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Hydrogen Energy: Part A PDF

687 Pages·1975·30.677 MB·English
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HYDROGEN ENERGY HYDROGEN ENERGY Pari A Edited by T. Nejat Veziroglu Director Clean Energy Research Institute School of Engineering and Environmental Design University of Miami Coral Gables, Florida PLENUM PRESS· NEW YORK AND LONDON Library of Congress Cataloging in Publication Data Hydrogen Economy Miami Energy Conference, Miami Beach Fla., 1974 Hydrogen energy. Includes bibliographical references and index. 1. Hydrogen as fuel-Congresses. I. Veziro~lu, T. Nejat, ed. II. Miami, Univer sity of, Coral Gables, Fla. School of Engineering and Environmental Design. III. Title. TP360.H94 1974 338.4'7'66581 74-34483 ISBN-13: 978-1-4684-2609-0 e-ISBN-13: 978-1-4684-2607-6 001: 10.1007/978-14684-2607-6 Proceedings of the Hydrogen Economy Miami Energy (THEME) Conference, held in Miami Beach, Florida, March 18-20, 1974 and presented by the Clean Energy Re search Institute, School of Engineering and Environmental Design, University of Miami, Coral Gables, Florida; sponsored by the National Science Foundation, the De fense Advanced Research Projects Agency and the School of Continuing Studies, University of Miami. © 1975 Plenum Press, New York Softcover reprint of the hardcover 1s t edition 1975 A Division of Plenum Publishing Corporation 227 West 17th Street, New York, N.Y. 10011 United Kingdom edition published by Plenum Press, London A Division of Plenum Publishing Company, Ltd. 4a Lower John Street, London W1 R 3PD, England All rights reserved The United States Government has a royalty-free, nonexclusive and irrevocable license throughout the world for Government purposes to publish, translate, reproduce, deliver, perform, dispose of, and to authorize others to do so, all or any portion of this work THEME Conference Committee General Chairman Howard P. Harrenstien Dean, School of Engineering and Enviror~ental Design Co-Chairman T. Nejat Veziroglu Chairman, Mechanical Engineering Department Coordinator Robert R. Adt, Jr. Associate Professor Mechanical Engineering Department Special Consultants William J. D. Escher Escher Technology Associates Ray Nell Chungo Clean Energy Research Institute Conference Staff Arrangements Tony Pajares Arlene Jacobsohn The School of Continuing Studies Program for Mary Gene Knopf Accompaniers Conference Services Special Assistants Jennie Myers Pauline Singer The School of Engineering and Environmental Design v ACKNOWLEDGMENTS The THEME Conference Committee gratefully acknowledges the financial support provided by the Conference Sponsoring Organiza tion: The National Science Foundation The Advanced Research Projects Agency, Department of Defense The School of Continuing Studies, University of Miami We also wish to extend a word of appreciation to the Confer ence Banquet guest speaker, Dr. Edward Teller. Thanks also are due our authors and presenters who provided the substance of the conference, related as published papers in the present proceedings. A special debt of appreciation is owed to the Session Chair man in organizing and executing the technical sessions, and to the Co-Chairmen from The University of Miami faculty for their support. In acknowledgment we list these session officials on the following page. Finally, we wish to thank our publisher, the Plenum Publishing Corporation for its basic role in printing and distributing the present formal edition of the Proceedings. THEME Conference Committee Miami, October 1974 vi SESSION OFFICIALS Session 1. Primary Energy Sources E. L. Armstrong, URS Systems Corporation, Falls Church, Virginia, Chairman D. Wells, University of Miami, Coral Gables, Florida, Co-Chairman Session 2. Hydrogen Storage and Transmission J. E. Johnson, Union Carbide Corporation, Linde Division, New York, New York, Chairman S. S. Lee, University of Miami, Coral Gables, Florida, Co-Chairman Session 3. Hydrogen Production Using Nuclear Energy C. L. Richard, General Atomic Company, San Diego, California, Chairman H. Plass, University of Miami, Coral Gables, Florida, Co-Chairman Session 4. Metal Hydride Storage F. Schulman, Fred Schulman Associates, Silver Spring, Maryland, Chairman W. B. King, University of Miami, Coral Gables, Florida, Co-Chairman Session 5. Hydrogen Production Alternatives I C. Marchetti, Euratom, Ispra, Italy, Chairman H. A. B. Wiseman, University of Miami, Coral Gables, Florida Session 6. Behavior of Hydrogen in Metals A. Bain, NASA, Kennedy Space Center, Cape Kennedy, Florida, Chairman L. Poteat, University of Miami, Coral Gables, Florida, Co-Chairman viii SESSION OFFICIALS Session 7. Hydrogen Production Using Solar Energy W. F. Cantieri, American Society of Mechanical Engineers, Chairman T. G. Olsen, University of Miami, Coral Gables, Florida, Co-Chairman Session 8. Hydrogen Storage in Vehicles L. W. Jones, University of Michigan, Ann Arbor, Michigan, Chairman J. Alexander, University of Miami, Coral Gables, Florida, Co-Chairman Session 9. Electrolytic Hydrogen Production J. W. Michel, Oak Ridge National Laboratory, Oak Ridge, Tennessee, Chairman C. Criss, University of Miami, Coral Gables, Florida, Co-Chairman Session 10. Hydrogen Utilization 1 G. Hagey, Environmental Protection Agency, Ann Arbor, Michigan, Chairman J. Anderson, University of Miami, Coral Gables, Florida, Co-Chairman Session 11. Thermochemical Hydrogen Production L. Topper, National Science Foundation, Washington, D.C., Chairman H. L. Craig, University of Miami, Coral Gables, Florida, Co-Chairman Session 12. Hydrogen Utilization II R. Murray, Oklahoma State University, Stillwater, Oklahoma, Chairman S. S. Lee, University of Miami, Coral Gables, Florida, Co-Chairman Session 13. Hydrogen Production Alternatives II J. E. Funk, University of Kentucky, Lexington, Kentucky, Chairman L. E. Poteat, University of Miami, Coral Gables, Florida, Co-Chairman Session 14. Hydrogen Utilization III K. Weil, Stevens Institute of Technology, Hoboken, New Jersey, Chairman H. J. Plass, University of Miami, Coral Gables, Florida, Co-Chairman SESSION OFFICIALS ix Session 15. Overviews and Alternatives K. C. Hoffman, Brookhaven National Laboratory. Long Island, New York, Chairman R. R. Adt, University of Miami, Coral Gables, Florida, Co-Chairman Session 16. Hydrogen in the Defense Sector R. C. Hamilton, Institute of Defense Analyses, Arlington, Virginia, Chairman S. RuQy, Advanced Research Projects Agency, Arlington, Virginia, Co-Chairman Session 17. Environmental Considerations J. D. Sauter, Lawrence Livermore Laboratory, UC, Livermore, California, Chairman L. G. Anderson, University of Miami, Coral Gables, Florida, Co-Chairman Session 18. Panel Discussion on the Hydrogen Economy D. P. Gregory, Institute of Gas Technology, Chicago, Illinois, Panel Moderator NOTE: For this edition of the Proceedings, the papers have been organized under five major headings rather than being pre sented in numerical order by sessions as in the preliminary edition. FOREWORD There are three important problems facing the world: deple tion of fossil fUels, demand for more energy, and the pollution of our environment. The world contains limited amounts of fossil fuels. They are being depleted, at an ever-growing rate. Peoples of the world are demanding more and more energy. This is due to the desires of peoples to improve their standard of living--and the standard of living is directly proportional to the energy con sumed. In addition, the world is demanding a cleaner environment to live in. Many of us, scientists and engineers, believe that replacing fossil fuels with the inexhaustible and clean synthetic fuel, hydrogen (produced from non-fossil primary sources of energy) will answer the above problems. Hydrogen, as the fUel of the post-fossil-fUel era, was pre dicted more than a hundred years ago by that great forecaster of the future, Jules Verne, in his novel The Mysterious Island: Water decomposed into its primitive elements, and decom posed doubtless by electricity, which will then have become a powerful and manageable force. • • . Yes, my friends, I believe that water will one day be employed as fuel, that hydrogen and oxygen, which constitute it, used singly or together, will furnish an inexhaustible source of heat and light of an intensity, of which coal is not capable •.•. I believe, then, that when the deposits of coal are exhausted, we shall heat and warm ourselves with water. Water will be the coal of the future. Today, two obvious yet pivotal points must be made when one speaks of the significance potentially of hydrogen-energy, as the authors have ably done in this collection from our THEME Confer ence: 1. Hydrogen is not a new energy source; it is an energy-carrier quite analogous to electricity, and xii FOREWORD 2. Hydrogen offers principally a long-range or strategic benefit in the sphere of energy de mand and supply. As such, the concept of the "Hydrogen Economy," whose facets are explored and critiqued within these pages, is but one option; an important one, deserving serious attention. Yet hydrogen energy is unlikely to displace all other approaches for moving energy to the consumer in wholesale fashion. It will, hopefully, become an optimal "part of the energy mix." Hydrogen energy derived from non-fossil primary energy sources- nuclear, geothermal, solar--clearly denotes the potential of evolv ing into a mandatory non-fossil fuel era. We may find the dawning of this era early in the 21st Century, provided our technological capability can be properly marshalled. Indeed, hydrogen offers it self as a means for evolving out of our inherently self-limited' fossil-fuel era. Following up the very successful Conference itself, held in Miami Beach on 18-20 March 1974, it is especially rewarding for us to present this formal edition of the Proceedings in view of the large number of requests we have received from allover the world. In this way, THEME-presented information relating to hydrogen energy will form a more permanent contribution to the technical literature on this subject of clearly growing importance. Howard P. Harrenstien, Chairman T. Nejat Veziroglu, Co-Cnairman and Editor--THEME Proceedings October 1974

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