Minerals as Advanced Materials I PDF
Preview Minerals as Advanced Materials I
Minerals as Advanced Materials I Sergey V. Krivovichev (Ed.) Minerals as Advanced Materials I Editor Prof.Dr.SergeyV.Krivovichev Department ofCrystallography,FacultyofGeology St.PetersburgStateUniversity UniversityEmb.7/9 St.Petersburg Russia199034 [email protected] ISBN:978-3-540-77122-7 e-ISBN:978-3-540-77123-4 LibraryofCongressControlNumber:2007942593 (cid:1)c 2008Springer-VerlagBerlinHeidelberg Thisworkissubjecttocopyright.Allrightsarereserved,whetherthewholeorpartofthematerialis concerned,specificallytherightsoftranslation,reprinting,reuseofillustrations,recitation,broadcasting, reproductiononmicrofilmorinanyotherway,andstorageindatabanks.Duplicationofthispublication orpartsthereofispermittedonlyundertheprovisionsoftheGermanCopyrightLawofSeptember9, 1965,initscurrentversion,andpermissionforusemustalwaysbeobtainedfromSpringer.Violationsare liabletoprosecutionundertheGermanCopyrightLaw. Theuseofgeneraldescriptivenames,registerednames,trademarks,etc.inthispublicationdoesnotimply, evenintheabsenceofaspecificstatement,thatsuchnamesareexemptfromtherelevantprotectivelaws andregulationsandthereforefreeforgeneraluse. Coverillustration:Yakovenchukite-(Y),anewyttriumsilicatewithuniquemicroporousstructurediscov- eredinKhibinymassif,Kolapeninsula,Russia(KrivovichevS.V.,PakhomovskyYa.A.,IvanyukG.Yu., MikhailovaJ.A.,Men’shikovYu.P.,ArmbrusterT.,SelivanovaE.A.,MeisserN.(2007):Yakovenchukite- (Y)K3NaCaY2[Si12O30](H2O)4,anewmineralfromtheKhibinymassif,KolaPeninsula,Russia:A noveltypeofoctahedral-tetrahedralopen-frameworkstructure.AmerMineral92:1525-1530) Coverdesign:deblik,Berlin Printedonacid-freepaper 9 8 7 6 5 4 3 2 1 springer.com Foreword This book contains chapters presented at the International workshop ‘Minerals as Advanced Materials I’ that was held in the hotel of the Russian Academy of Sci- encesontheImandralake,Kolapeninsula,oneofthemostbeautifulplacesofthe Russian North, during 8–12 July, 2007. The idea of the workshop originated from thenecessityofinteractionsbetweenmineralogyandmaterialscience,includingall aspects of both these disciplines. Many important materials that dominate modern technologicaldevelopmentwereknowntomineralogistsforhundredsyears,though theirpropertieswerenotfullyrecognized.Mineralogy,ontheotherhand,needsnew impactsforthefurtherdevelopment inthelineofmodernscientificachievements, includingnovelinsightsprovidedbydevelopmentofbio-andnanotechnologiesas wellasbytheunderstandingofadeeprolethatinformationplaysintheformation ofnaturalstructuresanddefinitionofnaturalprocesses. Thematically,thebookcanbeseparatedintoseveralpartsdedicatedtosomespe- cificideas:zeolitesandmicroporousmaterials(contributionsbyArmbruster,Pekov etal.,Petersetal.,Yakovenchuketal.,Merlinoetal.,ZubkovaandPushcharovsky, Spiridonova et al., Khomyakov, Zolotarev et al., Grigorieva et al., Olysych et al., Organova et al.), crystal chemistry of minerals with important properties (chap- tersbyYakubovich,FilatovandBubnova,Krzhizhanovskayaetal.,Britvin,Siidra and Krivovichev, Selivanova et al., Karimova and Burns), mineral nanostructures (chaptersbyFerraris,Kovalevski,Voytekhovsky,Krivovichev),mineralsasactinide host matrices (chapters by Livshits and Yudintsev, Burakov et al., Tananaev), and biomineralsandbiomineralogy(chaptersbyChukanovetal.,IzatulinaandElnikov, Frank-Kamenetskaya). Thus, the chapters in this book touch almost all important pointswheremineralogyintersectswithmaterialscienceandrelateddisciplines. Wehopethattheworkshopseries‘MineralsasAdvancedMaterials’willinitiate interestingandfruitfuldiscussionsthatwillhelpustoachievedeeperunderstanding ofinorganicnaturalmatter. ThanksareduetotheSwissNationalScienceFoundationforthesupportofthe firstworkshopoftheseries. v Contents Natural Zeolites: Cation Exchange, Cation Arrangement andDehydrationBehavior........................................ 1 ThomasArmbruster Natural Ion Exchange in Microporous Minerals: Different Aspects andImplications ................................................ 7 Igor V. Pekov, Arina A. Grigorieva, Anna G. Turchkova andEkaterinaV.Lovskaya WhyDoSuper-Aluminous SodalitesandMelilitesExist,butNotso Feldspars? ..................................................... 17 LarsPeters,Nouri-SaidRahmoun,KarstenKnorrandWulfDepmeier First Natural Pharmacosiderite-Related Titanosilicates and Their Ion-ExchangeProperties ......................................... 27 ViktorN.Yakovenchuk,EkaterinaA.Selivanova,GregoryYu.Ivanyuk, YakovA.Pakhomovsky,Dar’yaV.SpiridonovaandSergeyV.Krivovichev Tobermorite 11A˚ and Its Synthetic Counterparts: Structural RelationshipsandThermalBehaviour .............................. 37 Stefano Merlino, Elena Bonaccorsi, Marco Merlini, Fabio Marchetti andWalterGarra Mixed-FrameworkMicroporousNaturalZirconosilicates.............. 45 NataliaV.ZubkovaandDmitriiYu.Pushcharovsky Chivruaiite,aNewMineralwithIon-ExchangeProperties ............. 57 Viktor N. Yakovenchuk, Sergey V. Krivovichev, Yurii P. Men’shikov, Yakov A. Pakhomovsky, Gregory Yu. Ivanyuk, Thomas Armbruster andEkaterinaA.Selivanova vii viii Contents Tl-ExchangeinZoriteandETS-4 .................................. 65 Dar’ya V. Spiridonova, Sergey N. Britvin, Sergey V. Krivovichev, ViktorN.YakovenchukandThomasArmbruster TheLargestSourceofMineralswithUniqueStructureandProperties... 71 AlexanderP.Khomyakov TrigonalMembersoftheLovozeriteGroup:ARe-investigation......... 79 Andrey A. Zolotarev, Sergey V. Krivovichev, Viktor N. Yakovenchuk, ThomasArmbrusterandYakovA.Pakhomovsky Ion-ExchangePropertiesofNaturalSodiumZirconosilicateTerskite .... 87 ArinaA.Grigorieva,IgorV.PekovandIgorA.Bryzgalov ChemistryofCancrinite-GroupMineralsfromtheKhibiny–Lovozero AlkalineComplex,KolaPeninsula,Russia........................... 91 LyudmilaV.Olysych,IgorV.PekovandAtaliA.Agakhanov On the Inhomogeneities in the Structures of Labuntsovite-Group Minerals....................................................... 95 Natalia I. Organova, Sergey V. Krivovichev, Andrey A. Zolotarev andZoyaV. Shlyukova PhosphateswithAmphotericOxocomplexes:CrystalChemicalFeatures andExpectedPhysicalProperties .................................. 101 OlgaV.Yakubovich Structural Mineralogy of Borates as Perspective Materials forTechnologicalApplications..................................... 111 StanislavK.FilatovandRimmaS.Bubnova Zeolite-Like Borosilicates from the Si-Rich Part oftheR O–B O –SiO (R=K,Rb,Cs)Systems ..................... 117 2 2 3 2 MariaG.Krzhizhanovskaya,RimmaS.BubnovaandStanislavK.Filatov StructuralDiversityofLayeredDoubleHydroxides................... 123 SergeyN.Britvin CrystalChemistryofOxocenteredChainLeadOxyhalidesandtheir ImportanceasPerspectiveMaterials ............................... 129 OlegI.SiidraandSergeyV.Krivovichev FeaturesofLow-TemperatureAlterationofTi-andNb-Phyllosilicates UnderLaboratoryConditions..................................... 143 EkaterinaA.Selivanova,ViktorN.Yakovenchuk,YakovA.Pakhomovsky andGregoryYu.Ivanyuk SilicateTubesintheCrystalStructureofManaksite .................. 153 OxanaKarimovaandPeterC.Burns Contents ix Heterophyllosilicates, a Potential Source of Nanolayers forMaterialsScience ............................................ 157 GiovanniFerraris Fullerene-Like Carbon in Nature and Perspectives of its use inScience-BasedTechnologies..................................... 165 VladimirV.Kovalevski Fullerenes as Possible Collectors of Noble, Rare, and Disseminated Elements....................................................... 169 YuriiL.Voytekhovsky NanotubesinMineralsandMineral-RelatedSystems ................. 179 SergeyV.Krivovichev NaturalandSyntheticMinerals–Matrices(Forms)forActinideWaste Immobilization ................................................. 193 TatianaLivshitsandSergeyYudintsev Behavior of Actinide Host-Phases Under Self-irradiation: Zircon, Pyrochlore,Monazite,andCubicZirconiaDopedwithPu-238.......... 209 Boris E. Burakov, Maria A. Yagovkina, Maria V. Zamoryanskaya, Marina A. Petrova, Yana V. Domracheva, Ekaterina V. Kolesnikova, Larisa D. Nikolaeva, Vladimir M. Garbuzov, Alexander A. Kitsay andVladimirA.Zirlin StabilizationofRadioactiveSalt-ContainingLiquidandSludgeWaste ontheCeramicMatrices ......................................... 219 IvanG.Tananaev TheRoleofOrganicMatterinPeralkalinePegmatites:Comparison ofMinerogeneticandTechnologicalProcesses ....................... 221 NikitaV.Chukanov,IgorV.PekovandVeraN.Ermolaeva Structure, Chemistry and Crystallization Conditions of Calcium Oxalates–TheMainComponentsofKidneyStones .................. 231 AlinaR.IzatulinaandVladislavYu.Yelnikov Structure,ChemistryandSynthesisofCarbonateApatites–TheMain ComponentsofDentalandBoneTissues ............................ 241 OlgaV.Frank-Kamenetskaya Index .............................................................253 List of Contributors AtaliA.Agakhanov FersmanMineralogicalMuseum,Moscow,Russia ThomasArmbruster InstituteofGeologicalSciences,ResearchGroup:MineralogicalCrystallography, University of Bern, Freiestr. 3, CH-3012 Bern, Switzerland, e-mail: [email protected] ElenaBonaccorsi DipartimentodiScienzedellaTerra,Universita` diPisa,ViaS.Maria53,56126 Pisa,Italy SergeyN.Britvin DepartmentofCrystallography,FacultyofGeology,St.PetersburgStateUniversity, UniversityEmb.7/9,St.Petersburg,Russia,e-mail:[email protected] IgorA.Bryzgalov FacultyofGeology,MoscowStateUniversity,119991Moscow,Russia RimmaS.Bubnova InstituteofSilicateChemistryofRussianAcademyofSciences,St.Petersburg, Russia,e-mail:Rimma [email protected] BorisE.Burakov LaboratoryofAppliedMineralogyandRadiogeochemistry,V.G.KhlopinRadium Institute, 2-nd Site, KIRSI-branch, 1, Roentgen Street, 197101 St. Petersburg, Russia,e-mail:[email protected] PeterC.Burns DepartmentofCivilEngineering andGeologicalSciences,UniversityofNotre Dame,156FitzpatrickHall,NotreDame,IN46556-0767,USA xi xii ListofContributors NikitaV.Chukanov Institute of Problems of Chemical Physics Russian Academy of Sciences, Chernogolovka,Moscowregion,Russia,e-mail:[email protected] WulfDepmeier Universita¨tKiel,InstitutfuerGeowissenschaften,Olshausenstrasse40,D-24098 Kiel,Germany YanaV.Domracheva LaboratoryofAppliedMineralogyandRadiogeochemistry,V.G.KhlopinRadium Institute, 2-nd Site, KIRSI-branch, 1, Roentgen Street, 197101 St. Petersburg, Russia VeraN.Ermolaeva InstituteofGeochemistryandAnalyticalChemistry,119991Moscow,Russia GiovanniFerraris Dipartimento di Scienze Mineralogiche e Petrologiche, Universita` di Torino – Istituto di Geoscienze e Georisorse, CNR – Via Valperga Caluso 35, I-10125 Torino,Italy,e-mail:[email protected] StanislavK.Filatov Department of Crystallography, St. Petersburg State University, St. Petersburg, Russia,e-mail:fi[email protected] WalterGarra Dipartimento di Chimica e Chimica Industriale, Universita` di Pisa, Via Risorgimento35,56126Pisa,Italy VladimirM.Garbuzov LaboratoryofAppliedMineralogyandRadiogeochemistry,V.G.KhlopinRadium Institute, 2-nd Site, KIRSI-branch, 1, Roentgen Street, 197101 St. Petersburg, Russia ArinaA.Grigorieva FacultyofGeology,MoscowStateUniversity,119991Moscow,Russia,e-mail: [email protected] GregoryYu.Ivanyuk GeologicalInstitute,KolaScienceCentreoftheRussianAcademyofSciences, Apatity,Russia,e-mail:[email protected] AlinaR.Izatulina DepartmentofCrystallography,FacultyofGeology,St.PetersburgStateUniversity, UniversityEmb.7/9,St.Petersburg,Russia,e-mail:[email protected] OxanaKarimova DepartmentofMineralogy,InstituteofGeologyofOreDepositsRussianAcademy ofSciences,35Staromonetny,119017Moscow,Russia,e-mail:[email protected]
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