NONLINEAR OPTICS AND PHOTONICS Nonlinear Optics and Photonics Guang S. He StateUniversityofNewYorkatBuffalo 3 3 GreatClarendonStreet,Oxford,OX26DP, UnitedKingdom OxfordUniversityPressisadepartmentoftheUniversityofOxford. ItfurtherstheUniversity’sobjectiveofexcellenceinresearch,scholarship, andeducationbypublishingworldwide.Oxfordisaregisteredtrademarkof OxfordUniversityPressintheUKandincertainothercountries ©GuangS.He2015 Themoralrightsoftheauthorhavebeenasserted FirstEditionpublishedin2015 Impression:1 Allrightsreserved.Nopartofthispublicationmaybereproduced,storedin aretrievalsystem,ortransmitted,inanyformorbyanymeans,withoutthe priorpermissioninwritingofOxfordUniversityPress,orasexpresslypermitted bylaw,bylicenceorundertermsagreedwiththeappropriatereprographics rightsorganization.Enquiriesconcerningreproductionoutsidethescopeofthe aboveshouldbesenttotheRightsDepartment,OxfordUniversityPress,atthe addressabove Youmustnotcirculatethisworkinanyotherform andyoumustimposethissameconditiononanyacquirer PublishedintheUnitedStatesofAmericabyOxfordUniversityPress 198MadisonAvenue,NewYork,NY10016,UnitedStatesofAmerica BritishLibraryCataloguinginPublicationData Dataavailable LibraryofCongressControlNumber:2014945198 ISBN978–0–19–870276–4 PrintedinGreatBritainby ClaysLtd,StIvesplc To mywifeLan, mydaughterKatherineandherhusbandStephen, andmygrandchildren Emma,Joshua,Kate,Colette,andAdelyn Preface In this book, the author intends to provide a comprehensive presentation on most of the major topics in nonlinear optics and photonics, and to emphasize equally the principles, experiments, techniquesandapplications. Chapters1to10presentthefundamentalsofmodernnonlinearoptics,andcouldthereforebe adoptedasatextbookwithproblemsgivenattheendofeachchapter.Chapters11to17coverthe advancedtopicsoftechniquesandapplicationsofnonlinearopticsandphotonics,whichmayalso bebeneficialtosomeresearchersandexperts.Thisbookalsoincludes16colorpagesofselected photographstoillustratesometypicalnonlinearopticaleffectsandphenomena. Partofthisbook(Chapters2–5and18)isbasicallythesameasthatoriginallywrittenbythe authorinapreviousbook(G.S.HeandS.H.Liu,PhysicsofNonlinearOptics,WorldScientific, 1999); Chapters 6–11 are rewritten and updated; Chapters 12–17 are entirely new chapters dealingwiththelatestprogressandachievementsinnonlinearopticsandphotonics. As the author of this book, I am grateful to Prof. P. N. Prasad, the executive director of the Institute of Lasers, Photonics and Biophotonics, the State University of New York at Buffalo, forhislong-term(almostthreedecades)supportofmyresearchactivity.IamalsothankfultoDr. C.Y-CLee(AirForceOfficeofScientificResearch)forhisencouragementofmyresearchefforts. Inmyresearchcareer,Ihavebenefitedfromthecollaborationandinteractionwithmanytal- entedcolleaguesandoutstandingscientists.Forthisreason,IwouldliketothankDr.L.-S.Tan, Prof. H. Ågren, Prof. M. Samoc, Prof. R. W. Boyd, Prof. Y. R. Shen, Prof. I. C. Khoo, Prof. Y.Cui,Prof.D.L.Andrews,Prof.M.T.Swihart,Dr.A.Baev,andProf.S.H.Liu.Ialsowantto expressmygratitudetoDr.Y.ShenandProf.Q.D.Zhengforwritingsomeimportantsections, and to Prof. S. Y. Tian who critically read the entire manuscript and provided many necessary corrections.Finally,theadvicereceivedfromS.AdlungandtheassistancefromDr.J.ZhuandJ. Whitearegreatlyappreciated. TheInternationalSystemsofUnits(SI)isadoptedthroughoutthisbookforallformulations. GuangS.He Buffalo,NewYork September2014 Email:[email protected] [email protected] Contents 1 Introduction 1 1.1 Conventionalopticsandnonlinearoptics 1 1.2 Majortopicsofnonlinearopticsandphotonics 3 1.3 Characterizationofintensecoherentopticalfield 7 1.3.1 Intensityandbrightness 7 1.3.2 Spatialandtemporalcoherence 8 1.3.3 Photonmodeanddegeneracy 9 1.4 Twotheoreticalregimes 10 1.4.1 Semiclassicaltheory 10 1.4.2 Quantumtheoryofradiation 11 1.5 Applicabilityofthetwotheoriesinnonlinearopticsandphotonics 13 2 NonlinearPolarizationofanOpticalMedium 18 2.1 Opticalfield-inducedelectricpolarizationinamedium 18 2.2 Variousmechanismscausingnonlinearpolarizationinamedium 22 2.3 Manipulationofnonlinearsusceptibilities 23 2.4 Basicpropertiesofnonlinearsusceptibilities 25 2.4.1 Relativemagnitudeofvariousordersofsusceptibilities 25 2.4.2 Spatial-symmetryrestrictionsonsusceptibilities 25 2.4.3 Resonanceenhancementofsusceptibilities 26 2.4.4 Permutationsymmetryofsusceptibilities 26 2.4.5 Complexconjugationandtime-reversalsymmetryofsusceptibilities 27 2.5 Nonlinearcoupled-waveequations 27 2.6 Complexexpressionsofopticalwavefields 30 3 Second-OrderNonlinear(Three-Wave)FrequencyMixing 33 3.1 Second-harmonicgeneration(SHG) 33 3.1.1 QuantumdescriptionofthemechanismofSHG 33 3.1.2 SemiclassicaldescriptionofSHG 35 3.1.3 NonlinearcrystalsforSHG 39 3.1.4 SHGdevices 42 3.2 Opticalsum-anddifference-frequencygeneration 43 3.2.1 Opticalsum-frequencygeneration 43 3.2.2 Opticaldifference-frequencygeneration 45 3.2.3 Experimentalsetupsforopticalsum-anddifference-frequencygeneration 47 3.3 Opticalparametricamplificationandoscillation 47 3.3.1 Generaldescription 47 3.3.2 Solutionsofcoupled-waveequations 49 3.3.3 Experimentaldevices 51