KIRK'S FIRE INVESTIGATION SEVENTH EDITION John D. DeHaan David J. Icove _ t KIRK'S FIRE INVESTIGATION /-■aft'.*:" JohnD. Ph.D. Fire-Ex ForensicSk Inc VilkjOb CalHomia David J. kove* Ph.D^ P.E. The University of'fennessee KiK»cville« Tennessee Pearson Boston Columbus Indianapolis New York San Francisco Upper Saddle River Amsterdam Cape Town Dubai London Madrid Milan Munich Paris Montreal Toronto Delhi Mexico City Sao Paulo Sydney Hongkong Seoul Singapore Taipei Tokyo - 1 r ■ — ,-vj>Jvn|® , , , .' !-r««i ^*‘y’r \ .V . .. 4uci* ^qo^H Vi. ,rjfi uiif l^f/«.HU fwrj v<rLf42iia _ '. ■■ *^ J '-^’r'' ' ' . '■* ■ ||g .< »* • - .' <^’'••11 tr*i<i’,4^ ‘4ttnl—^Uri> Mi <l3(Tl.iM V< < y^O<Tpm M<a'' ■ -• iI''!. .. \\))^^ttil- •*•’' <-■.1! n!«ij;N> -, -.oiuitKiq lliinr? ? ' * . ?".'t .. ^ir.;,-f ;i '• ••'' ^■„ .^<-'AAanrrttiAl,!! ;■ . -:■• ‘ ’ ^ . . *'' i__ [»> '» ■ ? * . *'■ * ** •*r>^ *1^ , ♦ ./ ’•■ i -n • -* - 'M* i*iK' v-»? ; nw ►-• *1''- *^'t f’ ,-jvijiii>^ r ti ■fAr* ''.- ■ ir^ '* wJl* . I ji^' ' •!. ■i^TVr.'ii' ■|‘» •t/ ri 'V ■?* -I*!"*'. = -- rr 4«''tt ••''**VVti ‘ ■ -f ^-* ^J;IA II ■■ ;: -i^ ■ .% i'-'• sTt 4y 1 ‘ "' '~.J'»*/** -■*,* ;■ ' ■-£ Vi. «^ <;Yi|ij|f' - w'i’tiMa:-.' ^ tr- ^ -wm - ■ -» '••• --•.»» ^ ^ ^ I « ■ ^ ^ * t** “ ■ » C • »• ..uuPP ffMliif(cibS •• ■■ *.■ -►•■'* <* ■■■'■ i-^K<i y!:■ 'i . •■^ ■■■•»'* “-j*n’■■' >‘ - «.:■ •\ * ._•< -.<.4 - '.-"••■.'i l-'J '.■', ' ’i? '.< ' <■ • . *' ' '«l / • -a.^ ' ■*. ,. ' . . • ■ "•' ■•- ■ ■* - ■*.»..• j • . ^ -‘f—® ■ V; ? - > i-•'■■■V«— ’- ■-.vi - .•• * ■ •% !•, l-^ 4 1 • If* . ;» .^ , -t' .'^ - .c^uics r •A .’- r “ '-'iH* ■ ■• ' "V • ...^■. •*.,•♦•.,^*^ .• -•■•■♦ y-./;?-. -.r«i^- t, * M^' "* ‘;■, -rpfutlflrj^ ■*» -.V* t‘•• w> ,■♦ » |i |•5t . c-A r ■ -.■ ftli * ».'4 ^1 r « *Va.^* • « -* dTt^- ■- ■* # • *!-■ ■•■ f - r .’U^- ;4: . » M ^ -T • •, » V1 A ” - • •^H 7.,, ■ ' *■ ' r ■ . tMl.*; ., !H? r * ^ 1 • ■U ^** -Miftf' i un>«? -ir' •, -r T^:fl ■ - -i i’’, ■'•- '■ - -^t *•? ..' ’ /»i pi‘, --Ki y- * Y, . , *'' B. • Y*.'1 .* '4* n; \ i ''<'ts^ -'' ' *%; ' ill * Tt ■ .w ' ■ »•_*-.> -'W CONTENTS J Preface xxiii Acknowledgments xxvii About the Authors xxxi NFPA 1033 Correlation Matrix xxxii Fire and Emergency Services Higher Education (FESHE) Grid xxxiv Chapter 1 introduction 1 Fire Investigation 2 The Fire Problem 4 Fire Statistics in the United States 4 Fire Statistics in the United Kingdom 5 Role of the Fire Investigator in Accurately Reporting the Causes of Fires 5 The Detection of Incendiary Fires 6 Reporting Arson as a Crime 6 Problems Associated with Estimating Incendiary Fires 8 Scientifically Based Fire Investigation 10 Comprehensive Methodologies for Fire Investigation 10 The Scientific Approach to Fire Investigation 11 Applying the Scientific Method 11 Steps in the Scientific Method 12 Levels of Confidence 15 Legal Opinions Regarding Science in Investigation 16 Chapter Review 17 Review Questions 17 References 17 Chapter 2 The Elementary Chemistry of Combustion 19 Elements, Atoms, and Compounds 20 The Oxidation Reaction 21 Carbon Compounds 22 Other Elements 22 Organic Compounds 23 Hydrocarbons 23 Petroleum Products 25 Carbohydrates 26 Pyrolysis of Organics 28 Conclusions about Organic Compounds 28 State of the Fuel 28 Significance of State of Fuel 29 VII Difficulty in Classifying Some Hydrocarbons 29 Solids 30 Liquids 30 Chapter Review 31 Summary 31 Review Questions 31 References 31 Chapter 3 Fundamentals of Fire Behavior and Building Construction 32 Basic Combustion 33 Flaming Fire 34 Structure of Flames 36 Smoldering Fire 38 Explosive Combustion 41 Heat 42 Heat and the Rate of Reaction 42 Heat and Temperature 43 Heat Release Rate 43 Heat Transfer and Heat Flux 45 Direct Flame Impingement 50 Flame Plume 51 Sequence of a Room Fire 54 Beginning or Incipient Stage 54 Growth, a Free-Burning Stage 56 Fire Growth to Flashover 56 Post-Flashover Stage 61 Decay Stage 62 Flow of Hot Gases 63 Effects of Environmental Conditions 65 Temperature 65 Humidity 66 Wetness of Fuel (Fuel Moisture Content) 67 Wind 68 Oxygen Content 68 Elements of Building Construction 69 Structural Shell 69 Fire Resistance Ratings 72 Internal Structure 73 Chapter Review 82 Summary 82 Review Questions 82 References 82 viii Contents