InterfacesofCeramic-MatrixComposites Interfaces of Ceramic-Matrix Composites Design,CharacterizationandDamageEffects LongbiaoLi Author AllbookspublishedbyWILEY-VCH arecarefullyproduced.Nevertheless, Prof.LongbiaoLi authors,editors,andpublisherdonot NanjingUniversityofAeronauticsand warranttheinformationcontainedin Astronaut thesebooks,includingthisbook,to CollegeofCivilAviation befreeoferrors.Readersareadvised No.29YudaoSt. tokeepinmindthatstatements,data, 210016Nanjing illustrations,proceduraldetailsorother China itemsmayinadvertentlybeinaccurate. LibraryofCongressCardNo.: appliedfor BritishLibraryCataloguing-in-Publication Data Acataloguerecordforthisbookis availablefromtheBritishLibrary. Bibliographicinformationpublishedby theDeutscheNationalbibliothek TheDeutscheNationalbibliotheklists thispublicationintheDeutsche Nationalbibliografie;detailed bibliographicdataareavailableonthe Internetat<http://dnb.d-nb.de>. ©2020WILEY-VCHGmbH,Boschstr. 12,69469Weinheim,Germany Allrightsreserved(includingthoseof translationintootherlanguages).No partofthisbookmaybereproducedin anyform–byphotoprinting, microfilm,oranyothermeans–nor transmittedortranslatedintoa machinelanguagewithoutwritten permissionfromthepublishers. Registerednames,trademarks,etc.used inthisbook,evenwhennotspecifically markedassuch,arenottobe consideredunprotectedbylaw. PrintISBN: 978-3-527-34778-0 ePDFISBN: 978-3-527-82803-6 ePubISBN: 978-3-527-82805-0 oBookISBN: 978-3-527-82804-3 Typesetting SPiGlobal,Chennai,India PrintingandBinding Printedonacid-freepaper 10 9 8 7 6 5 4 3 2 1 ToShengning vii Contents Preface xi Acknowledgments xiii 1 Definition,Function,andDesignofInterfaceinCeramic-Matrix Composites 1 1.1 Introduction 1 1.2 TheDefinitionofInterfaceinCeramic-MatrixComposites 2 1.2.1 Non-oxideCMCs 3 1.2.2 Oxide/OxideCMCs 13 1.3 TheFunctionofInterfaceinCeramic-MatrixComposites 18 1.3.1 EffectofInterphaseonSlidingResistance 19 1.3.2 EffectofInterphaseonThermalMisfitStress 19 1.4 TheDesignofInterfaceinCeramic-MatrixComposites 20 1.4.1 PyCInterphase 20 1.4.2 BNInterphase 21 1.5 Conclusion 21 References 22 2 InterfaceCharacterizationofCeramic-MatrixComposites 29 2.1 Introduction 29 2.2 EffectofInterfacePropertiesonTensileandFatigueBehaviorof Ceramic-MatrixComposites 30 2.2.1 TheoreticalAnalysis 31 2.2.1.1 FirstMatrixCrackingStress 31 2.2.1.2 MatrixCrackingDensity 31 2.2.1.3 FatigueHysteresis-BasedDamageParameters 32 2.2.2 ResultsandDiscussion 33 2.2.2.1 EffectoftheInterfacePropertiesonFirstMatrixCrackingStress 33 2.2.2.2 EffectoftheInterfacePropertiesonMatrixCrackingDensity 36 2.2.2.3 EffectoftheInterfacePropertiesontheFatigueHysteresis-Based DamageParameters 39 2.2.3 ExperimentalComparisons 41 2.2.3.1 FirstMatrixCrackingStress 42 2.2.3.2 MatrixCrackingDensity 43 viii Contents 2.2.3.3 FatigueHysteresis-BasedDamageParameters 46 2.3 EffectofPre-exposureonTensileDamageandFractureof Ceramic-MatrixComposites 51 2.3.1 TheoreticalAnalysis 52 2.3.1.1 StressAnalysisConsideringInterfaceOxidationandFiberFailure 54 2.3.1.2 MatrixMulticrackingConsideringInterfaceOxidation 56 2.3.1.3 InterfaceDebondingConsideringInterfaceOxidation 57 2.3.1.4 FiberFailureConsideringInterfaceandFiberOxidation 58 2.3.1.5 TensileStress–StrainCurvesConsideringEffectofPre-exposure 59 2.3.2 ResultsandDiscussion 60 2.3.2.1 EffectofPre-exposureTemperatureonTensileandDamage Process 60 2.3.2.2 EffectofPre-exposureTimeonTensileandDamageProcesses 61 2.3.2.3 EffectofInterfaceShearStressonTensileandDamageProcesses 62 2.3.2.4 EffectofFiberStrengthonTensileandDamageProcesses 64 2.3.2.5 EffectofFiberWeibullModulusonTensileandDamageProcesses 65 2.3.3 ExperimentalComparisons 66 2.4 EffectofInterfacePropertiesonLifetimeofCeramic-Matrix Composites 71 2.4.1 TheoreticalAnalysis 73 2.4.1.1 LifePredictionModelatRoomTemperature 74 2.4.1.2 LifePredictionModelatElevatedTemperaturesintheOxidative Environment 77 2.4.2 ExperimentalComparisons 79 2.4.2.1 LifePredictionatRoomTemperature 79 2.4.2.2 LifePredictionatElevatedTemperature 89 2.5 Conclusion 100 References 103 3 InterfaceAssessmentofCeramic-MatrixComposites 109 3.1 Introduction 109 3.2 RelationshipsBetweenInterfaceSlipandTemperatureRisingin CMCs 112 3.2.1 HysteresisTheories 112 3.2.1.1 CaseI 113 3.2.1.2 CaseII 115 3.2.1.3 CaseIII 116 3.2.1.4 CaseIV 117 3.2.2 ExperimentalComparisons 118 3.2.2.1 UnidirectionalCMCs 118 3.2.2.2 Cross-PlyCMCs 122 3.2.2.3 2DCMCs 124 3.3 InterfaceAssessmentofCMCsfromHysteresisLoops 127 3.3.1 ResultsandDiscussion 128 3.3.1.1 UnidirectionalC/SiCComposite 129 3.3.1.2 Cross-PlyC/SiCComposite 131 3.3.1.3 2.5DC/SiCComposite 135