Table Of Content

Nanomaterials Synthesis This pageintentionallyleftblank Nanomaterials Synthesis Design, Fabrication, and Applications Editedby YASIRBEERAN POTTATHARA UniversityofMaribor,FacultyofMechanicalEngineering,Slovenia SABU THOMAS TheViceChancellorofMahatmaGandhiUniversity,Kottayam and FounderDirectorofInternationalandInterUniversityCentrefor NanoscienceandNanotechnology,andProfessoratSchoolof ChemicalSciences,MahatmaGandhiUniversity,Kottayam,India NANDAKUMAR KALARIKKAL DirectorandanAssociateProfessorofInternationalandInter UniversityCentreforNanoscienceandNanotechnology,andDirector andChairofSchoolofPureandAppliedPhysics,MahatmaGandhi University,Kottayam,India YVES GROHENS DirectorofLIMATBLaboratory,UniversityofSouthBrittany(UBS), France VANJAKOKOL AssociateProfessoratUniversityofMaribor,FacultyofMechanical Engineering,Slovenia Elsevier Radarweg29,POBox211,1000AEAmsterdam,Netherlands TheBoulevard,LangfordLane,Kidlington,OxfordOX51GB,UnitedKingdom 50HampshireStreet,5thFloor,Cambridge,MA02139,UnitedStates Copyright©2019ElsevierInc.Allrightsreserved. Nopartofthispublicationmaybereproducedortransmittedinanyformorbyanymeans, electronicormechanical,includingphotocopying,recording,oranyinformationstorageand retrievalsystem,withoutpermissioninwritingfromthepublisher.Detailsonhowtoseek permission,furtherinformationaboutthePublisher’spermissionspoliciesandour arrangementswithorganizationssuchastheCopyrightClearanceCenterandtheCopyright LicensingAgency,canbefoundatourwebsite:www.elsevier.com/permissions. Thisbookandtheindividualcontributionscontainedinitareprotectedundercopyrightby thePublisher(otherthanasmaybenotedherein). Notices Knowledgeandbestpracticeinthisfieldareconstantlychanging.Asnewresearchand experiencebroadenourunderstanding,changesinresearchmethods,professionalpractices, ormedicaltreatmentmaybecomenecessary. Practitionersandresearchersmustalwaysrelyontheirownexperienceandknowledgein evaluatingandusinganyinformation,methods,compounds,orexperimentsdescribed herein.Inusingsuchinformationormethodstheyshouldbemindfuloftheirownsafety andthesafetyofothers,includingpartiesforwhomtheyhaveaprofessionalresponsibility. Tothefullestextentofthelaw,neitherthePublishernortheauthors,contributors,or editors,assumeanyliabilityforanyinjuryand/ordamagetopersonsorpropertyasamatter ofproductsliability,negligenceorotherwise,orfromanyuseoroperationofanymethods, products,instructions,orideascontainedinthematerialherein. BritishLibraryCataloguing-in-PublicationData AcataloguerecordforthisbookisavailablefromtheBritishLibrary LibraryofCongressCataloging-in-PublicationData AcatalogrecordforthisbookisavailablefromtheLibraryofCongress ISBN:978-0-12-815751-0 ForInformationonallElsevierpublications visitourwebsiteathttps://www.elsevier.com/books-and-journals Publisher:MatthewDeans AcquisitionEditor:SimonHolt EditorialProjectManager:AndraeAkeh ProductionProjectManager:R.VijayBharath CoverDesigner:GregHarris TypesetbyMPSLimited,Chennai,India CONTENTS ListofContributors xi 1. Synthesis andProcessing of Emerging Two-Dimensional Nanomaterials 1 YasirBeeranPottathara,YvesGrohens,VanjaKokol, NandakumarKalarikkalandSabuThomas 1.1 Introduction 1 1.2 Emerging2DNanomaterials:UniquenessandAdvances 3 1.3 SynthesisApproaches 5 1.4 SummaryandOutlook 16 References 17 2. Nanomaterial Synthesis: Chemicaland Biological Route andApplications 27 SantanuSasidharan,ShwetaRaj,ShirishSonawane, ShriramSonawane,DipakPinjari,A.B.PanditandPrakashSaudagar 2.1 IntroductionandBackground:NanoparticleSynthesisApproaches 27 2.2 DifferentChemicalRoutesforNanomaterialSynthesis 31 2.3 NanoparticleSynthesisUsingtheBiologicalRoute 37 2.4 ApplicationofNanomaterials 42 2.5 RecentAdvancesintheChemicalandBiologicalSynthesisRoutes 44 2.6 Scale-UpIssuesofNanoparticleProductionandChallenges 46 2.7 Summary 46 Acknowledgment 47 References 47 3. Chemical Approachesfor 1D Oxide Nanostructures 53 F.A.TaherandE.Abdeltwab 3.1 Introduction 53 3.2 1DNanostructureSynthesisTechniques 55 3.3 1DZnONanostructures 57 3.4 1DTiO Nanostructure 67 2 3.5 Conclusion 79 References 79 v vi Contents 4. One- and Two-Dimensional NanostructuresPrepared byCombustion Synthesis 85 A.S.MukasyanandK.V.Manukyan 4.1 Introduction 85 4.2 CSFundamentals 88 4.3 MicrostructuralCharacteristicsofCombustion-DerivedNanomaterials 95 4.4 Conclusions 112 References 114 5. Microwave-Assisted Synthesis for Carbon Nanomaterials 121 SabzoiNizamuddin,SadafAftabAbbasi,AbdulSattarJatoi, M.T.H.Siddiqui,HumairAhmedBaloch,N.M.Mubarak,G.J.Griffin, E.C.Abdullah,KhadijaQureshiandRamaRaoKarri 5.1 Introduction 121 5.2 MethodsofSynthesisofCarbonNanomaterials 122 5.3 ChemicalVaporDeposition 124 5.4 Plasma-EnhancedChemicalVaporDeposition-BasedCarbon Nanomaterials 127 5.5 Microwave-EnhancedChemicalVaporDeposition 130 5.6 FluidizedBedChemicalVaporDeposition 134 5.7 VaporPhaseGrowthChemicalVaporDeposition 137 5.8 Microwave-AssistedSynthesisofGraphene 138 5.9 FutureProspectsforCarbonNanomaterialSynthesisandChallenges 139 5.10 Conclusion 140 References 141 6. Strategies in Laser-Induced Synthesis ofNanomaterials 149 V.Saikiran,MudasirH.Dar,R.Kuladeep,L.JyothiandD.NarayanaRao 6.1 Introduction 150 6.2 ExperimentalFabrication 158 6.3 ResultsandDiscussion 162 6.4 Conclusions 190 References 191 7. FlameSynthesis of Nanostructured Transition Metal Oxides: Trends,Developments, and Recent Advances 201 WilsonMerchan-Merchan,WalmyCuelloJimenez, OctavioRodriguezCoriaandChadWallis 7.1 Introduction 202 Contents vii 7.2 PropertiesandApplicationsof1Dand3DTransitionMetalOxide Nanostructures 206 7.3 FabricationTechniquestoSynthesizeTMONanostructures 214 7.4 FlamesasaUniqueFabricationTooltoProduceTMONanoparticles 218 7.5 FlameSynthesisofMultidimensionalTMOsUsingthe“SolidSupport” Method 226 7.6 VolumetricFlameSynthesisof1Dand3DTMOs 235 7.7 Core(cid:1)ShellandMixedTransitionMetalOxideNanostructures 240 7.8 Conclusions 252 Acknowledgments 253 References 253 8. Design andFabrication of Porous Nanostructures and Their Applications 265 ArpitaHazraChowdhury,NoorSalam,RinkuDebnath,Sk.ManirulIslam andTanimaSaha 8.1 Introduction 266 8.2 ClassificationofPorousNanostructures 267 8.3 SynthesisofPorousMaterials 267 8.4 NewSynthesisApproachesandChallengesofPorousNanostructures 278 8.5 ApplicationsofPorousMaterials 279 8.6 Conclusion 288 References 288 9. Synthesis andProcessing of Thermoelectric Nanomaterials, Nanocomposites,andDevices 295 LazarosTzounis 9.1 IntroductiontoEnergyNeedsandWastedThermalEnergy 295 9.2 FundamentalsoftheThermoelectricEffectandThermoelectricMaterials 297 9.3 InorganicThermoelectricNanomaterials 302 9.4 OrganicThermoelectrics:PolymerandNanocompositeSystems 309 9.5 WorkingPrincipleandSpecificArchitecturesofThermoelectric Generators 319 9.6 ApplicationofThermoelectricGenerators 321 9.7 RecentTrendsandChallenges 322 9.8 FuturePerspectives 326 9.9 SummaryandConclusions 326 Acknowledgment 327 References 327 viii Contents 10.Fabrication TechniquesofGroup 15 Ternary Chalcohalide Nanomaterials 337 MarianNowak,MarcinJesionek,andKrystianMistewicz 10.1 Introduction 338 10.2 FabricationofCompositeMaterials 339 10.3 BallMillingofBulkCrystals 346 10.4 Vapor-PhaseGrowthofSbSINanorods 347 10.5 Graphoepitaxy 349 10.6 SonochemicalSynthesisofSbSI-TypeNanowires 349 10.7 UltrasonicSprayPyrolysis 356 10.8 FillingofCarbonNanotubes 359 10.9 SolutionProcessing 363 10.10 Microwave-AssistedAqueousSynthesis 365 10.11 HydrothermalGrowth 366 10.12 ConversionofSb S IntoSbSI 369 2 3 10.13 HeatandLaserFormationofSbSINano-ObjectsinChalcohalide Glasses 370 10.14 NewTrendsinFabricationTechniques 377 10.15 FuturePerspectives 378 10.16 Summary 378 References 378 11.Advanced Carbon Materials for Electrochemical Energy Storage 385 RohitRanganathanGaddam,NanjundanAshokKumar, RamanujNarayan,K.V.S.N.RajuandX.S.Zhao 11.1 Introduction 385 11.2 CarbonMaterials:TypesandSources 388 11.3 CarbonMaterialsforEnergyStorage 397 11.4 ChallengesandFuturePerspectives 413 Acknowledgments 414 References 414 12.Organic(cid:1)Inorganic HybridNanomaterials: Synthesis, Characterization, and Application 419 VesnaLazic´ andJovanM.Nedeljkovic´ 12.1 Introduction 419 12.2 InterfacialChargeTransferComplexes:FormationMechanism andOpticalProperties 420 12.3 PolymerSupportsDecoratedWithInorganicNanoparticles 431 12.4 NewSyntheticApproachesandChallenges 435 Contents ix 12.5 PotentialApplicationofOrganicaInorganicHybrids:Photo-Driven ProcessesandAntimicrobialAbility 437 12.6 SummaryandOutlook 443 Acknowledgments 444 References 444 13.Fabrication, Characterization, and OptimizationofMn O x y Nanofibersfor Improved Supercapacitive Properties 451 JaiBhagwan,NageshKumarandYogeshSharma 13.1 Introduction 451 13.2 Synthesisof1DNanofibers 454 13.3 UtilizationofBinaryMnxOyNanofibersforEnergy-StorageApplications 469 13.4 FutureAspects,Challenges,andSummary 476 Acknowledgments 478 References 478 14.Fabrication of Micro/Nano-Miniaturized Platforms for Nanotheranosticsand Regenerative Medicine Applications 483 G.Praveen,NandakumarKalarikkalandSabuThomas 14.1 NanotheranosticsandRegenerativeMedicine:Introduction 484 14.2 BioartificialOrgans:Introduction 487 14.3 Micro-andNanofluidicDevices:Introduction 490 14.4 Biomimetics:Introduction 494 14.5 BiopatterningtheComplexitiesofLife:Introduction 497 14.6 BioprintingofOrgansandTissues 501 14.7 Conclusions 514 References 515 15.Recent Trends inthe Synthesis of Carbon Nanomaterials 519 MaríaM.AfonsoandJoséAntonioPalenzuela 15.1 Fullerenes 520 15.2 CarbonNanotubes 525 15.3 Graphene 529 15.4 GrapheneNanoribbons 539 15.5 CarbonDots 540 15.6 ChallengesandFuturePerspectives 543 References 544 Index 557