Christian Schneider Light in the World of Nanotechnology A Comprehensible Introduction to the Basics and Applications essentials Springer essentials Springer essentials provide up-to-date knowledge in a concentrated form. They aim to deliver the essence of what counts as “state-of-the-art” in the cur- rent academic discussion or in practice. With their quick, uncomplicated and comprehensibleinformation,essentialsprovide: (cid:129) anintroductiontoacurrentissuewithinyourfieldofexpertise (cid:129) anintroductiontoanewtopicofinterest (cid:129) aninsight,inordertobeabletojoininthediscussiononaparticulartopic Available in electronic and printed format, the books present expert knowledge fromSpringerspecialistauthorsinacompactform.Theyareparticularlysuitable foruseaseBooksontabletPCs,eBookreadersandsmartphones.Springeressen- tials form modules of knowledge from the areas economics, social sciences and humanities, technology and natural sciences, as well as from medicine, psycho- logy and health professions, written by renowned Springer-authors across many disciplines. More information about this subseries at https://link.springer.com/bookseries/ 16761 Christian Schneider Light in the World of Nanotechnology A Comprehensible Introduction to the Basics and Applications ChristianSchneider TUKaiserslauternFachbereichPhysik Kaiserslautern,Germany ISSN2197-6708 ISSN2197-6716 (electronic) essentials ISSN2731-3107 ISSN2731-3115 (electronic) Springeressentials ISBN978-3-658-33069-9 ISBN978-3-658-33070-5 (eBook) https://doi.org/10.1007/978-3-658-33070-5 ©SpringerFachmedienWiesbadenGmbH,partofSpringerNature2022 This work is subject to copyright. All rights are reserved by the Publisher, whether the whole or part of the material is concerned, specifically the rights of reprinting, reuse of illustrations, recitation,broadcasting,reproductiononmicrofilmsorinanyotherphysicalway,andtransmission orinformationstorageandretrieval,electronicadaptation,computersoftware,orbysimilaror dissimilarmethodologynowknownorhereafterdeveloped. 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Theregisteredcompanyaddressis:Abraham-Lincoln-Str.46,65189Wiesbaden,Germany essential WhatYou Can Find in this (cid:129) Howlightinteractswithmatter (cid:129) Whatmakesthephysicsofthenanoworldspecial (cid:129) Hownanostructurescanbeproduced (cid:129) Aselectionofnanotechnologicalapplications (cid:129) Newideasfromresearchontheuseofnanotechnology v Preface Only 100 years ago, Max Planck—one of the co-founders of quantum mecha- nics—was advised not to study physics, since everything important had already beenresearched.Buteventodaywestillliveinanexcitingphysicaltime!Nobel prizes are awarded for inventions such as the CCD sensor or the blue light- emitting diode, and discoveries such as the Higgs boson or gravitational waves showthatphysicsresearchisbynomeansatanend. Today,theadvanceintoamicroscopicallysmallworldallowsevernew,some- times groundbreaking discoveries and inventions. A good example of this is nanotechnology. In the first chapter of this book, I would like to show you the physical principles on which nanotechnological applications are based. In the nextchapter,Iwillfirstdiscussmethodsforproducingnanostructures.Afterward, some exemplary selected applications are presented, ranging from those already activelyusedtothosestillinresearch. Withthisbook,youcanembarkonajourneyintotheworldofnanotechnology, gainaninsightintotheresultingpossibilitiesandperhapsevenlearnaboutthings familiarfromyoureverydaylifefromadifferentperspective! Iwishyoumuchpleasurewiththisessential andexcitingfieldofresearch! ChristianSchneider vii Contents 1 Introduction ................................................... 1 2 FundamentalsofLight-BasedNanotechnology .................... 3 2.1 WhatisLight? ............................................. 3 2.2 FromIndividualAtomstoSolidBodies ....................... 6 2.3 TheWorldisColorful:ResonancesandMieTheory ............ 10 3 ProductionofNanostructures ................................... 15 3.1 ElectronBeamLithography ................................. 15 3.2 FocusedIonBeam(FIB)Milling ............................. 17 3.3 ChemicalSynthesis ........................................ 18 4 Applications ................................................... 21 4.1 StainedGlassWindows ..................................... 21 4.2 DiagnosisandTherapy:UseofNanoparticlesinMedicine ...... 25 4.3 ElectricityfromLight:NanotechnologyinSolarCells .......... 28 4.4 TheColorfulWorldofPlasmonsforDigitalApplications ....... 33 5 SummaryandOutlook ......................................... 37 References ........................................................ 41 ix 1 Introduction In recent decades, there has been an increasing trend toward miniaturization of components.Thelecture“There’sPlentyofRoomattheBottom”1 bytheAmeri- canphysicistRichardFeynmanisoftencitedasthefatherofthisidea(Feynman n.y.).In1959,Feynmandescribedhowthe“downwardleeway”—i.e.,themicros- copic range—can be used. He calculated, for example, that with the help of nanotechnology (a word he did not use throughout his presentation), the entire information available worldwide in the form of books (approximately 24 million books)couldbestoredinacubewithanedgelengthofhalfamillimeter. These then visionary ideas have now partly become reality and nanotech- nology is part of our everyday life. Nano—Greek for “dwarf” —is incredibly small: 1 nanometer (nm) is 10−9 m—that is, one billionth of a meter or mil- lionth of a millimeter. One nanometer to the diameter of an orange is like the diameter of an orange to that of the earth! In the field of basic research, nano- technologyiscurrentlyverybig:theFederalMinistryofEducationandResearch (Bundesministerium für Bildung und Forschung, BMBF) alone spends around e220 million annually on research and development in the field of nanotechno- logy. According to the “nano.DE Report 2013” (Federal Ministry of Education and Research 2013), which was also published by the BMBF, the turnover of Germannanotechnologycompaniesin2013wasapproximatelye15billion. Nanotechnology is therefore currently experiencing a boom—new types of effectsthatpromiseinterestingandversatiletechnologicalapplicationsareemer- ging.Despitetheriseofnanotechnologyinthelast50years,thefirsteffectsbased on it reach far back into the Middle Ages, where alchemists used gold nanopar- ticles to color the windows in churches. However, a physical description of this effectbecamepossibleforthefirsttimeatthebeginningofthetwentiethcentury, 1German:EsgibtvielSpielraumnachunten. ©SpringerFachmedienWiesbadenGmbH,partofSpringerNature2022 1 C.Schneider,LightintheWorldofNanotechnology,essentials, https://doi.org/10.1007/978-3-658-33070-5_1 2 1 Introduction after James Clerk Maxwell presented his equations for describing light waves. Based on these equations, the physicist Gustav Mie developed a theory to des- cribe the light absorption of metallic nanoparticles in his article “Contributions totheopticsofturbidmedia,especiallycolloidalmetalsolutions”(“Beiträgezur Optik trüber Medien, speziell kolloidaler Metallösungen”) (Mie, 1908), which is knowntodayasthe“Mietheory.” Itishopedthatnewfindingsinnanotechnologywillnotonlyleadtoaminiatu- rizationofexistingcomponents,butalsoabovealltoimprovementsinmanyareas of daily life, ranging from medical analysis and treatment methods, electronics, sensorandmeasurementtechnologytoenergytechnology,wherenanotechnology isused,amongotherthings,toincreasetheefficiencyofsolarcells. Nanotechnology is thus not a science limited to one subject area of physics, but is used in a wide variety of research and application areas. Therefore, this text can only deal with a partial aspect of nanotechnology. Thus, the following chapters will deal with various exciting effects of the interaction of light with nanoparticles, which could perhaps revolutionize our lives in various areas in a fewyears.