Hybrid Organic-Inorganic Interfaces: Towards Advanced Functional Materials

991 Pages·2018·35.448 MB·English

by  Marie Helene Delville, Andreas Taubert

HybridOrganic–InorganicInterfaces
Hybrid Organic–Inorganic Interfaces
TowardsAdvancedFunctionalMaterials
EditedbyMarie-HeleneDelvilleandAndreasTaubert
Volume1
Hybrid Organic–Inorganic Interfaces
TowardsAdvancedFunctionalMaterials
EditedbyMarie-HeleneDelvilleandAndreasTaubert
Volume2
Editors AllbookspublishedbyWiley-VCHare
carefullyproduced.Nevertheless,authors,
Dr.Marie-HeleneDelville editors,andpublisherdonotwarrantthe
UniversitedeBordeaux informationcontainedinthesebooks,
InstitutdeChimiedelaMatiere includingthisbook,tobefreeoferrors.
CondenseedeBordeaux(ICMCB) Readersareadvisedtokeepinmindthat
CNRSUPR9048 statements,data,illustrations,procedural
87avenueduDr.A.Schweitzer detailsorotheritemsmayinadvertently
33608Pessac beinaccurate.
France
LibraryofCongressCardNo.:appliedfor
Prof.AndreasTaubert
UniversityofPotsdam BritishLibraryCataloguing-in-Publication
InstituteofChemistry Data
14476Potsdam Acataloguerecordforthisbookisavail-
Germany ablefromtheBritishLibrary.
Cover Bibliographicinformationpublishedby
fotolia/VAlex,fotolia/rafalkawa62 theDeutscheNationalbibliothek
TheDeutscheNationalbibliothek
liststhispublicationintheDeutsche
Nationalbibliografie;detailed
bibliographicdataareavailableonthe
Internetat<http://dnb.d-nb.de>.
©2018Wiley-VCHVerlagGmbH&Co.
KGaA,Boschstr.12,69469Weinheim,
Germany
Allrightsreserved(includingthoseof
translationintootherlanguages).Nopart
ofthisbookmaybereproducedinany
form–byphotoprinting,microfilm,or
anyothermeans–nortransmittedor
translatedintoamachinelanguage
withoutwrittenpermissionfromthe
publishers.Registerednames,trademarks,
etc.usedinthisbook,evenwhennot
specificallymarkedassuch,arenottobe
consideredunprotectedbylaw.
PrintISBN:978-3-527-34255-6
ePDFISBN:978-3-527-80710-9
ePubISBN:978-3-527-80712-3
MobiISBN:978-3-527-80711-6
oBookISBN:978-3-527-80713-0
CoverDesign SchulzGrafik-Design,
Fußgönheim,Germany
Typesetting SPiGlobal,Chennai,India
PrintingandBinding
Printedonacid-freepaper
v
ContentstoVolume1
Preface xv
1 Clay–OrganicInterfacesforDesignofFunctionalHybrid
Materials 1
PilarAranda,MargaritaDarder,BerndWicklein,GioraRytwo,and
EduardoRuiz-Hitzky
1.1 Introduction 1
1.1.1 ClayConcepts,Definitions,andClassification 1
1.1.2 Clay–OrganicInteractions:Clay–OrganicInterfacesand
FunctionalizationofClayMinerals 4
1.1.3 Clay–OrganicMaterialsandInterfaces:DesignandPreparationof
NanostructuredHybridswithFunctionalProperties 6
1.2 AnalyticalandMeasuringToolsinClay–OrganicHybridInterfaces 9
1.2.1 Composition 9
1.2.1.1 IndirectMethods 10
1.2.1.2 DirectMethods 12
1.2.2 Structure 14
1.2.2.1 VisualizationMethods 14
1.2.2.2 StructureDetermination 15
1.2.3 Activity 17
1.2.3.1 ParticleSizeoftheHybrids 18
1.2.3.2 SpecificAreaoftheHybrids 20
1.3 NanoarchitecturesfromOrganic–ClayInterfaces 21
1.3.1 Organic–InorganicInterfacesinPILCandOtherRelatedClay
Nanoarchitectures 23
1.3.2 Organic–InorganicInterfacesandPorousClayHeterostructures
(PCH) 26
1.3.3 Organic–InorganicInterfacestoProduceDelaminatedPorousClay
Heterostructures(DPCH) 28
1.3.4 AssemblyofNanoparticlestoFibrousClaysUsingOrganic–Inorganic
Interfaces 31
1.4 Clay-SupportedBiointerfacesandBiomedicalApplications 34
1.4.1 Clay-SupportedBiointerfaces 34
1.4.2 BiomedicalApplicationsofClays 38
1.4.2.1 NaturalClaysinPharmaceuticalApplications 38
vi contents
1.4.2.2 Clay-BasedHybridsforDrugDeliveryApplications 38
1.4.2.3 Clay-BasedHybridsforVaccineApplications 43
1.4.2.4 Clay-BasedHybridsinRegenerativeMedicine 44
1.5 ClayInterfacesforEnvironmentalProtection 47
1.5.1 NaturalClaysasAdsorbentsofOrganicPollutants 48
1.5.1.1 Clay-BasedHybridMaterialsasAdsorbentsofPollutants 49
1.5.1.2 EnvironmentalApplicationsofHybridMaterials 51
1.5.1.3 WaterPurificationandTreatmentofEffluents 51
1.5.1.4 FormulationsofPestManagementCompounds 53
1.6 ConcludingRemarks 54
ListofAbbreviations 56
References 58
2 HybridNanocompositesBasedonPrussianBlue-Type
NanoparticlesIncludedintoPolysaccharidesMatrices 85
JérômeLong,FrançoiseQuignard,YannickGuari,EricGuibal,ThierryVincent,
ChristianGuérin,LuísD.Carlos,andJouliaLarionova
2.1 Introduction 85
2.1.1 NanocompositeMaterialsBasedonCoordinationPolymersatthe
Nanoscale 85
2.1.2 ChoiceofthePolysaccharidesasMatrices 89
2.2 SynthesisofthePrussianBlue-TypeNanoparticlesIncludedinthe
ChitosanandtheAlginate 90
2.2.1 Step-by-StepApproachtoDesignthePrussianBlue-Type
Nanocomposites 90
2.2.2 Encapsulation 95
2.3 MagneticPropertiesoftheNanocomposites 97
2.4 PhotoluminescenceoftheNanocomposites 100
2.5 MonovalentCationSorption:ApplicationforDecontamination
ofCs+ 102
2.5.1 SorptionIsotherms 103
2.5.2 UptakeKinetics–DiffusionMechanisms 105
2.5.3 ModeofApplication 106
2.5.4 Applicationto137CsSorption 107
2.6 Conclusion 107
ListofAbbreviations 109
References 109
3 Self-HealingThermosettingComposites:Concepts,Chemistry,
andFutureAdvances 121
JamalSeyyedMonfaredZanjani,BurcuSanerOkan,YusufMenceloglu,and
MehmetYildiz
3.1 Introduction 121
3.2 Self-HealingProcessbyMicroencapsulation 122
3.2.1 Capsule-BasedSelf-HealingMechanism 122
3.2.2 CapsuleProductionTechniques 123
contents vii
3.3 Fiber-BasedSelf-HealingMechanisms 126
3.3.1 HollowGlassFibers 126
3.3.2 MicrovascularNetworks 127
3.3.3 Core–ShellElectrospunFibers 130
3.4 Self-HealingInterfacesbytheCombinationofOrganicandInorganic
Reinforcements 134
3.5 ChemistryofVascular-andCapsule-BasedSelf-HealingSystems 136
3.5.1 Ring-OpeningMetathesisPolymerization 136
3.5.2 EpoxyResin-BasedHealingReaction 138
3.5.3 Poly(dimethylsiloxane)-BasedHealingReaction 140
3.5.4 Solvent-BasedHealingReactions 140
3.5.5 OtherChemicalApproaches 141
3.6 FutureAdvancesinSelf-HealingofInterphases/Interfacesin
Composites 142
ListofAbbreviations 143
References 143
4 Silica–PolymerInterfaceandMechanicalReinforcementin
RubberNanocomposites 151
RobertoScotti,MassimilianoD’Arienzo,BarbaraDiCredico,LucaGiannini,
andFrancaMorazzoni
4.1 Introduction 151
4.2 Silica–RubberComposites 153
4.2.1 SurfaceandStructureofSilicaFiller 153
4.2.2 SilicaSurfaceModification:TheRoleofCouplingAgenttoImprove
theInteractionwithRubber 155
4.2.3 Dynamic-MechanicalPropertiesofFiller–Rubber
Nanocomposites 160
4.2.4 InfluenceofParticleAspectRatioontheMechanicalPropertiesof
RubberNCs 163
4.3 Filler–FillerandFiller–RubberInteractionsandSilica–Rubber
Interface 164
4.3.1 Filler–FillerInteractionandFillerNetworking 164
4.3.2 Filler–RubberInteraction 168
4.3.2.1 BoundRubber 169
4.3.2.2 ModelsofFiller–RubberInteractionandInterface 169
4.3.2.3 MicroscopyandSpectroscopyInvestigationsonSilica–Rubber
InteractionandInterface 173
4.4 Conclusions 183
ListofAbbreviations 184
References 186
5 SustainableOrganic–InorganicInterfacesinEnergy
Applications 199
RyanGuterman,JiayinYuan,LijiSobhana,PedroFardim,
SusanaGarcía-Mayo,andGermanSalazar-Alvarez
5.1 Introduction 199
viii contents
5.2 Poly(IonicLiquid)-BasedHybridMaterials 200
5.2.1 PIL/CarbonNanotubeHybrids 200
5.2.2 PIL/GrapheneHybrids 202
5.2.3 PIL/MetallicNanoparticleHybrids 204
5.2.4 PIL/SilicaHybrids 206
5.3 Polysaccharide-BasedHybrids 209
5.3.1 CelluloseNanofiber/ReducedGrapheneOxide/CarbonNanotube
Hybrids 209
5.3.2 LithiumTitanate/CarbonNanotube/CelluloseNanofiber
Hybrids 212
5.3.3 Chitosan/PhosphorylatedGrapheneOxideHybrids 214
5.3.4 Chitosan/SnO /PANITernaryHybrids 216
2
5.4 Protein-BasedHybrids 218
5.4.1 Silk/NanoparticleHybrid 219
5.4.2 Collagen/NanoparticleHybrids 226
5.5 ConcludingRemarks 228
ListofAbbreviations 228
References 229
6 HybridConjugatedPolymer–InorganicObjects:Elaborationof
NovelOrganicElectronicMaterials 241
AntoineBousquet,RogerC.Hiorns,ChristineDagron-Lartigau,and
LaurentBillon
6.1 Introduction 241
6.2 PolymerBrushes:GeneralFeatures 244
6.2.1 AnchoringGroup 244
6.2.2 GraftingTechniques 245
6.2.3 StructuralPropertiesofBrushes 246
6.3 Surface-InitiatedPolymerizationofConjugatedMonomers 247
6.3.1 KumadaCatalystTransferPolycondensation 247
6.3.1.1 GeneralFeatures 247
6.3.1.2 Surface-InitiatedKumadaCatalystTransferPolycondensation:
GraftingFrom 249
6.3.2 StilleCoupling 254
6.3.2.1 GeneralFeatures 254
6.3.2.2 Surface-InitiatedPolymerizationviaStilleCoupling 255
6.3.3 Suzuki–MiyauraCoupling 256
6.3.3.1 GeneralFeatures 256
6.3.3.2 Surface-InitiatedPolymerizationviaSuzukiCoupling 256
6.4 SurfaceFunctionalizationviathe“GraftingThrough”
Methodology 257
6.4.1 YamamotoPolymerization 257
6.4.1.1 GeneralFeatures 257
6.4.1.2 YamamotoSurfacePolymerization 257
6.4.2 SonogashiraPolymerization 258
6.4.2.1 GeneralFeatures 258
6.4.2.2 SonogashiraSurfacePolymerization 259
contents ix
6.4.3 GilchPolymerization 260
6.4.3.1 GeneralFeatures 260
6.4.3.2 SurfacePolymerizationviaGilchCoupling 261
6.5 “GraftingOnto”CouplingTechniques 262
6.5.1 DirectSubstrate–PolymerCouplingUsingKCTP 262
6.5.2 DirectPolymer–SubstrateCouplingusingOtherPolymerization
Technique 265
6.5.3 SurfaceAnchoringviaHeckCoupling 269
6.5.4 SurfaceAnchoringviaCycloaddition 271
6.5.5 SurfaceAnchoringviaEsterification/Amidification 273
6.6 ConjugatedPolymerBrushesApplications 274
6.6.1 SolarCells 274
6.6.1.1 HybridSolarCell 274
6.6.1.2 AdditivesintheActiveLayer 275
6.6.1.3 Hole/ElectronTransportingLayer 277
6.6.2 Light-EmittingDiode 278
6.6.3 Sensor 280
6.6.4 OtherApplications 280
6.7 Conclusion 281
ListofAbbreviations 282
References 284
7 HybridOrganic–InorganicNanostructuresforSpinSwitching
andSpintronicApplications 301
SayaniMajumdar,GerardS´liwin´ski,andYannGarcia
7.1 Introduction 301
7.2 FundamentalsofSpintronics 304
7.2.1 SpinInjection,Transport,andDetection 304
7.2.1.1 SpinInjection 305
7.2.1.2 SpinTransportandRelaxation 306
7.2.1.3 SpinDetection 307
7.2.2 GiantandTunnelingMagnetoresistance 307
7.3 HybridOrganic–InorganicSpinValvesandMagneticTunnel
Junctions 309
7.3.1 HybridSpinValves 309
7.3.2 HybridMagneticTunnelJunctions 312
7.3.3 TowardSingleMolecularDevices 314
7.4 PreparationMethodsofOrganicSemiconductorThinFilmsfor
Spintronics 315
7.4.1 SingleCrystalsandThinFilmFabrication 316
7.4.2 FabricationfromSolutions 318
7.4.3 VacuumDepositionMethods 319
7.4.3.1 HotWallEpitaxy 320
7.4.3.2 PhysicalVaporTransport 321
7.4.3.3 PulsedLaserDeposition 321
7.4.3.4 Matrix-AssistedPulsedLaserEvaporation 322
7.4.4 NanoparticlesandNanofibers 325
x contents
7.4.5 Morphology-DependentSpinTransportProperties 329
7.5 InorganicFerromagnet–OrganicInterface 330
7.5.1 InterfaceSpinPolarization 330
7.5.1.1 EnergyLevelAlignmentofFMElectrode/OSC 330
7.5.1.2 HybridSpinterfaceCharacterizationTechniquesandResults 332
7.5.2 InterfaceMagnetism 334
7.6 SpinCrossoverNanomaterials 336
7.6.1 SpinCrossoverThinFilms 338
7.6.1.1 SpinCrossoverHybrids 342
7.7 ConclusionandFuturePerspective 342
ListofAbbreviations 343
References 343
8 ApplicationofSol–GelMethodtoSynthesize
Organic–InorganicHybridCoatingstoMinimizeCorrosionin
MetallicSubstrates 355
RitaB.FigueiraandCarlosJ.R.Silva
8.1 Introduction 355
8.2 EvolutionoftheSol–GelProcessandItsMainApplications 357
8.3 GeneralSynthesisStrategiesforHybridMaterials:Chemistry
Background 361
8.4 HybridSol–GelCoatings:ApplicationsandCoatingMethods 363
8.5 OIHSol–GelCoatingsforCorrosionMitigation 373
8.5.1 OIHSol–GelCoatingsforCorrosionMitigationofIron-Based
Alloys 378
8.5.2 OIHSol–GelCoatingsforCorrosionMitigationofAluminum-Based
Alloys 379
8.5.3 OIHSol–GelCoatingsforCorrosionMitigationofCopper-Based
Alloys 381
8.5.4 OIHSol–GelCoatingsforCorrosionMitigationofZinc-Based
Alloys 381
8.6 PhysicalOIHGelMaterialsandCharacterizationofMetal/Coating
InterfacebyElectrochemicalMethods 382
8.6.1 PotentiodynamicElectrochemicalTechniques 387
8.6.2 ElectrochemicalImpedanceSpectroscopyMeasurements 392
References 399
9 Gas-OrganicandGas-InorganicInterfacialEffectsin
Gas/AdsorbentInteractions:TheCaseofCO /CH
2 4
Separation 413
MirthaA.O.Lourenço,JoséR.B.Gomes,andPaulaFerreira
9.1 Introduction 413
9.2 SelectiveCO CaptureAdsorbents 415
2
9.3 Organic–InorganicPorousMaterialsforCO /CH Separation 417
2 4
9.3.1 ModifiedCarbons 417
9.3.2 Metal–OrganicFrameworks 419