Nanoscale Multifunctional Materials: Science and Applications

416 Pages·2012·15.43 MB·English

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NANOSCALE
MULTIFUNCTIONAL
MATERIALS
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JWBS079-fm JWBS079-Mukhopadhyay July27,2011 1:53 PrinterName:YettoCome
NANOSCALE
MULTIFUNCTIONAL
MATERIALS
Science and Applications
Editedby
SHARMILAM.MUKHOPADHYAY
AJOHNWILEY&SONS,INC.,PUBLICATION
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Copyright© 2012byJohnWiley&Sons,Inc.Allrightsreserved.
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LibraryofCongressCataloging-in-PublicationData:
Nanoscalemultifunctionalmaterials:science&applications/editedbySharmilaMukhopadhyay
p.cm.
Includesbibliographicalreferencesandindex.
ISBN978-0-470-50891-6(hardback)
1.Nanostructuredmaterials. I.Mukhopadhyay,SharmilaM.
TA418.9.N35N345542011
620.1(cid:2)15—dc23
2011021421
PrintedintheUnitedStatesofAmerica
oBookISBN:9781118114063
ePDFISBN:9781118114032
ePubISBN:9781118114056
MOBIISBN:9781118114049
10 9 8 7 6 5 4 3 2 1
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CONTENTS
CONTRIBUTORS vii
PREFACE ix
SECTIONI OVERVIEW 1
1 KeyAttributesofNanoscaleMaterialsandSpecialFunctionalities
EmergingFromThem 3
SharmilaM.Mukhopadhyay
2 SocietalImpactandFutureTrendsinNanomaterials 33
SharmilaM.Mukhopadhyay
SECTIONII PROCESSINGANDANALYSIS 61
3 FabricationTechniquesforGrowingCarbonNanotubes 63
I.T.Barney
4 NanoparticlesandPolymerNanocomposites 87
GuillermoA.Jimenez,ByoungJ.Lee,andSadhanC.Jana
5 Laser-AssistedFabricationTechniques 125
P.T.Murray
v
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vi CONTENTS
6 ExperimentalCharacterizationofNanomaterials 153
A.G.Jackson
7 ModelingandSimulationofNanoscaleMaterials 175
SoumyaS.PatnaikandMesfinTsige
SECTIONIII APPLICATIONS 199
8 NanomaterialsforAlternativeEnergy 201
HongHuangandBorZ.Jang
9 EnhancementofThrough-ThicknessThermalConductivityin
AdhesivelyBondedJointsUsingAlignedCarbonNanotubes 247
SangwookSihn,SabyasachiGanguli,AjitK.Roy,
LiangtiQu,andLimingDai
10 UseofMetalNanoparticlesinEnvironmentalCleanup 271
SushilR.Kanel,ChunmingSu,UpendraPatel,andAbinashAgrawal
11 UseofCarbonNanotubesinWaterTreatment 321
VenkataK.K.Upadhyayula,JayeshP.Ruparelia,andAbinashAgrawal
12 PeptideNanotubesinBiomedicalandEnvironmental
Applications 369
Byung-WookParkandDong-ShikKim
INDEX 393
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CONTRIBUTORS
AbinashAgrawal, DepartmentofEarthandEnvironmentalSciences,WrightState
University,Dayton,Ohio
IanT.Barney, CenterforNanoscaleMultifunctionalMaterials,WrightStateUni-
versity,Dayton,Ohio
LimingDai, CaseWesternReserveUniversity,Cleveland,Ohio
SabyasachiGanguli, UniversityofDaytonResearchInstitute,Dayton,Ohio
HongHuang, CollegeofEngineeringandComputerScience,WrightStateUniver-
sity,Dayton,Ohio
Allen G. Jackson, Center for Nanoscale Multifunctional Materials, Wright State
University,Dayton,Ohio
SadhanC.Jana, DepartmentofPolymerEngineering,UniversityofAkron,Akron,
Ohio
BorZ.Jang, CollegeofEngineeringandComputerScience,WrightStateUniver-
sity,Dayton,Ohio
GuillermoA.Jimenez, DepartmentofPolymerEngineering,UniversityofAkron,
Akron,Ohio;currentlyattheSchoolofChemistry,NationalUniversityofCosta
Rica,Heredia,CostaRica
SushilR.Kanel, DepartmentofSystemsandEngineeringManagement,AirForce
InstituteofTechnology,Wright-PattersonAirForceBase,Dayton,Ohio
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viii CONTRIBUTORS
Dong-ShikKim, DepartmentofChemicalandEnvironmentalEngineering,Univer-
sityofToledo,Toledo,Ohio
ByoungJ.Lee, DepartmentofPolymerEngineering,UniversityofAkron,Akron,
Ohio;currentlyatGoodyearTireandRubberCompany,Akron,Ohio
Sharmila M. Mukhopadhyay, Center for Nanoscale Multifunctional Materials,
WrightStateUniversity,Dayton,Ohio
PaulT.Murray, UniversityofDaytonResearchInstitute,Dayton,Ohio
Byung-WookPark, DepartmentofChemicalandEnvironmentalEngineering,Uni-
versityofToledo,Toledo,Ohio
UpendraPatel, Dr.JivrajMehtaInstituteofTechnology,Gujarat,India
Soumya S. Patnaik, Air Force Research Laboratory, Wright-Patterson Air Force
Base,Dayton,Ohio
LiangtiQu, BeijingInstituteofTechnology,Beijing,China
Ajit K. Roy, Air Force Research Laboratory, Wright-Patterson Air Force Base,
Dayton,Ohio
JayeshP.Ruparelia, InstituteofTechnology,NirmaUniversity,Ahmedabad,India
SangwookSihn, UniversityofDaytonResearchInstitute,Dayton,Ohio
ChunmingSu, U.S.EnvironmentalProtectionAgency,Ada,Oklahoma
MesfinTsige, DepartmentofPolymerScience,UniversityofAkron,Akron,Ohio
VenkataK.K.Upadhyayula, OakRidgeInstituteofScienceandEducation,Oak
Ridge,Tennessee
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PREFACE
Thepossibleimpactofnanomaterialsonfutureproductsandservicesisenormous.
Thishasledtoatremendousexpansioninresearchanddevelopmenteffortsrelated
tonanoscalematerialsanddevices.Ithasalsoraisednewquestionsastohowthese
products will influence the environment, human health, business, education, and
other areas of society. As with any emerging field, a vast amount of disconnected
information is emerging, often spread across multiple disciplines. The influence of
these materials, however, is truly multidisciplinary, and progress will depend upon
cross-communication between fundamental science and diverse applications. This
workisanattemptatconsolidatingseveraldiverseareasofnanomaterialsinorderto
providethereaderwithabroaderperspective.Itwillalsohelpinenvisioningfuture
productsandpossibilitiesthatmaynotexisttoday.
The book has been divided into three sections: Section I provides a panoramic
overviewofnanomaterials,beginningwithachapterhighlightingthescientificphe-
nomenathatmakenanomaterialsdifferentfromconventionalsolids.Thisisfollowed
byachapterdetailingtheimpactmadebythesematerialsonvariousareasofsoci-
ety. Section II provides articles related to the processing and analysis of nanoscale
materials. These involve multiple experimental approaches in fabrication and char-
acterization, as well as theoretical modeling and simulations. Section III provides
discussions of technological areas where nanomaterials can be used. Examples are
included dealing with the advanced energy, thermal management, environmental
and biomedical areas. Selected figures are reproduced in color free of charge at
ftp://ftp.wiley.com/public/sci tech med/nanoscale multifunctional.
ix
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x PREFACE
Thebookisaimedatthefollowingreaders:
(cid:2)
Advancedstudentsandinstructorsinthefieldsofscienceandengineering.
(cid:2)
Professional scientists and engineers, who may be trained in more traditional
disciplinesbutwhoneedtolearnaboutthisemergingarea.
(cid:2)
Policymakersandmanagementexpertslookingforanunderstandingofscientific
challenges,prospectiveuses,andemergingmarketsfornanomaterials.
The overall goal is to capture the multidisciplinary and multifunctional flavor of
nanomaterialswhileprovidingin-depthexpertdiscussionofselectareas.
Acknowledgments
Several people have made this book possible. I express my sincere gratitude to the
contributorsfortheireffortanddedicationinpreparingthechapters,toWrightState
University, and to my students for the teaching experience that motivated me to
createthisbook.SpecialthankstoAnilKarumuri,Ph.D.student,forhiscontinuous
assistance and hard work in putting the manuscript together. I also thank Anita
Lekhwani of Wiley, for giving me the idea of starting a book, and her publication,
team for their continuous help and support. Finally, I am indebted to my husband,
Bhaskar Mukhopadhyay, for his constant encouragement and support, and to my
daughter,Amrita,forherendlessenthusiasmandhelpwithgraphicdesign.
Dayton,Ohio SharmilaM.Mukhopadhyay
November 2010
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SECTION I
OVERVIEW