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Multinary Alloys Based on II-VI Semiconductors Multinary Alloys Based on II-VI Semiconductors Vasyl Tomashyk V. Ye. Lashkaryov Institute of Semiconductor Physics of NAS of Ukraine, Kyiv CRC Press Taylor & Francis Group 6000 Broken Sound Parkway NW, Suite 300 Boca Raton, FL 33487-2742 © 2016 by Taylor & Francis Group, LLC CRC Press is an imprint of Taylor & Francis Group, an Informa business No claim to original U.S. Government works Version Date: 20150721 International Standard Book Number-13: 978-1-4822-3652-1 (eBook - PDF) This book contains information obtained from authentic and highly regarded sources. Reasonable efforts have been made to publish reliable data and information, but the author and publisher cannot assume responsibility for the validity of all materials or the consequences of their use. 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Visit the Taylor & Francis Web site at http://www.taylorandfrancis.com and the CRC Press Web site at http://www.crcpress.com Contents Preface....................................................................................................................xvii Author .....................................................................................................................xix List of Symbols .......................................................................................................xxi Chapter 1 Systems Based on ZnS .........................................................................1 1.1 Zn–H–Na–Ba–O–Cl–S .............................................................1 1.2 Zn–H–Na–C–N–O–S ...............................................................1 1.3 Zn–H–Na–Sn–O–S ...................................................................1 1.4 Zn–H–Na–N–O–Cl–S ..............................................................2 1.5 Zn–H–Na–O–S .........................................................................2 1.6 Zn–H–K–C–S............................................................................2 1.7 Zn–H–K–O–S ...........................................................................2 1.8 Zn–H–Rb–O–S .........................................................................2 1.9 Zn–H–Cs–C–N–O–Re–S .........................................................3 1.10 Zn–H–Cs–O–S .........................................................................3 1.11 Zn–H–Cu–C–N–Br–S ..............................................................3 1.12 Zn–H–Ba–C–N–O–S ................................................................3 1.13 Zn–H–Cd–C–N–O–S ...............................................................4 1.14 Zn–H–Cd–C–N–S ....................................................................4 1.15 Zn–H–Cd–C–N–I–S .................................................................5 1.16 Zn–H–Hg–C–N–O–Fe–S .........................................................5 1.17 Zn–H–Hg–C–N–S ....................................................................6 1.18 Zn–H–Hg–C–N–Fe–S ..............................................................6 1.19 Zn–H–B–C–N–O–S .................................................................7 1.20 Zn–H–B–C–N–O–F–S .............................................................8 1.21 Zn–H–B–C–N–O–Cl–S ...........................................................9 1.22 Zn–H–B–C–N–S ....................................................................10 1.23 Zn–H–B–C–N–F–S ................................................................12 1.24 Zn–H–B–C–N–Cl–S ..............................................................12 1.25 Zn–H–B–C–N–Cl–F–Ni–S ....................................................13 1.26 Zn–H–B–C–N–Cl–Br–S ........................................................13 1.27 Zn–H–B–C–N–Cl–I–S ...........................................................14 1.28 Zn–H–B–C–N–Br–S ..............................................................14 1.29 Zn–H–B–C–N–I–S .................................................................15 1.30 Zn–H–Ga–C–Sn–N–S ............................................................15 1.31 Zn–H–Ga–C–Sn–N–Se–S ......................................................16 1.32 Zn–H–Ga–C–N–Se–S ............................................................17 1.33 Zn–H–In–C–N–O–S ..............................................................17 1.34 Zn–H–In–C–N–S ....................................................................18 1.35 Zn–H–Tl–O–S.........................................................................18 1.36 Zn–H–Tb–C–N–O–S ..............................................................18 v vi Contents 1.37 Zn–H–C–Si–N–O–F–S ..........................................................19 1.38 Zn–H–C–Si–N–S ....................................................................19 1.39 Zn–H–C–Si–N–F–S................................................................19 1.40 Zn–H–C–Si–N–Cl–S ..............................................................19 1.41 Zn–H–C–Si–N–I–S ................................................................20 1.42 Zn–H–C–Si–S .........................................................................20 1.43 Zn–H–C–Ge–N–O–S .............................................................21 1.44 Zn–H–C–Ge–N–S ..................................................................21 1.45 Zn–H–C–Sn–N–S ...................................................................21 1.46 Zn–H–C–N–P–O–S ................................................................22 1.47 Zn–H–C–N–P–O–Cl–S ..........................................................30 1.48 Zn–H–C–N–P–O–I–S ............................................................31 1.49 Zn–H–C–N–P–S .....................................................................31 1.50 Zn–H–C–N–P–F–S .................................................................32 1.51 Zn–H–C–N–P–F–Cl–Pt–S .....................................................33 1.52 Zn–H–C–N–P–I–S ..................................................................33 1.53 Zn–H–C–N–O–S ....................................................................34 1.54 Zn–H–C–N–O–F–S ................................................................73 1.55 Zn–H–C–N–O–F–Cl–S ..........................................................75 1.56 Zn–H–C–N–O–Cl–S ..............................................................75 1.57 Zn–H–C–N–O–Br–S ..............................................................79 1.58 Zn–H–C–N–O–I–S .................................................................80 1.59 Zn–H–C–N–O–Re–S .............................................................81 1.60 Zn–H–C–N–S .........................................................................81 1.61 Zn–H–C–N–Se–S .................................................................118 1.62 Zn–H–C–N–Se–Cl–S ...........................................................118 1.63 Zn–H–C–N–Se–Br–S ...........................................................118 1.64 Zn–H–C–N–Se–I–S ..............................................................119 1.65 Zn–H–C–N–F–S ...................................................................119 1.66 Zn–H–C–N–Cl–S .................................................................120 1.67 Zn–H–C–N–Br–S .................................................................130 1.68 Zn–H–C–N–I–S ....................................................................136 1.69 Zn–H–C–N–Mn–S................................................................141 1.70 Zn–H–C–N–Co–S ................................................................142 1.71 Zn–H–C–P–O–S ...................................................................142 1.72 Zn–H–C–P–S ........................................................................150 1.73 Zn–H–C–P–I–S .....................................................................153 1.74 Zn–H–C–As–O–S.................................................................153 1.75 Zn–H–C–As–S ......................................................................154 1.76 Zn–H–C–As–Cl–S ................................................................154 1.77 Zn–H–C–O–Se–S .................................................................154 1.78 Zn–H–C–O–S .......................................................................154 1.79 Zn–H–C–O–F–S ...................................................................159 1.80 Zn–H–C–O–Cl–S .................................................................160 1.81 Zn–H–C–Se–S ......................................................................161 1.82 Zn–H–Ge–N–S .....................................................................161 Contents vii 1.83 Zn–H–N–O–S .......................................................................161 1.84 Zn–H–V–O–S .......................................................................162 1.85 Zn–K–Rb–Sn–S ....................................................................162 1.86 Zn–K–Cs–Sn–S .....................................................................162 1.87 Zn–K–Cu–Ba–S ....................................................................162 1.88 Zn–Cu–Ag–Hg–Tl–As–Sb–S ...............................................163 1.89 Zn–Cu–Ag–Sn-S ...................................................................163 1.90 Zn–Cu–Ca–O-S ....................................................................163 1.91 Zn–Cu–Sr–O–S ....................................................................163 1.92 Zn–Cu–Hg–Tl–As–S ............................................................163 1.93 Zn–Cu–In–Mn–S ..................................................................165 1.94 Zn–Cu–Si–Sn–S....................................................................165 1.95 Zn–Cu–Ge–Fe–S ..................................................................166 1.96 Zn–Cu–Sn–Se–S ...................................................................166 1.97 Zn–Cu–Sn–Fe–S ...................................................................168 1.98 Zn–Cu–Pb–Fe–S ...................................................................169 1.99 Zn–Cu–O–Se–S ....................................................................170 1.100 Zn–Cu–O–Fe–S ....................................................................172 1.101 Zn–Cu–Mn–Fe–S .................................................................173 1.102 Zn–Mg–Mn–Fe–S .................................................................175 1.103 Zn–Ca–O–Fe–S ....................................................................175 1.104 Zn–Sr–Ge–O–S ....................................................................176 1.105 Zn–Ba–Ge–O–S ...................................................................176 1.106 Zn–Cd–C–N–S .....................................................................176 1.107 Zn–Cd–Mn–Fe–S .................................................................177 1.108 Zn–Hg–C–N–S .....................................................................177 1.109 Zn–Ga–La–O–S ....................................................................178 1.110 Zn–Tl–O–Cl–S......................................................................178 1.111 Zn–C–Pb–N–S ......................................................................178 1.112 Zn–Pb–Sb–O–S ....................................................................178 References ........................................................................................178 Chapter 2 Systems Based on ZnSe ...................................................................205 2.1 Zn–H–Na–Mg–O–Te–Mn–Fe–Se ........................................205 2.2 Zn–H–Na–C–N–O–Re–Se ...................................................205 2.3 Zn–H–Na–C–O–Se ...............................................................205 2.4 Zn–H–Na–O–Se ...................................................................205 2.5 Zn–H–K–C–Sn–O–Se ..........................................................206 2.6 Zn–H–K–O–Se .....................................................................206 2.7 Zn–H–Rb–C–O–Se ..............................................................206 2.8 Zn–H–Rb–Sn–O–Se .............................................................206 2.9 Zn–H–Rb–O–Se ...................................................................207 2.10 Zn–H–Rb–O–Cl–Se .............................................................207 2.11 Zn–H–Rb–O–Br–Se .............................................................207 2.12 Zn–H–Cs–O–Se ....................................................................207 viii Contents 2.13 Zn–H–Ag–Sn–N–Se .............................................................207 2.14 Zn–H–Ba–Sn–O–Se .............................................................208 2.15 Zn–H–B–C–N–O–Se ...........................................................208 2.16 Zn–H–B–C–N–S ..................................................................208 2.17 Zn–H–Ga–C–Ge–N–Se ........................................................208 2.18 Zn–H–Ga–C–Sn–N–O–Se ...................................................208 2.19 Zn–H–Ga–C–Sn–N–Se ........................................................209 2.20 Zn–H–Ga–C–Sn–N–Mn–Se ................................................210 2.21 Zn–H–Ga–C–N–Se ...............................................................211 2.22 Zn–H–Tl–O–Se .....................................................................211 2.23 Zn–H–C–Si–N–P–Se ............................................................211 2.24 Zn–H–C–Ge–N–Se ..............................................................212 2.25 Zn–H–C–Sn–N–O–Se ..........................................................213 2.26 Zn–H–C–Sn–N–Se ...............................................................213 2.27 Zn–H–C–N–P–Se .................................................................214 2.28 Zn–H–C–N–Sb–Se ...............................................................214 2.29 Zn–H–C–N–O–Se ................................................................215 2.30 Zn–H–C–N–O–Re–Se ..........................................................216 2.31 Zn–H–C–N–Se......................................................................217 2.32 Zn–H–C–N–Cl–Se................................................................220 2.33 Zn–H–C–N–Br–Se................................................................221 2.34 Zn–H–C–N–I–Se ..................................................................222 2.35 Zn–H–C–P–O–Se .................................................................222 2.36 Zn–H–C–P–Se ......................................................................223 2.37 Zn–H–C–O–Se .....................................................................224 2.38 Zn–H–N–O–Se .....................................................................225 2.39 Zn–H–As–O–Se ....................................................................225 2.40 Zn–K–Rb–Sn–Se ..................................................................225 2.41 Zn–Cu–Mg–Sn–Se ................................................................225 2.42 Zn–Cu–Al–Sn–Se .................................................................225 2.43 Zn–Cu–Ge–Mn–Se ...............................................................226 2.44 Zn–Cu–Ge–Fe–Se ................................................................226 2.45 Zn–Ag–Ba–O–Se ..................................................................226 2.46 Zn–Cd–C–N–Se ....................................................................226 2.47 Zn–Ga–Si–P–Se ....................................................................226 2.48 Zn–Ga–Sn–As–Se .................................................................226 References ........................................................................................228 Chapter 3 Systems Based on ZnTe ....................................................................233 3.1 Zn–H–Na–O–Te ....................................................................233 3.2 Zn–H–Cu–Mg–O–Fe–Te ......................................................233 3.3 Zn–H–Mg–O–Mn–Fe–Te .....................................................233 3.4 Zn–H–Mg–O–Fe–Te .............................................................233 3.5 Zn–H–C–Si–N–P–Te ............................................................233 3.6 Zn–H–C–Si–N–Te .................................................................234 Contents ix 3.7 Zn–H–C–Si–Te ......................................................................234 3.8 Zn–H–C–Sn–N–Te ................................................................235 3.9 Zn–H–C–Sn–N–I–Te ............................................................236 3.10 Zn–H–C–N–P–Te ..................................................................236 3.11 Zn–H–C–N–V–O–Te ............................................................237 3.12 Zn–H–C–N–O–Re–Te ..........................................................237 3.13 Zn–H–C–N–Te ......................................................................238 3.14 Zn–H–C–P–Te .......................................................................239 3.15 Zn–H–C–P–Cl–Te .................................................................240 3.16 Zn–H–N–O–Mo–Te ..............................................................240 3.17 Zn–H–O–Mo–Te ...................................................................240 3.18 Zn–Li–Ag–O–Te ...................................................................240 3.19 Zn–Cu–In–Mn–Te .................................................................240 3.20 Zn–Cu–O–Cl–Te ...................................................................241 3.21 Zn–Ag–In–Mn–Te .................................................................241 3.22 Zn–Ca–Pb–O–Te ..................................................................242 3.23 Zn–Ca–O–Co–Te ..................................................................242 3.24 Zn–Ba–O–Cl–Te ...................................................................242 3.25 Zn–Cd–O–Co–Te ..................................................................243 3.26 Zn–Pb–As–O–Te ...................................................................243 3.27 Zn–O–Br–Co–Te ...................................................................243 References ........................................................................................243 Chapter 4 Systems Based on CdS .....................................................................245 4.1 Cd–H–Na–C–N–O–S ...........................................................245 4.2 Cd–H–Na–P–O–S .................................................................245 4.3 Cd–H–K–C–N–O–S .............................................................246 4.4 Cd–H–K–P–O–S ...................................................................246 4.5 Cd–H–Cs–C–N–O–Re–S .....................................................246 4.6 Cd–H–Cs–P–O–S .................................................................246 4.7 Cd–H–Cu–C–N–Br–S ..........................................................247 4.8 Cd–H–Ba–C–N–O–S ...........................................................247 4.9 Cd–H–Hg–C–N–O–S ...........................................................247 4.10 Cd–H–Hg–C–N–S ................................................................248 4.11 Cd–H–Hg–C–N–I–S .............................................................249 4.12 Cd–H–B–C–N–O–S .............................................................249 4.13 Cd–H–B–C–N–O–F–S .........................................................249 4.14 Cd–H–B–C–N–S ..................................................................249 4.15 Cd–H–B–C–N–F–S ..............................................................252 4.16 Cd–H–B–C–N–Cl–S ............................................................252 4.17 Cd–H–B–C–N–Br–S ............................................................252 4.18 Cd–H–B–C–N–I–S ...............................................................253 4.19 Cd–H–B–C–F–S ...................................................................253 4.20 Cd–H–In–C–N–O–S ............................................................254 4.21 Cd–H–In–C–N–S ..................................................................255 x Contents 4.22 Cd–H–C–Si–N–S ..................................................................255 4.23 Cd–H–C–Si–N–I–S ..............................................................255 4.24 Cd–H–C–Ge–N–S ................................................................255 4.25 Cd–H–C–Sn–N–S .................................................................256 4.26 Cd–H–C–N–P–O–S ..............................................................256 4.27 Cd–H–C–N–P–O–Cl–S........................................................260 4.28 Cd–H–C–N–P–S ...................................................................260 4.29 Cd–H–C–N–P–Se–S .............................................................262 4.30 Cd–H–C–N–P–F–S ..............................................................263 4.31 Cd–H–C–N–P–F–Cl–Pt–S ...................................................263 4.32 Cd–H–C–N–P–Br–S .............................................................264 4.33 Cd–H–C–N–P–I–S ...............................................................264 4.34 Cd–H–C–N–P–Fe–S .............................................................264 4.35 Cd–H–C–N–As–S .................................................................264 4.36 Cd–H–C–N–O–S ..................................................................265 4.37 Cd–H–C–N–O–Se–S ............................................................290 4.38 Cd–H–C–N–O–F–S .............................................................291 4.39 Cd–H–C–N–O–Cl–S ............................................................293 4.40 Cd–H–C–N–O–Br–S ............................................................297 4.41 Cd–H–C–N–O–I–S ..............................................................299 4.42 Cd–H–C–N–O–Re–S ...........................................................300 4.43 Cd–H–C–N–S .......................................................................301 4.44 Cd–H–C–N–Se–S .................................................................327 4.45 Cd–H–C–N–Se–Cl–S ...........................................................329 4.46 Cd–H–C–N–Se–Br–S ...........................................................329 4.47 Cd–H–C–N–Se–I–S .............................................................329 4.48 Cd–H–C–N–Te–S .................................................................329 4.49 Cd–H–C–N–F–S ...................................................................329 4.50 Cd–H–C–N–Cl–S .................................................................331 4.51 Cd–H–C–N–Cl–Br–S ...........................................................339 4.52 Cd–H–C–N–Cl–I–S ..............................................................340 4.53 Cd–H–C–N–Br–S .................................................................340 4.54 Cd–H–C–N–I–S ....................................................................346 4.55 Cd–H–C–N–Fe–S .................................................................351 4.56 Cd–H–C–N–Ru–S ................................................................352 4.57 Cd–H–C–P–O–S ...................................................................352 4.58 Cd–H–C–P–O–Se–F–S ........................................................354 4.59 Cd–H–C–P–O–Cl–S .............................................................354 4.60 Cd–H–C–P–S ........................................................................355 4.61 Cd–H–C–P–Se–S ..................................................................359 4.62 Cd–H–C–P–I–S ....................................................................359 4.63 Cd–H–C–As–O–S ................................................................359 4.64 Cd–H–C–As–Se–S ...............................................................360 4.65 Cd–H–C–O–S .......................................................................360 4.66 Cd–H–C–O–Cl–S .................................................................364 4.67 Cd–H–C–O–Br–S .................................................................366

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