Multidimensional NMR Methods for the Solution State

588 Pages·2010·10.149 MB·English

by  Gareth A. Morris, James W. Emsley

Multidimensional
NMR Methods
for the Solution
State
EMR Handbooks
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NMRCrystallography
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Encyclopedia of Magnetic Resonance
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Multidimensional
NMR Methods
for the Solution
State
Editors
Gareth A. Morris
University of Manchester, Manchester, UK
James W. Emsley
University of Southampton, Southampton, UK
A John Wiley and Sons, Ltd., Publication
Thiseditionfirstpublished2010
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LibraryofCongressCataloging-in-PublicationData
MultidimensionalNMRmethodsforthesolutionstate/editors,GarethA.Morris,
JamesW.Emsley.
p.cm.
Includesbibliographicalreferencesandindex.
ISBN978-0-470-77075-7(cloth)
1. Liquids—Spectra.2.Nuclearmagneticresonancespectroscopy.3.Nuclear
magneticresonance.I.Morris,GarethA.II.Emsley,J.W.(JamesWilliam)
QC145.4.O6M852010
543’.66—dc22
2009054386
AcataloguerecordforthisbookisavailablefromtheBritishLibrary.
ISBN-13:978-0-470-77075-7
Setin9.5/11.5ptTimesbyLaserwords(Private)Limited,Chennai,India
PrintedandboundinSingaporebyMarkonoPrintMediaPteLtd
Encyclopedia of Magnetic Resonance
Editorial Board
Editors-in-Chief
RobinK.Harris RoderickE.Wasylishen
UniversityofDurham UniversityofAlberta
Durham Edmonton,Alberta
UK Canada
Section Editors
SOLID-STATE NMR & PHYSICS
MelindaJ.Duer BernardC.Gerstein
UniversityofCambridge Ames,IA
Cambridge USA
UK
SOLUTION-STATE NMR & CHEMISTRY
JamesW.Emsley GeorgeA.Gray GarethA.Morris
UniversityofSouthampton VarianInc. UniversityofManchester
Southampton PaloAlto,CA Manchester
UK USA UK
BIOCHEMICAL NMR
AnnE.McDermott TatyanaPolenova
ColumbiaUniversity UniversityofDelaware
NewYork,NY Newark,DE
USA USA
MRI & MRS
JohnR.Griffiths VivianS.Lee IanR.Young
CancerResearchUK NYULangoneMedical ImperialCollege
CambridgeResearch Center London
Institute NewYork,NY UK
Cambridge USA
UK
HISTORICAL PERSPECTIVES
EdwinD.Becker
NationalInstitutesofHealth
Bethesda,MD
USA
vi Encyclopedia of Magnetic Resonance
International Advisory Board
David M. Grant(Chairman)
University of Utah
Salt Lake City, UT
USA
Isao Ando Adriaan Bax Chris Boesch
Tokyo Institute National Institutes of Health University of Bern
of Technology Bethesda, MD Bern
Tokyo USA Switzerland
Japan
Paul A. Bottomley William G. Bradley Graeme M. Bydder
Johns Hopkins University UCSD Medical Center UCSD Medical Center
Baltimore, MD San Diego, CA San Diego, CA
USA USA USA
Paul T. Callaghan Richard R. Ernst Ray Freeman
Victoria University Eidgeno¨ssische Technische University of Cambridge
of Wellington Hochschule (ETH) Cambridge
Wellington Zu¨rich UK
New Zealand Switzerland
Lucio Frydman Maurice Goldman Harald Gu¨nther
Weizmann Institute Villebon sur Yvette Universita¨t Siegen
of Science France Siegen
Rehovot Germany
Israel
Herbert Y. Kressel C. Leon Partain Alexander Pines
Harvard Medical School Vanderbilt University Medical University of California
Boston, MA Center at Berkeley
USA Nashville, TN Berkeley, CA
USA USA
George K. Radda Hans Wolfgang Spiess Charles P. Slichter
University of Oxford Max-Planck Institute University of Illinois
Oxford of Polymer Research at Urbana-Champaign
UK Mainz Urbana, IL
Germany USA
John S. Waugh Bernd Wrackmeyer Kurt Wu¨thrich
Massachusetts Institute Universita¨t Bayreuth The Scripps Research
of Technology (MIT) Bayreuth Institute
Cambridge, MA Germany La Jolla, CA
USA USA
and
ETH Zu¨rich
Zu¨rich
Switzerland
Contents
Contributors xi
Series Preface xvii
Volume Preface xix
PartA:Principles 1
1 MultidimensionalNMR:anIntroduction
GarethA.Morris,JamesW.Emsley 3
2 MultidimensionalSpectroscopy:Concepts
RichardR.Ernst 29
3 UltrafastMultidimensionalNMR:PrinciplesandPracticeofSingle-ScanMethods
MaayanGal,LucioFrydman 43
4 FastMultidimensionalNMRbyHadamardSpectroscopy
¯
RayFreeman,EriksKupcˇe 61
5 MultidimensionalNMRbyProjection-Reconstruction
¯
RayFreeman,EriksKupcˇe 73
6 RapidMultidimensionalNMR:DecompositionMethodsandtheirApplications
MartinBilleter,DoroteyaK.Staykova 85
7 MultidimensionalCorrelationSpectroscopybyCovarianceNMR
DavidA.Snyder,RafaelBru¨schweiler 97
8 MaximumEntropyMethodsinMultidimensionalNMR
JeffreyC.Hoch,MehdiMobli 107
9 FilterDiagonalizationMethodsforTime-DomainSignals
A.J.Shaka,VladimirA.Mandelshtam 119
10 FourierTransformandLinearPredictionMethods
JensJ.Led,HenrikGesmar 131
PartB:Techniques 143
11 Two-DimensionalJ-ResolvedSpectroscopy
GarethA.Morris 145
12 COSY
DavidM.Doddrell 161
13 COSY:QuantitativeAnalysis
AlexD.Bain 167
viii Contents
14 E.COSY:DeterminationofCouplingConstants
HaraldSchwalbe,P.Schmidt,ChristianGriesinger 177
15 RelayedCoherenceTransferExperiments
PhilipH.Bolton 197
16 TOCSY
TimothyD.W.Claridge 205
17 MultipleQuantumSpectroscopyofLiquidSamples
TimothyJ.Norwood 221
18 NOESY
MichaelP.Williamson 233
19 ROESY
AdBax,StephanGrzesiek 245
20 TOCSYinROESYandROESYinTOCSY
J.Schleucher,J.Quant,S.J.Glaser,ChristianGriesinger 259
21 2DMethodsofMonitoringExchange
KeithG.Orrell 277
22 HeteronuclearShiftCorrelationSpectroscopy
ThomasT.Nakashima,R.E.D.McClung 289
23 2DMethodsfortheMeasurementofLong-RangeProton–CarbonCouplingConstants
TeodorParella 305
24 Homonuclear3DNMRofBiomolecules
RolfBoelens,RobertKaptein 315
25 3DHMQC-NOESY,NOESY-HMQC,andNOESY-HSQC
RanjithMuhandiram,LewisE.Kay 335
26 3Dand4DHeteronuclearMagneticResonance
G.MariusClore,AngelaM.Gronenborn 351
PartC:Applications 363
27 2DCarbon–HeteroelementCorrelation
StefanBerger 365
28 MultidimensionalNMRinOrganotinChemistryandCatalysis
MoniqueBiesemans,RudolphWillem 373
29 2DNMRofMoleculesOrientedinLiquidCrystallinePhases
AnilKumar 387
30 2DNMRofMoleculesOrientedinLiquidCrystals—RecentDevelopments
AnilKumar,N.Suryaprakash 401
31 LocalFieldExperimentsinLiquidCrystals
StefanoCaldarelli 435
32 MultipleQuantumSpectroscopyinLiquidCrystallineSolvents
LeslieD.Field 449
33 BiologicalMacromolecules:StructureDeterminationinSolution
KurtWu¨thrich 461
34 StructuresofLargerProteins,Protein–Ligand,andProtein–DNAComplexes
byMultidimensionalHeteronuclearNMR
G.MariusClore,AngelaM.Gronenborn 473
35 RapidMultidimensionalNMR:FastPulsingTechniquesandtheirApplicationstoProteins
BernhardBrutscher,PaulSchanda 501