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Introduction to Food Process Engineering PDF

714 Pages·2014·15.245 MB·English
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Food Science and Technology Ibarz Barbosa-Cánovas FOOD Introduction to Food Process Engineering PRESERVATION FOOD PRESERVATION TECHNOLOGY SERIES TECHNOLOGY SERIES Consumer expectations are systematically growing, with demands for foods with a number of attributes, which are sometimes difficult for manufacturers to meet. The engineering processes that are needed to obtain top-quality I foods are a major challenge due to the diversity of raw materials, n intermediates, and final products. As in any other enterprise, the food t r industry must optimize each of the steps in the production chain to attain o Introduction to the best possible results. There is no question that a very important aspect d to take into consideration when developing a process, designing a food Introduction to u factory, or modifying existing facilities is the in-depth knowledge of the basic engineering aspects involved in a given project. c t Food i Food Process Introduction to Food Process Engineering covers the fundamental o principles necessary to study, understand, and analyze most unit operations n in the food engineering domain. It was conceived with two clear objectives t in mind: 1) to present all of the subjects in a systematic, coherent, and o Process sequential fashion in order to provide an excellent knowledge base for a F number of conventional and unconventional processes encountered in food industry processing lines, as well as novel processes at the research and o development stages; 2) to be the best grounding possible for another CRC o Press publication, Unit Operations in Food Engineering, Second Edition, d Engineering by the same authors. These two books can be consulted independently, but P at the same time, there is a significant and welcomed match between the two in terms of terminology, definitions, units, symbols, and nomenclature. r o c Highlights of the book include: e • Dimensional analysis and similarities • Thermal processing s s • Physicochemistry of food systems • Chilling and freezing • Heat and mass transfer in food • Evaporation E • Food rheology • Dehydration n Albert Ibarz • Physical properties • Extensive examples, problems, g • Water activity and solutions i n Gustavo V. Barbosa-Cánovas e e r i n g K10455 Introduction to Food Process Engineering FOOD PRESERVATION TECHNOLOGY SERIES Series Editor Gustavo V. Barbosa-Cánovas Introduction to Food Process Engineering Editors: Albert Ibarz and Gustavo V. Barbosa-Cánovas Shelf Life Assessment of Food Editor: Maria Cristina Nicoli Cereal Grains: Laboratory Reference and Procedures Manual Sergio O. Serna-Saldivar Advances in Fresh-Cut Fruits and Vegetables Processing Editors: Olga Martín-Belloso and Robert Soliva-Fortuny Cereal Grains: Properties, Processing, and Nutritional Attributes Sergio O. Serna-Saldivar Water Properties of Food, Pharmaceutical, and Biological Materials Editors: Maria del Pilar Buera, Jorge Welti-Chanes, Peter J. Lillford, and Horacio R. Corti Food Science and Food Biotechnology Editors: Gustavo F. Gutiérrez-López and Gustavo V. Barbosa-Cánovas Transport Phenomena in Food Processing Editors: Jorge Welti-Chanes, Jorge F. Vélez-Ruiz, and Gustavo V. Barbosa-Cánovas Unit Operations in Food Engineering Albert Ibarz and Gustavo V. Barbosa-Cánovas Engineering and Food for the 21st Century Editors: Jorge Welti-Chanes, Gustavo V. Barbosa-Cánovas, and José Miguel Aguilera Osmotic Dehydration and Vacuum Impregnation: Applications in Food Industries Editors: Pedro Fito, Amparo Chiralt, Jose M. Barat, Walter E. L. Spiess, and Diana Behsnilian Pulsed Electric Fields in Food Processing: Fundamental Aspects and Applications Editors: Gustavo V. Barbosa-Cánovas and Q. Howard Zhang Trends in Food Engineering Editors: Jorge E. Lozano, Cristina Añón, Efrén Parada-Arias, and Gustavo V. Barbosa-Cánovas Innovations in Food Processing Editors: Gustavo V. Barbosa-Cánovas and Grahame W. Gould Introduction to Food Process Engineering Albert Ibarz Gustavo V. Barbosa-Cánovas Boca Raton London New York CRC Press is an imprint of the Taylor & Francis Group, an informa business CRC Press Taylor & Francis Group 6000 Broken Sound Parkway NW, Suite 300 Boca Raton, FL 33487-2742 © 2014 by Taylor & Francis Group, LLC CRC Press is an imprint of Taylor & Francis Group, an Informa business No claim to original U.S. Government works Version Date: 20140117 International Standard Book Number-13: 978-1-4822-1966-1 (eBook - PDF) This book contains information obtained from authentic and highly regarded sources. Reasonable efforts have been made to publish reliable data and information, but the author and publisher cannot assume responsibility for the valid- ity of all materials or the consequences of their use. The authors and publishers have attempted to trace the copyright holders of all material reproduced in this publication and apologize to copyright holders if permission to publish in this form has not been obtained. If any copyright material has not been acknowledged please write and let us know so we may rectify in any future reprint. Except as permitted under U.S. Copyright Law, no part of this book may be reprinted, reproduced, transmitted, or uti- lized in any form by any electronic, mechanical, or other means, now known or hereafter invented, including photocopy- ing, microfilming, and recording, or in any information storage or retrieval system, without written permission from the publishers. For permission to photocopy or use material electronically from this work, please access www.copyright.com (http:// www.copyright.com/) or contact the Copyright Clearance Center, Inc. (CCC), 222 Rosewood Drive, Danvers, MA 01923, 978-750-8400. CCC is a not-for-profit organization that provides licenses and registration for a variety of users. For organizations that have been granted a photocopy license by the CCC, a separate system of payment has been arranged. Trademark Notice: Product or corporate names may be trademarks or registered trademarks, and are used only for identification and explanation without intent to infringe. Visit the Taylor & Francis Web site at http://www.taylorandfrancis.com and the CRC Press Web site at http://www.crcpress.com Albert dedicates this book to his family and Gustavo to Kezban Candoğan Contents Preface.............................................................................................................................................xix Acknowledgments ...........................................................................................................................xxi Authors .........................................................................................................................................xxiii Chapter 1 Introduction to Unit Operations ...................................................................................1 1.1 Process ...............................................................................................................1 1.2 Food Process Engineering .................................................................................1 1.3 Transformation and Commercialization of Agricultural Products ...................2 1.4 Flowcharts and Description of Some Food Processes ......................................2 1.5 Steady and Unsteady States ...............................................................................4 1.6 Discontinuous, Continuous, and Semicontinuous Operations ..........................4 1.7 Unit Operations: Classification ..........................................................................5 1.7.1 Momentum Transfer Unit Operations ..................................................5 1.7.2 Mass Transfer Unit Operations ............................................................6 1.7.3 Heat Transfer Unit Operations .............................................................6 1.7.4 Simultaneous Mass–Heat Transfer Unit Operations ............................6 1.7.5 Complementary Unit Operations .........................................................7 1.8 Mathematical Setup of the Problems.................................................................7 Chapter 2 Unit Systems, Dimensional Analysis, and Similarities ................................................9 2.1 Magnitude and Unit Systems .............................................................................9 2.1.1 Absolute Unit Systems .........................................................................9 2.1.2 Technical Unit Systems ........................................................................9 2.1.3 Engineering Unit Systems ..................................................................10 2.1.4 International Unit System ...................................................................11 2.1.5 Thermal Units ....................................................................................11 2.1.6 Unit Conversion ..................................................................................12 2.2 Dimensional Analysis ......................................................................................14 2.2.1 Buckingham’s π Theorem ..................................................................15 2.2.2 Dimensional Analysis Methods .........................................................16 2.2.2.1 Buckingham’s Method ........................................................16 2.2.2.2 Rayleigh’s Method ..............................................................17 2.2.2.3 Method of Differential Equations .......................................18 2.3 Similarity Theory ............................................................................................18 2.3.1 Geometric Similarity..........................................................................19 2.3.2 Mechanical Similarity ........................................................................20 2.3.2.1 Static Similarity ..................................................................20 2.3.2.2 Kinematic Similarity ..........................................................20 2.3.2.3 Dynamic Similarity ............................................................20 Problems .....................................................................................................................24 Chapter 3 Introduction to Transport Phenomena ........................................................................33 3.1 Historical Introduction ....................................................................................33 3.2 Transport Phenomena ......................................................................................34 vii viii Contents 3.3 Circulation Regimes: Reynold’s Experiment ..................................................34 3.4 Transport Phenomena Mechanisms.................................................................36 3.4.1 Mass Transfer .....................................................................................37 3.4.2 Energy Transfer ..................................................................................38 3.4.3 Momentum Transfer ...........................................................................38 3.4.4 Velocity Laws .....................................................................................38 3.4.5 Coupled Phenomena ...........................................................................39 Chapter 4 Momentum, Energy, and Mass Transfer ....................................................................41 4.1 Introduction .....................................................................................................41 4.2 Momentum Transfer: Newton’s Law of Viscosity ...........................................41 4.3 Energy Transfer: Fourier’s Law of Heat Conduction ......................................42 4.4 Mass Transfer: Fick’s Law of Diffusion ..........................................................44 4.5 General Equation of Velocity ..........................................................................47 Chapter 5 Macroscopic Balances ................................................................................................49 5.1 Introduction .....................................................................................................49 5.2 Macroscopic Mass Balance .............................................................................50 5.3 Macroscopic Energy Balance ..........................................................................52 Problems .....................................................................................................................59 Chapter 6 Physicochemistry of Food Systems ............................................................................73 6.1 Introduction .....................................................................................................73 6.2 General Concepts ............................................................................................73 6.2.1 Thermodynamic System ....................................................................73 6.2.2 State Equation for Gases ....................................................................75 6.2.3 Different Forms of Energy .................................................................76 6.3 Zeroth Law of Thermodynamics .....................................................................77 6.4 First Principle of Thermodynamics .................................................................77 6.5 Enthalpy ...........................................................................................................78 6.6 Heat Capacity ..................................................................................................79 6.7 Second Principle of Thermodynamics: Entropy .............................................81 6.8 Thermal Machines: Carnot’s Cycle .................................................................83 6.9 Third Principle of Thermodynamics ...............................................................84 6.10 Chemical Thermodynamics ............................................................................85 6.11 Helmholtz Free Energy ...................................................................................85 6.12 Gibbs Free Energy ...........................................................................................86 6.13 Chemical Potential: Phase Equilibrium ..........................................................88 6.14 Phase Diagram .................................................................................................92 Chapter 7 Mass Transfer .............................................................................................................95 7.1 Introduction .....................................................................................................95 7.2 Mass Transfer by Diffusion .............................................................................96 7.2.1 1D Diffusion in Binary Mixtures .......................................................98 7.2.1.1 Diffusion through Gases .....................................................98 7.2.1.2 Diffusion through Liquids ................................................101

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