Inorganic Reactions and Methods: Formation of Bonds to Elements of Group IVB (C, Si, Ge, Sn, Pb) (Part 4), Volume 12B

783 Pages·1990·101.173 MB·English

Inorganic Reactions
and Methods
Volume 126
Inorganic Reactions
and Methods
Editor
Professor A.P. Hagen
Department of Chemistry
The University of Oklahoma
Norman, Oklahoma 73019
Editorial Advisory Board
Professor N. Bartlett Professor A.G. MacDiarmid
Department of Chemistry Department of Chemistry
University of California at Berkeley University of Pennsylvania
Berkeley, California 94720 Philadelphia, Pennsylvania 1917 4
Professor Schmidt
Professor F.A. Cotton M.
lnstitut fur Anorganische Chemie der
Department of Chemistry
Universitit
Texas A&M University
0-8700 Wutzburg
College Station, Texas 77840
Am Hubland
Federal Republic of Germany
Professor E.O. Fischer
Anorganisch-chemisches Laboratorium Professor H. Taube
der Technischen Universitit
Department of Chemistry
D-8046 Garching
Stanford University
Lichtenbergestrasse 4 Stanford, California 94305
Federal Republic of Germany
Professor L.M. Venanzi
Professor P. Hagenmuller Laboratorium fur Anorganische Chemie
Laboratoire de Chemie du Solide du der ETH
C.N.R.S. CH-80006 Zurich
351 cours de la Liberation Universitlitsstrasse5
F-33405 Talence Switzerland
France
Professor Sir Geoffrey Wilkinson, F.R.S.
Professor M.F. Lappert Department of Chemistry
The Chemical Laboratory Imperial College
University of Sussex South Kensington
Falmer, Brighton, BN1 9A3 London, SW7 2AY
England England
0 1991 VCH Publishers, Inc., New York
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Inorganic Reactions
and Methods
Volume 12B
The Formation of Bonds to
Elements of Group IVB
(C, Si, Ge, Pb) (Part 4)
Sn,
~~
Founding Editor
J.J. Zuckerman
Editor
A.P. Hagen
Library of Congress Cataloging-in-PublicationD ata
Inorganic reactions and methods.
Includes bibliographies and indexes.
-
Contents: v. 1. The formation of bonds to hydrogen
pt. 2, v. 2. The formation of the bond to hydrogen -
v. 15. Electron-transfer and electrochemical
reactions; photochemical and other energized reactions.
1. Chemical reaction, Conditions and laws of -
Collected works. 2. Chemistry, Inorganic - Synthesis -
Collected works. 1. Zuckerman, Jerry J.
QD501.1623 1987 541.39 85-15 627
ISBN 0-89573-250-0( set)
0 1991 VCH Publishers, Inc.
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Contents of Volume 128
How to Use this Book
Preface to the Series
Editorial Consultants to the Series
Contributors to Volume
128
5. The Formation of Bonds to Elements
of Group IVB (C, Si, Ge, Sn, Pb)
(Part 4) 1
5.8. Formation of Bonds between Elements
of Groups IVB (C, Si, Ge, Sn, Pb) and
Transition and Inner-Transition Metals 2
Introduction
5.8.1. 2
Formation of the Carbon-Transition and
5.8.2.
Inner Transition Metal Bond
2
from Alkali-Metal Carbanions
5.8.2.8. 2
a-Alkyl- and Aryl-Metal Complexes
5.8.2.8.1.
by Reaction with the Corresponding
Metal Halides
2
n-Ally1 Metal Complexes by Reaction
5.8.2.8.2.
with the Corresponding Metal
Halides
18
q5 n-Cyclopentadienyl Metal
5.8.2.8.3.
Complexes by Reaction with the
Corresponding Metal Halides
35
o-Acyls from Alkali-Metal
5.8.2.8.4. q1
Carbanions and Metal Carbonyls.
68
a-Acyl and Carbene Complexes
5.8.2.8.5. q1
by Reaction with Corresponding
Metal-Carbonyl Complexes.
72
a-Cyanide Complexes
5.8.2.8.6. q1 87
Ylide Complexes of the Transition
5.8.2.8.7.
Metals by Treating the Ylide with
Transition-Metal Halide.
104
from Organic Halides, Tosylates and
5.8.2.9.
Acetates.
108
V
vi Contents of Volume
128
5.8.2.9.1. q1 o-Alkyl, -Aryl and -Acyl Metal
Complexes by Oxidative
Addition. 108
5.8.2.9.2. (q’)-a-Alkyl-, -Aryl-, and -Acyl-Metal
Complexes by Reaction with Metal-
Complex Anions. 121
5.8.2.9.3. q1 a-Alkyl-, -Aryl-, Acyl- and Silyl
Metal Complexes by Reaction of
Metal-Atom Vapors. 125
5.8.2.9.4. q3 n-Ally1 Transition-Metal
Complexes by Oxidative Addition 131
5.8.2.9.5. n-Cyclobu tad ie ny I Com p Ie xes
q4
from 3,4-Di haI o cyclo but enes. 153
5.8.2.10. from Aldehydes 156
5.8.2.1 1. from Other Organometallics 160
5.8.2.1 1. l. by Transmetallation from Boron and
Tin 160
5.8.2.1 1.2. by Transmetallation from Mercury 167
5.8.2.1 1.3. by Transmetallation from Other
Metal Organometallics to Metal
Halides. 176
5.8.2.12. from Carbon Monoxide 183
5.8.2.12.1. Carbonyl Complexes by Direct
Reaction of the Metals with Carbon
Monoxide or by Reduction-Oxidation
Procedures. 183
5.8.2.12.2. Carbonyl Complexes by Ligand-
Exchange Reactions. 190
5.8.2.12.3. q1 o-Acyl Complexes by Insertion of
CO in a-Alkyl Complexes. 19 7
5.8.2.12.4. Carbamoyl Complexes by Reaction
of Metal Carbonyls with Amines. 201
5.8.2.12.5. Al koxycarbonyl Complexes by
Reaction of Metal Carbonyls with
Alcohols and Alkoxides. 204
5.8.2.13. from Carbon Disulfide, Thioacid
Chlorides, or Carbon Diselenide 206
5.8.2.13.1. Thio- and Selenocarbonyl
Complexes by Ligand-Exchange
Reactions with Metal Complexes. 206
5.8.2.14. from Carbon Dioxide 209
5.8.2.14.1. by Ligand-Exchange Reactions with
M eta1 Com plexes. 209
5.8.2.1 5. from Isonitriles 213
Contents of Volume 128 vii
Isonitrile Complexes by Ligand-
5.8.2.15.1.
Exchange Reactions.
213
lminoacyl Complexes by Isonitrile
5.8.2.15.2.
Insertion.
216
from Miscellaneous Species
5.8.2.16. 218
Carbyne Complexes from
5.8.2.16.1.
Heterocarbene Complexes.
218
Carbyne Complexes by
5.8.2.16.2.
Deprotonation of Cationic Carbene
Complexes.
222
Carbyne Complexes by
5.8.2.16.3.
Dehalogenation of Chlorocarbene
Complexes.
224
by Metal-Atom and Related
5.8.2.16.4.
Reactions.
225
The Formation of the Silicon-Transition
5.8.3.
and Inner Transition-Metal Bond
227
from the Elements.
5.8.3.1. 227
from Silicon Hydrides
5.8.3.2. 227
by Reaction with a Transition- or
5.8.3.2.1.
Inner Transition-Metal Halide
Derivative in the Presence of
Triethylamine.
227
by Reaction with a Transition- or
5.8.3.2.2.
Inner Transition-Metal Hydride
Complex.
228
by Reaction with a Mononuclear
5.8.3.2.3.
Transition- or Inner Transition-Metal
Carbonyl in the Presence of
Ultraviolet Radiation.
229
by Reaction with Di- or Trinuclear
5.8.3.2.4.
Transition- or Inner Transition-Metal
Carbonyl Complexes.
230
by Oxidative Addition to a Low-
5.8.3.2.5.
Valent Transition- or Inner
Transition-Metal Complex.
234
by Reaction with a Group-IVB
5.8.3.2.6.
Transition- or Inner Transition-Metal
Derivative.
237
from Silicon Halides
5.8.3.3. 239
by Reaction with a Reactive Metal
5.8.3.3.1.
Derivative of a Transition-Metal
Complex (a Transition- or Inner
Transition-Metal-Anion Complex).
239
viii Contents of Volume
126
from Silyl-Alkali Metal Reagents
5.8.3.4. 242
by Reaction with a Transition- or
5.8.3.4.1.
Inner Transition-Metal Halide
Complex.
242
by Reaction with a Low-Valent
5.8.3.4.2.
Transition- or Inner Transition-Metal
Complex.
243
from Bis(sily1) Mercurials
5.8.3.5. 244
by Reaction with a Transition- or
5.8.3.5.1.
Inner Transition-Metal-Halide
Complex.
244
by Reaction with Low-Valent
5.8.3.5.2.
Transition- or Inner Transition-Metal
Co mp Ie xes.
245
Miscellaneous Reactions
5.8.3.6. 245
by Oxidative Addition of Si,X, and
5.8.3.6.1.
Strained Cyclic Disilanes to Low-
Valent Transition- or Inner
Transition-Metal Complexes.
245
from Sila- and 1, 3-Disilacyclobutanes
5.8.3.6.2.
by Reaction with FeJCO),.
246
by Reaction of SIR, with a Low-
5.8.3.6.3.
Valent Transition- or Inner
Transition-Metal Complex.
248
from Silyl Amides by Reaction with a
5.8.3.6.4.
Transition- or Inner Transition-Metal
Hydride.
248
The Formation of Germanium-Transition
5.8.4.
and Inner-Transition Metal Bond
249
from the Elements.
5.8.4.1. 249
from Germanium Hydrides
5.8.4.2. 250
by Addition to Transition-
5.8.4.2.1.
Metal-Transition-Metal Bonds
250
by Oxidative Addition to Low-
5.8.4.2.2.
Coordinate Transition-Metal
Complexes
255
by Reaction with Transition- or
5.8.4.2.3.
Inn e r-Transit ion-Metal Hal ide,
Hydride and Related Complexes.
258
by Proton Abstraction of Hydrogen
5.8.4.2.4.
To Form Unsaturated Ge-Metal
Bonds.
260
Miscellaneous Reactions of the
5.8.4.2.5.
Ge-H Bond.
26 1
Contents of Volume 128 ix
from Germanium Halides
5.8.4.3. 262
by Reaction with an Active Metal
5.8.4.3.1.
Derivative of a Transition- or Inner-
Transition-Metal Complex (an Anion
Com plex) .
262
by Reaction of Germanium
5.8.4.3.2.
Tetrahalides with Neutral
Mononuclear Metal Carbonyls and
Related Species.
266
by Reaction with a Silyl-Transition-
5.8.4.3.3.
or In ne r-Trans it io n-M eta I-M eta I
Co mp Ie x.
268
from Germyl-Alkali-Metal Reagents
5.8.4.4. 268
by Reaction with Transition- or
5.8.4.4.1.
Inner-Transition-Metal-Halide
Complexes.
268
from Bis(germy1)mercury or -cadmium
5.8.4.5.
[NOTE: These substances are
highly toxic and must be handled
with care.]
271
by Reaction with Transition- or
5.8.4.5.1.
In ner-Trans it io n-M eta1 Hal id e
Complexes.
27 1
by Reaction with Low-Valent
5.8.4.5.2.
Transition- or Inner-Transition-Metal
Complexes
272
from Germanium( II ).
5.8.4.6. 273
by Use of GeX, or GeR,.
5.8.4.6.1. 273
by Use of [GeX,] .
5.8.4.6.2. - 275
from Germyl Amides by Reaction with
5.8.4.7.
Transition- or Inner-Transition-Metal
Hydr ides.
276
from Species Containing Ge Bonded to
5.8.4.8.
Unsaturated Ligands.
277
The Formation of the Tin-Transition- or
5.8.5.
Inner Transition-Metal Bond
277
from the Elements.
5.8.5.1. 278
from Organotin Hydrides
5.8.5.2. 278
by Reaction with Mononuclear
5.8.5.2.1.
Transition- or Inner Transition-Metal
Carbonyl Derivatives.
278
by Reaction with Polynuclear
5.8.5.2.2.
Transition- or Inner Transition-Metal
Carbonyl Derivatives.
279
X Contents of Volume 128
~
by Reaction with Transition- or Inner
5.8.5.2.3.
Transition-Metal-Halide and
-Amide Complexes.
279
by Reaction with Transition-Metal or
5.8.5.2.4.
Inner Transition-Metal-Olefin
Co mp Ie xes.
280
by Reaction with Silyl-Transition-
5.8.5.2.5.
Metal or -Inner Transition-Metal
Complexes.
280
from Tin(lV) and Organotin Halides
5.8.5.3. 280
by Reaction with a Reactive Metal
5.8.5.3.1.
Derivative of a Transition-Metal
Complex or Inner Transition-Metal
Complex.
280
by Reaction with a Transition- or
5.8.5.3.2.
Inner Transition-Meial-Hydride
Complex.
283
by Reaction with a Transition- or
5.8.5.3.3.
Inner Transition-Metal-Mercury
Complex.
283
by Reaction with Mononuclear
5.8.5.3.4.
Transition-Metal Carbonyl
Derivatives.
283
by Reaction with Polynuclear
5.8.5.3.5.
Transition- or inner Transition-Metal
Carbonyl Derivatives.
284
by Reaction with Transition- or Inner
5.8.5.3.6.
Transition-Metal-Olefin Complexes
and Other Complexes with Readily
Displaceable Ligands.
285
from Organotin-Nitrogen Compounds
5.8.5.4. 286
by Reaction with an Organotin
5.8.5.4.1.
Amide with a Transition- or Inner
Transition-Metal-Hydride Complex.
286
by Reaction of an Organotin Azide
5.8.5.4.2.
with a Transition- or Inner
Transition-Metal-Hydride Complex.
286
by Reaction of Organotin-Nitrogen
5.8.5.4.3.
Compounds with Other Complexes
of the Transition or Inner Transition
Metals.
286
from Stannyl-Active Metal Reagents
5.8.5.5. 287
by Reaction with Transition- or Inner
5.8.5.5.1.
Transition-Metal-Halide
Complexes.
287