Ionic liquids : current state and future directions

326 Pages·2017·40.028 MB·English

by  Scurto, Aaron M., Shiflett, Mark B

Ionic Liquids:
Current State and Future Directions

1250
ACS SYMPOSIUM SERIES
Ionic Liquids:
Current State and Future Directions
Mark B. Shiflett, Editor
The University of Kansas
Lawrence, Kansas
Aaron M. Scurto, Editor
The University of Kansas
Lawrence, Kansas
Sponsored by the
ACSDivisionofIndustrialandEngineeringChemistry
AmericanChemicalSociety,Washington,DC
DistributedinprintbyOxfordUniversityPress
LibraryofCongressCataloging-in-PublicationData
Names:Shiflett,MarkB.,editor.|Scurto,AaronM.,editor.|American
ChemicalSociety.DivisionofIndustrialandEngineeringChemistry.
Title:Ionicliquids:currentstateandfuturedirections/MarkB.
Shiflett,editor,TheUniversityofKansas,Lawrence,Kansas,AaronM.
Scurto,editor,TheUniversityofKansas,Lawrence,Kansas;sponsoredby
theACSDivisionofIndustrialandEngineeringChemistry.
Description:Washington,DC:AmericanChemicalSociety,[2017]|Series:ACS
symposiumseries;1250|Includesbibliographicalreferencesandindex.
Identifiers:LCCN2017035029(print)|LCCN2017039058(ebook)|ISBN
9780841232129(ebook)|ISBN9780841232136
Subjects: LCSH:Ionicsolutions.
Classification:LCCQD561(ebook)|LCCQD561.I56872017(print)|DDC
541/.372--dc23
LCrecordavailableathttps://lccn.loc.gov/2017035029
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Foreword
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Contents
Preface.............................................................................................................................. ix
1. IonicLiquids:CurrentStateandFutureDirections............................................ 1
MarkB.ShiflettandAaronM.Scurto
Applications
2. TranslationalResearchfromAcademiatoIndustry:FollowingthePathway
ofGeorgeWashingtonCarver .............................................................................. 17
OleksandraZavgorodnya,JuliaL.Shamshina,PaulaBerton,andRobinD.Rogers
3. CurrentandFutureIonicLiquidMarkets.......................................................... 35
ThomasJ.S.Schubert
Materials
4. PhotopolymerizationofAlkyl-andEther-FunctionalizedCoordinatedIonic
LiquidMonomers................................................................................................... 69
JohnW.Whitley,MichaelT.Burnette,ShellbyC.Benefield,andJasonE.Bara
5. Self-AssemblyofBlockCopolymersinIonicLiquids ........................................ 83
RuXie,CarlosR.López-Barrón,andNormanJ.Wagner
6. Multi-PurposeCellulosicIonogels...................................................................... 143
ChipJ.SmithII,DurgeshV.Wagle,HughM.O’Neill,BarbaraR.Evans,
SheilaN.Baker,andGaryA.Baker
7. Liquid–LiquidExtractionoff-BlockElementsUsingIonicLiquids .............. 157
JérémyDehaudt,Chi-LinhDo-Thanh,HuiminLuo,andShengDai
Biomass Processing
8. ViscosityandRheologyofIonicLiquidMixturesContainingCelluloseand
CosolventsforAdvancedProcessing.................................................................. 189
DavidL.Minnick,RaulA.Flores,andAaronM.Scurto
9. Ultra-LowCostIonicLiquidsfortheDelignificationofBiomass ................... 209
FlorenceJ.V.Gschwend,AgnieszkaBrandt-Talbot,ClementineL.Chambon,and
JasonP.Hallett
vii
Fundamentals
10. WateratIonicLiquidInterfaces ........................................................................ 227
AliciaBroderickandJohnT.Newberg
11. RadiationandRadicalChemistryofIonicLiquidsforEnergy
Applications .......................................................................................................... 251
JamesF.Wishart
12. ExperimentalStudyoftheInteractionsofFullerenewithIonicLiquids ....... 273
M.F.CostaGomes,L.Pison,andA.A.H.Padua
13. BiphasicExtraction,RecoveryandIdentificationofOrganicandInorganic
CompoundswithIonicLiquids........................................................................... 283
RicoE.DelSesto,AndrewT.Koppisch,DavidT.Fox,MattieR.Jones,
KatherineS.Lovejoy,TylerE.Stevens,andToddC.Monson
Editors’Biographies .................................................................................................... 303
Indexes
AuthorIndex ................................................................................................................ 307
SubjectIndex................................................................................................................ 309
viii
Preface
The purpose of this book is to provide an update on some of the latest
research and applications in the broad field of ionic liquids. This volume spans
researchanddevelopmentactivitiesrangingfromfundamentalandexperimental
investigationstocommercialapplications. Abriefhistoryofthefieldisincluded,
as well as both new developments and reviews organized in the general topical
areasofapplications,materials,biomassprocessing,andfundamentalstudies.
Thistextwasdevelopedfromaselectionofpaperspresentedinatwo-session
symposium entitled Ionic Liquids: Current and Future Trends at the 251st
American Chemical Society (ACS) National Meeting which was held in San
Diego, CaliforniaonMarch14, 2016. ThesymposiumwasorganizedbyAaron
Scurto, aprofessorfromtheUniversityofKansas, DepartmentofChemicaland
Petroleum Engineering. The symposium was a virtual “who’s who” in the field
of ionic liquids and thus the book chapters are written by some of the leading
expertsinthefield.
The symposium was held in honor of Dr. Mark B. Shiflett who was named
aDivisionFellowbytheIndustrialandEngineeringChemistry(I&EC)Division
of the American Chemical Society. He received the award in recognition of his
researchattheDuPontCompanywhichhasimpactedbothappliedchemistryand
chemicalengineering.
Dr. Shiflettwashonoredspecificallyfor:
• Working with his team to invent and patent several energy-efficient
refrigerant mixtures based on hydrofluorocarbons that replaced
ozone-depletingchlorofluorocarbons(CFCs). Theseproductssavedthe
refrigerationindustryhundredsofmillionsofdollarsinretrofitcostsand
acceleratedthetransitionawayfromCFCswhichhasledtothehealing
oftheEarth’sozonelayer.
• Developing novel materials for hydrogen storage, a next-generation
technology for the green manufacturing of titanium dioxide and
pioneeringworktostudytheinteractionoffluorinatedionicliquidsand
fluorochemicals.
• Publishing over 70 papers in peer-reviewed journals and being an
inventoron44U.S.patents.
• Teaching and advising the next generation of chemical engineering
students at the University of Delaware in the Department of Chemical
andBiomolecularEngineering.
ix