MODERN PHYSIOS AND QUANTUM MEOHANIOS: ELMER E. ANDERSON, Ph.D. Chairman, D"port*ent of Physics, Clnrkson College of Technobgy Potsdarn, New York . . W. B. SAUNDERS COMPANY PHILADELPHIA LONDON TORONTO 1971 W. B. Saunders Company: West Washington Square Philadelphia, Pa. 19105 l2 Dyott Street London, WCIA lDB 1835 Yonge Street Toronto 7. Ontario Modern Physics and Quantum Mechanics sBN 0-7216-1220-2 e D7l by W. B. Saunders Company. Copyright under the International Copyright Union. All rights reseived. This book is protected by copyright. No part of it may be reproduced, stored in a relrieval system, or transmitted in any form or by any means, electronic, mechanical, photocopying, recording. or otherwise, without written permission from the publisher. Made in the United States of America. Press of W. B. Saunders Company. Library of Congress catalog card number 77-145554. Print No.: ffiffiffiffiffiffiffi This book grew out of my experience in teaching a one-year course in quantum physics given to our seniors in the physics curriculum. It is designed to bridge the gap between the descriptive course at the sophomore level and a graduate course in quantum mechanics in which formai operator methods are used freely. I have written this text because I have been unable to find a book which suits our needs, although there ate a number of excellent texts which are satisfactory for certain parts of the course. Since many diverse areas ofmodern physics have developed simultaneously, a strictly chronological presentation would not necessarily be the most logical to follow. Therefore, I have chosen to develop the ideas that I consider necessary for an understanding of quantum physics without regard to historical order and with no attempt at complete coverage of all of twentieth century physics. The use of the word "Modern" in the title is not intended to suggest the same list of topics as is included in the sophomore course bearing that name. It is assumed, in fact, that the student has previously taken such a course at the sophomore level, as well as previous or concurrent courses in classical mechanics, electromagnetic waves, and thermodynamics. Much of the material of the first four chapters should not be new to the student but is included for the sake of logical completeness in the development of quantum mechanics. Four great conceptual edifices form the principal themes for the first four chapters. These are: (l ) the special theory of relativity and some ex- amples of its role in contemporary physics ; (2) the quantum theory of radiation and the concept of the photon as a wave packet which can display both particle and wave properties; (3) the Bohr theory of the atom and the quantization of angular momentum; and (4) the representation of a particle by a wave packet and the development of a wave mechanics for the description of a particle's dynamical states. In Chapter 5, Schrddinger's wave mechanics is applied to one-dimensional problems. In that chapter the linear harmonic oscillator is solved by both the series and the operator methods in order to familiarize the student with both of these approaches. This is followed in Chapter 6 by a summary of the postulates of quantum mechanics and the development of matrix mechanics. The angular momentum operators and their eigenfunctions are introduced in Chapter 7 where they are applied to ilt tv PREFACE the hvdrogen atom. The complexities resulting from spin and its interactions u-ith orbital angular momenta are treated in Chapter B. The phenomenon of exchange degeneracy resulting from the symmetry properties of identical particles is also discussed in this chapter. Chapter 9 is an important chapter. Here some approximate methods are introduced which enable the reader to solrre large classes of real problems by means of the solutions obtained for the ideal systems in earlier chapters. In Chapter 10, approximate methods are applied to some specific atomic problems, and Chapter 11 is an introduction to quantum mechanical scattering theory. The book contains over 250 problems in addition to the numerical ex- amples which are worked at appropriate points in the text. The importance of solving a large number of problems in order to achieve a mastery of the material cannot be overemphasized. It is a pleasure to acknowledge the help of the following people and to thank them for their indispensable roles in the preparation of this book: my students over the past few years for their enthusiasm and inspiration; Agatha Hollister and Amelia Anderson for typing and preparing the manuscript; Rita Arajs for making all of the drawings; my colleagues, Professors Fred Otter and Sigurds Arajs, as well as Professors Henri Amar of Temple University, Paul H. Cutler of the Pennsylvania State University, Thomas B. W. Kirk of Harvard University, John Reading of Northeastern University, John G. Teasdale of San Diego State College, and an anonymous reviewer, for their most valuable critical comments; to John J. Hanley and others of the staff of the W. B. Saunders Co. for their assistance and encouragement; last of all, to my mother and to my family-Amy, Kenneth, Mark, Scott, Ruth, and Carl-to whom I dedicate this book. Potsdam, Ir{ew York E. E. A. wffiffiffiffiffiffiffi Sometimes the over-dramatization of the concepts of modern physics tends to give the erroneous impression that success is achieved in the physical sciences in proportion to one's rejection of what was previously regarded as "intuitively obvious." The truth is, however, that the great natural philosophers in the modern era have not rejected the obvious but have forced us to redefine the obvious after taking a closer look at the evidence. The transition from lgth to 20th century physics is replete with illustrations of redefinitions of such concepts as space, time, causality, measurement, waves, particles, and so on. Admittedly, there have been some bold postulates made by modern physicists, but these generally arose out of the compelling urge either to incorporate new experimental facts into known theory or to make existing theories consistent with each other. It is hoped that the student of modern physics will learn to appreciate its conceptual structure as well as its application to specific physical problems.