetentprofessionalshouldbe sought. Thepublisherandtheauthormakenorepresentationsorwarrantieswithrespecttotheaccuracyorcompleteness ofthecontentsofthisworkandspecificallydisclaimallwarranties,includingwithoutlimitationanyimplied warrantiesoffitnessforaparticularpurpose.Thisworkissoldwiththeunderstandingthatthepublisherisnot engagedinrenderingprofessionalservices.Theadviceandstrategiescontainedhereinmaynotbesuitablefor everysituation.Inviewofongoingresearch,equipmentmodifications,changesingovernmentalregulations,and theconstantflowofinformationrelatingtotheuseofexperimentalreagents,equipment,anddevices,thereader isurgedtoreviewandevaluatetheinformationprovidedinthepackageinsertorinstructionsforeachchemical, pieceofequipment,reagent,ordevicefor,amongotherthings,anychangesintheinstructionsorindicationof usageandforaddedwarningsandprecautions.ThefactthatanorganizationorWebsiteisreferredtointhis workasacitationand/orapotentialsourceoffurtherinformationdoesnotmeanthattheauthororthepublisher endorsestheinformationtheorganizationorWebsitemayprovideorrecommendationsitmaymake.Further, readersshouldbeawarethatInternetWebsiteslistedinthisworkmayhavechangedordisappearedbetween whenthisworkwaswrittenandwhenitisread.Nowarrantymaybecreatedorextendedbyanypromotional statementsforthiswork.Neitherthepublishernortheauthorshallbeliableforanydamagesarisingherefrom. LibraryofCongressCataloging-in-PublicationData Yukihara,EduardoG. Opticallystimulatedluminescence:fundamentalsandapplications/EduardoG.YukiharaandStephenW.S. McKeever. p.cm. Includesbibliographicalreferencesandindex. ISBN978-0-470-69725-2(cloth)–ISBN978-0-470-97705-7(ePDF)–ISBN978-0-470-97706-4(ebook) 1.Opticallystimulatedluminescencedating. 2.Radiationdosimetry. I.McKeever,S.W.S.,1950– II.Title. QE508.Y852011 535(cid:2).356–dc22 2010037269 AcataloguerecordforthisbookisavailablefromtheBritishLibrary. PrintISBN: 978-0-470-69725-2 ePDFISBN: 978-0-470-97705-7 oBookISBN: 978-0-470-97706-4 ePubISBN: 978-0-470-97721-7 Typesetin10/12ptTimesbyAptaraInc.,NewDelhi,India. PrintedandboundinSingaporebyMarkonoPrintMediaPteLtd. ToStefanie,mymusic,mysilence ToJoanandourwonderfuldaughters,KatieandAlison. Contents Preface xi Acknowledgments xiii Disclaimer xiv ListofAcronyms xv 1 Introduction 1 1.1 AShortHistoryofOpticallyStimulatedLuminescence 1 1.2 BriefDescriptionofSuccessfulApplications 7 1.2.1 Personal 7 1.2.2 Space 8 1.2.3 Medical 9 1.2.4 Security 10 1.3 TheFuture 10 2 TheoryandPracticalAspects 13 2.1 Introduction 13 2.2 BasicAspectsoftheOSLPhenomenon 17 2.2.1 EnergyLevelsinPerfectCrystals 17 2.2.2 DefectsintheCrystal 18 2.2.3 ExcitationoftheCrystalbyIonizingRadiation 19 2.2.4 TrappingandRecombinationatDefectLevels 22 2.2.5 ThermalStimulationofTrappedCharges 24 2.2.6 OpticalStimulationofTrappedCharges 25 2.2.7 TheLuminescenceProcess 27 2.2.8 RateEquationsforOSLandTLProcesses 33 2.2.9 TemperatureDependenceoftheOSLSignal 40 2.2.10 OtherOSLModels 44 2.3 OSLReadout 47 2.3.1 BasicElementsofanOSLReader 47 2.3.2 StimulationModalities 48 2.4 Instrumentation 58 2.4.1 LightSources 59 2.4.2 LightDetectors 63 2.4.3 OpticalFilters 67 2.4.4 LightCollection 69 2.4.5 SampleHeaters 69 viii Contents 2.5 AvailableOSLReaders 70 2.5.1 ExperimentalArrangements 70 2.5.2 AutomatedResearchReaders 71 2.5.3 CommercialDosimetryReaders 73 2.5.4 OpticalFiberSystems 74 2.5.5 ImagingSystems 75 2.5.6 PortableOSLReaders 76 2.6 ComplementaryTechniques 76 2.6.1 OSLEmissionandStimulationSpectrum 76 2.6.2 LifetimeandTime-ResolvedOSLMeasurements 78 2.6.3 CorrelationsBetweenOSLandTL 78 2.6.4 OtherPhenomena 82 2.7 OverviewofOSLMaterials 82 2.7.1 ArtificialMaterials 85 2.7.2 NaturalMaterials 95 2.7.3 ElectronicComponents 98 2.7.4 OtherOSLMaterialsandMaterialNeeds 98 3 PersonalDosimetry 101 3.1 Introduction 101 3.2 QuantitiesofInterest 102 3.2.1 AbsorbedDoseandOtherPhysicalQuantities 103 3.2.2 ProtectionQuantities 108 3.2.3 OperationalQuantities 110 3.3 DosimetryConsiderations 111 3.3.1 Definitions 111 3.3.2 DoseCalculationAlgorithm 114 3.3.3 ReferenceCalibrationFieldsforPersonalandAreaDosimeters 118 3.3.4 UncertaintyAnalysisandExpressionofUncertainty 119 3.4 Detectors 123 3.4.1 GeneralCharacteristics 123 3.4.2 Al O :CDetectors 129 2 3 3.4.3 BeODetectors 140 3.5 DosimetrySystems 143 3.5.1 Luxel+DosimetrySystem 143 3.5.2 InLightDosimetrySystem 146 3.6 Neutron-SensitiveOSLDetectors 150 3.6.1 DevelopmentofNeutron-SensitiveOSLDetectors 151 3.6.2 PropertiesofOSLNDetectors 154 3.6.3 IonizationDensityEffects 157 4 SpaceDosimetry 163 4.1 Introduction 163 4.2 SpaceRadiationEnvironment 165 4.2.1 GalacticCosmicRays(GCR) 165 4.2.2 Earth’sRadiationBelts(ERB) 167

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