Lecture Notes in Physics 953 Werner Ebeling Thorsten Pöschel Lectures on Quantum Statistics With Applications to Dilute Gases and Plasmas Lecture Notes in Physics Volume 953 FoundingEditors WolfBeiglböck,Heidelberg,Germany JürgenEhlers,Potsdam,Germany KlausHepp,Zürich,Switzerland Hans-ArwedWeidenmüller,Heidelberg,Germany SeriesEditors MatthiasBartelmann,Heidelberg,Germany PeterHänggi,Augsburg,Germany MortenHjorth-Jensen,Oslo,Norway MaciejLewenstein,Barcelona,Spain AngelRubio,Hamburg,Germany ManfredSalmhofer,Heidelberg,Germany WolfgangSchleich,Ulm,Germany StefanTheisen,Potsdam,Germany DieterVollhardt,Augsburg,Germany JamesD.Wells,AnnArbor,MI,USA GaryP.Zank,Huntsville,AL,USA The Lecture Notes in Physics The series Lecture Notes in Physics (LNP), founded in 1969, reports new devel- opmentsin physicsresearch and teaching-quicklyand informally,but with a high qualityand the explicitaim to summarizeand communicatecurrentknowledgein anaccessibleway.Bookspublishedinthisseriesareconceivedasbridgingmaterial between advanced graduate textbooks and the forefront of research and to serve threepurposes: (cid:129) to be a compact and modern up-to-date source of reference on a well-defined topic (cid:129) to serve as an accessible introduction to the field to postgraduate students and nonspecialistresearchersfromrelatedareas (cid:129) to be a source of advanced teaching material for specialized seminars, courses andschools Bothmonographsandmulti-authorvolumeswillbeconsideredforpublication. 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Proposalsshouldbe sent to a memberof the EditorialBoard, ordirectly to the managingeditoratSpringer: LisaScalone SpringerNature PhysicsEditorialDepartment Tiergartenstrasse17 69121Heidelberg,Germany [email protected] Moreinformationaboutthisseriesathttp://www.springer.com/series/5304 ¨ Werner Ebeling (cid:129) Thorsten Poschel Lectures on Quantum Statistics With Applications to Dilute Gases and Plasmas 123 WernerEbeling ThorstenPöschel FBPhysik Friedrich-Alexander-Universität HumboldtUniversita¨tzuBerlin Erlangen-Nürnberg Berlin,Germany Erlangen,Germany ISSN0075-8450 ISSN1616-6361 (electronic) LectureNotesinPhysics ISBN978-3-030-05733-6 ISBN978-3-030-05734-3 (eBook) https://doi.org/10.1007/978-3-030-05734-3 LibraryofCongressControlNumber:2019933558 ©SpringerNatureSwitzerlandAG2019 Thisworkissubjecttocopyright.AllrightsarereservedbythePublisher,whetherthewholeorpartof thematerialisconcerned,specificallytherightsoftranslation,reprinting,reuseofillustrations,recitation, broadcasting,reproductiononmicrofilmsorinanyotherphysicalway,andtransmissionorinformation storageandretrieval,electronicadaptation,computersoftware,orbysimilarordissimilarmethodology nowknownorhereafterdeveloped. Theuseofgeneraldescriptivenames,registerednames,trademarks,servicemarks,etc.inthispublication doesnotimply,evenintheabsenceofaspecificstatement,thatsuchnamesareexemptfromtherelevant protectivelawsandregulationsandthereforefreeforgeneraluse. Thepublisher,theauthorsandtheeditorsaresafetoassumethattheadviceandinformationinthisbook arebelievedtobetrueandaccurateatthedateofpublication.Neitherthepublishernortheauthorsor theeditorsgiveawarranty,expressorimplied,withrespecttothematerialcontainedhereinorforany errorsoromissionsthatmayhavebeenmade.Thepublisherremainsneutralwithregardtojurisdictional claimsinpublishedmapsandinstitutionalaffiliations. ThisSpringerimprintispublishedbytheregisteredcompanySpringerNatureSwitzerlandAG Theregisteredcompanyaddressis:Gewerbestrasse11,6330Cham,Switzerland Preface In spite of the dominatingimportance of solids and liquids in our life, it is a fact that most of the matter in our universeoccursin the state of gas and plasma. The overwhelming part of this matter exists under extreme conditions. Therefore, the physicsofgasesandplasmasisafieldofgrowinginterest.We believethatweare just at the beginning of the exploration of the world beyond the narrow window of experience given by the state of our planet. Thus, the deeper reason for the growinginterestinthephysicsofgasesandplasmasisthedominatingroleofthis stateofmatterintheuniverse.Thesubjectofresearchisfundamentalphysicsand in particular the quantum-statistical thermodynamics of states of matter, starting from rare gases and ending with plasma states. We are deeply convinced that the thermodynamics and quantum statistics are still the solid foundation on which even the most advanced research is operating. It remains our conviction that in spite of a flood of modern concepts, the traditional concepts of thermodynamics and statistics with terms such as temperature, pressure, energy, and entropy and the theory developed by Planck, Einstein, Nernst, Saha, and other pioneers are fundamentaltothefield.Thebodyofthesenotesisbasedonlecturesatuniversities andpresentationsatseminarsandconferences.Inparticular,theselecturenotesare based on the lectures on quantum statistics and plasma physics given by Werner EbelingattheUniversityofRostockbetween1970and1979andattheHumboldt UniversityofBerlinbetween1980and2001,includingshorterguestlecturesatthe Universities Paris VI 1977, Minneapolis 1986, Moscow 2005, and Krakow 2008. The body of the text is based on the last full two-semester course on quantum statistics held jointly by Werner Ebeling and Thorsten Pöschel at the Humboldt UniversityofBerlin,assistedbyseveralformercoworkerssuchasAndreasFörster, BurkhardMilitzer,LutzMolgedey,andWaldemar Richertandbyseveralstudents such as Jörn Dunkel, Hendrik Hache, Stefan Hilbert, Dirk Holste, Thomas Pohl, MichaelSpahn,andothers.Thistextisbasedonthenotesincludingofthecomplete lecturewrittendownbyThorstenPöschelaswellasseverallaterrevisions. Following the personal interests of the authors and the traditions of quantum statisticalthermodynamicsinBerlinandRostock,weconcentrateonthefundamen- tals and applications to gases and plasmas. This is in contrast to most textbooks v vi Preface andmonographsonquantumstatisticswhichrevealsomebiastocondensedmatter and in particular to solid state systems. We believe that the focus on gases and plasmas corresponds to trends in research evidenced, e.g., by several recent large internationalresearchprojectsandconferences. Thisbookiswrittenonanintermediatelevel,thatis,mostofitscontentsshould be accessible for undergraduate and graduate students, while a few results might be on a more advanced level and, thus, addressed to young researchers in the field. Readersinterested in additionalinformation,in particular also on numerical methods and extreme states of matter, are referred to a monographby one of the current authors (W.E.) together with V.E. Fortov and V. Filinov which appeared recently in Springer’s “Series in Plasma Science and Technology” (Ebeling et al. 2017). On many occasions, the text contains historical remarks on the roots of quan- tum statistics. There are two reasons why we decided to include this historical material: – Thefirstreasonisrelatedtothegeniusloci:Infact,alargepartofthebookgoes backtolecturesgiveninBerlinwheremanyfundamentalsofquantumstatistics weredevelopedbetween1900and1932. – We are convinced—and this is based on a long experience in lecturing—that studentsarestronglymotivatedbylookingbacktothehistoryofthedevelopment ofourscience. The spirit of this textbookis influenced by meetings and discussions with several pioneersofquantumstatisticalthermodynamics,such asAlexanderA. Abrikosov, Berni Alder, Nikolay N. Bogolyubov, Alexander S. Davydov, Hans Falkenhagen, MichaelFisher, VitaliL. Ginzburg,GünterKelbg,HughDeWitt, and inparticular Yuri L. Klimontovich. Further, we have to thank our colleagues in Berlin, in particular Dietmar Ebert, Wolfgang Muschik, and Lutz Schimansky-Geier,and in Rostock,inparticularKlausKilimann,Wolf-DietrichKraeft,DietrichKremp,and GerdRöpke,aswellasPeterHänggifromAugsburgforcollaboration,advice,and discussions. Berlin,Germany WernerEbeling Erlangen,Germany ThorstenPöschel Summer2018 Reference Ebeling,W.,V.E.Fortov,andV.S.Filinov.2017.QuantumStatisticsofDenseGases and Nonideal Plasmas. Springer Series in Plasma Science and Technology. Springer. Contents 1 BasicPhysicsofGasesandPlasmas ....................................... 1 1.1 MatterinFormofGasesandPlasmas ................................. 1 1.2 BasicPhysicsofGases.................................................. 2 1.2.1 ClassicalGasLaws............................................. 2 1.2.2 Third Law of Thermodynamicsand the Roots ofQuantumStatistics........................................... 5 1.3 BasicPhysicsofPlasmas............................................... 8 1.3.1 CoulombInteractionsandIonizationEquilibrium............ 8 1.3.2 DifferentPlasmaStatesonEarth............................... 12 References..................................................................... 16 2 ElementsofQuantumStatisticalTheory.................................. 19 2.1 Many-BodyQuantumTheory.......................................... 19 2.1.1 QuantumStates ................................................. 19 2.1.2 IdentityandSymmetry ......................................... 24 2.2 QuantumDynamicsofManyParticles................................. 27 2.2.1 SchrödingerEquation........................................... 27 2.2.2 PureandMixedEnsembles .................................... 32 2.3 StandardApproximationsforMany-ParticleStates................... 35 2.3.1 Hartree-FockApproximation .................................. 35 2.3.2 Born-OppenheimerApproximation,VirialTheorem andCoulombStability.......................................... 36 2.3.3 Thomas-FermiTheoryofMulti-ElectronAtoms ............. 38 2.4 QuantumStatisticalEnsembleTheory................................. 41 2.4.1 MicrocanonicalandCanonicalEnsembles.................... 41 2.4.2 GrandCanonicalEnsembles ................................... 42 2.5 TheoryofFluctuationsandRelaxationProcesses..................... 44 2.5.1 Einstein-OnsagerRelaxationTheory.......................... 44 2.5.2 Correlations,Spectra,andSymmetryRelations............... 49 References..................................................................... 52 vii viii Contents 3 IdealQuantumGases........................................................ 55 3.1 QuantumStatisticsofOscillatorandPhononGases .................. 55 3.1.1 EinsteinModelofOscillationsinCrystals .................... 55 3.1.2 DebyeTheoryofPhononExcitationsinLattices ............. 57 3.2 StatisticsofBose-EinsteinandFermi-DiracGases.................... 58 3.2.1 DevelopmentoftheQuantumStatisticsofGases............. 58 3.2.2 GasesasParticleSystemswithAdditiveHamiltonian........ 61 3.3 Fermi-andBoseDistributions.......................................... 62 3.3.1 Bose-EinsteinGases............................................ 62 3.3.2 Fermi-DiracGases.............................................. 63 3.4 ThermodynamicsPropertiesofBose-EinsteinGases ................. 64 3.5 BlackBodyRadiationandRelativisticGases ......................... 70 3.5.1 Planck’sLawofRadiation ..................................... 70 3.5.2 RadiationasaRelativisticGas................................. 74 3.6 ThermodynamicFunctionsofFermiGases............................ 75 3.6.1 TheIdealFermiGas............................................ 75 3.6.2 FermiGasesintheHigh-andLow-TemperatureLimits...... 76 3.7 Density-DependentFermiGasFunctions.............................. 79 3.7.1 ExpansionsforWeaklyDegeneratedFermiGases............ 79 3.7.2 ThermodynamicsinFullDensityRange ...................... 81 3.8 Hartree-FockTheoryofWeaklyInteractingElectronGases.......... 83 References..................................................................... 88 4 DensityOperatorsandOtherToolsofQuantumStatistics ............. 91 4.1 DensityMatricesandOperators........................................ 92 4.1.1 DensityMatrices................................................ 92 4.1.2 vonNeumann’sDensityOperatorsandTimeEvolution...... 94 4.1.3 MaximumEntropyPrincipleandThermodynamic Functions........................................................ 100 4.2 RepresentationsinCoordinateSpaceandTwo-TimeFunctions...... 103 4.2.1 CoordinateRepresentationsandBlochEquations ............ 103 4.2.2 Two-TimeDensityOperators .................................. 108 4.3 Bogolyubov’sReducedDensityOperators ............................ 109 4.4 Slater-,Wigner-andKlimontovichRepresentations.................. 111 4.4.1 SlaterRepresentations.......................................... 112 4.4.2 Wigner-Representation......................................... 113 4.4.3 Klimontovich’sMicroscopicDensity.......................... 114 4.5 DensityFunctionals,VirialTheoremsandStability................... 116 4.5.1 Kohn-ShamandThomas-FermiFunctionals.................. 116 4.5.2 CoulombStabilityandVirialTheorem........................ 118 4.6 SecondQuantization.................................................... 119 4.6.1 OccupationNumberRepresentations.......................... 119 4.6.2 SecondQuantization............................................ 123 4.6.3 KlimontovichOperatorinSecondQuantization .............. 125 Contents ix 4.7 Green’sFunctions....................................................... 126 4.7.1 DefinitionandRelationsforGreen’sFunctions............... 126 4.7.2 ThermodynamicsandGreen’sFunctions...................... 129 4.8 PairBoundStatesandBethe-SalpeterEquation....................... 134 References..................................................................... 138 5 RealGasQuantumStatistics ............................................... 141 5.1 ClusterExpansionsforRealGases..................................... 141 5.2 SlaterFunctionsandVirialCoefficients ............................... 146 5.2.1 GeneralDensityExpansions ................................... 146 5.2.2 SlaterSumsforPairCorrelations.............................. 148 5.3 TheSecondVirialCoefficient.......................................... 149 5.3.1 VirialCoefficientIncludingExchangeEffects................ 149 5.3.2 Beth–UhlenbeckMethodforNon-associatingGases......... 153 5.4 EquationofStateforGaseswithDeepBoundStates................. 154 5.4.1 FugacityExpansions............................................ 154 5.4.2 ChemicalPicture................................................ 159 5.5 HeliumandOtherQuantumGasesatLowTemperature.............. 161 5.5.1 VirialExpansionforHelium ................................... 161 5.5.2 PhaseTransitionsinLow-TemperatureGases................. 162 5.6 WeaklyInteractingQuantumGases.................................... 164 5.6.1 BlochEquation ................................................. 164 5.6.2 SlaterFunctionandFreeEnergy............................... 167 References..................................................................... 169 6 QuantumStatisticsofDilutePlasmas ..................................... 171 6.1 BasicPhysicsofPlasmas............................................... 171 6.1.1 ScreeningandLatticeFormationinCoulombSystems....... 171 6.1.2 TheDivergenceofthePartitionFunction ..................... 175 6.2 PairCorrelationsonNon-degeneratePlasmas......................... 180 6.2.1 DensityMatrixofPairs......................................... 180 6.2.2 MethodofEffectivePotentials................................. 185 6.3 ThermodynamicsoftheClassicalElectronGasandQuantum Corrections.............................................................. 190 6.3.1 ClassicalBogolyubovExpansions............................. 190 6.3.2 QuantumCorrections........................................... 192 6.4 ScreeningandThermodynamicFunctionsofNon-degenerate Plasmas.................................................................. 193 6.4.1 Debye-HückelScreening....................................... 193 6.4.2 RingFunctions.................................................. 195 6.5 ThePairBoundStateContributions.................................... 196 6.5.1 Mean-MassApproximation—SymmetricalPlasmas ......... 196 6.5.2 TheSecondVirialCoefficientforGeneralPlasmas........... 200