Handbook of Poylmer-Liquid Interaction Parameters and Solubility Parameters

762 Pages·1990·44.822 MB·English

by  Allan F.M. Barton

HANDBOOK
of
POLYMER-LIQUID
INTERACTION
PARAMETERS
and
SOLUBILITY
PARAMETERS
Allan F. M. Barton, Ph.D., F.N.Z.I.C., FR.A.C.1.
Associate Professor of Chemistry
Murdoch University
Perth
Western Australia
CRC PR ESS
Boca Raton London New York Washington, D.C.
Library of Congress Cataloging-in-Publication Data
Barton, Allan F. M.
CRC handbook of polymer-liquid interaction parameters and
solubility parameters /author, Allan F. M. Barton
p. cm.
Bibiolography: p.
ISBN 0-8493-3544-2
ISBN 13: 978-0-8493-3544-0
1. Polymers—Solubility—Handbooks, manuals, etc. I. Title.
II. Title: Handbook of polymer-liquid interaction parameters and
solubility parameters.
QD381.9.S65B37 1990
547.704542—dc20 89-15909
This book contains information obtained from authentic and highly regarded sources. Reprinted material is quoted with
permission, and sources are indicated. A wide variety of references are listed. Reasonable efforts have been made to publish
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© 1990 by CRC Press LLC
No claim to original U.S. Government works
International Standard Book Number 0-8493-3544-2
Library of Congress Card Number 89-15909
Printed in the United States of America 3 4 5 6 7 8 9
THE AUTHOR
Allan F. M. Barton received M.Sc. (First Class Honours) and Ph.D. degrees in chem­
istry from the University of Auckland, New Zealand. He then worked as a postdoctoral
fellow in the electrochemistry group of Southampton University in England from 1965 to
1968 before returning to New Zealand to an academic staff position at Victoria University
of Wellington. In 1974 he was appointed a foundation staff member of the new Murdoch
University in Perth, Western Australia, where he is now Associate Professor in Chemistry.
He is a Fellow of both the New Zealand Institute of Chemistry and the Royal Australian
Chemical Institute, and in 1975 he received the New Zealand Association of Scientists
Research Medal.
Professor Barton’s scientific contributions have been made as the result of the application
of a variety of physical and chemical techniques to pure and applied problems associated
with the properties of liquids and solutions, rates of chemical processes and resource uti­
lization. He has been involved with the Solubility Data Project of the International Union
of Pure and Applied Chemistry since 1975, and was foundation Chairman of the Liquid-
liquid Subcommittee of the Commission on Solubility Data. His publications include the
books The Dynamic Liquid State (1974), Resource Recovery and Recycling (1979), and
Handbook of Solubility Parameters and Other Cohesion Parameters (1983), as well as
reviews and research papers on high pressure molten salt electrochemistry, liquid transport
properties, kinetics of halate-halide reactions in aqueous solution, solid dissolution rates,
and phase transitions.
In addition to liquid state properties, his present interests include the production of
chemicals from biomass, the recovery of resources from wastes, and technology transfer
from research to industry.
To
Margaret June Ellis
ACKNOWLEDGMENTS
I am deeply indebted to
• the many scientists and techologists throughout the world who responded generously
to my requests for reprints and details of their work
• the Inter-Library Loans staff and Physical Sciences staff of Murdoch University Library
• Connie Carlsen, for her assistance with the bibliography compilation
• the Western Australian Product Innovation Centre Pty. Ltd., where I was based during
the second half of 1987 while on study leave from Murdoch University
• the members of my family, for their tolerance and support.
This volume includes a comprehensive compilation of cohesion parameters for polymers
as well as polymer-liquid interaction parameters.
The complementary cohesion parameter values for liquids and detailed information on
their applications appear in the companion volume CRC Handbook of Solubility Parameters
and Other Cohesion Parameters, first published in 1983 and updated in the forthcoming
Second Edition.
TABLE OF CONTENTS
PART I. INTRODUCTION............................................................................................... 1
Definitions and Relationships..................................................................................................3
Basic Quantities....................................................................................................................3
Polymer-Liquid Interaction Parameter, x............................................................................4
Theta Temperature...............................................................................................................5
Values of Xh Xs..........................................................................................................6
Differential and Integral Interaction Parameters.................................................................6
Determination of x Values..................................................................................................7
Concentration Dependence of x..........................................................................................9
Copolymers and Cosolvents...............................................................................................10
Equation-of-State Interaction Parameters..........................................................................10
Choice of Model.................................................................................................................10
Cohesion Parameters..........................................................................................................11
Cohesive Energy Density..................................................................................................11
Hildebrand Parameter, 8....................................................................................................11
Determination of 8 Values.................................................................................................13
Hansen Parameters..............................................................................................................14
Other Cohesion Parameters...............................................................................................15
Numerical Values of Cohesion Parameters.......................................................................16
Calculated Cohesion Parameters.......................................................................................17
Crystallinity.........................................................................................................................17
Citation of References............................................................................................................17
Solvents and Nonsolvents......................................................................................................18
Ordering of Entries in Part III...............................................................................................18
Glossary of Symbols.............................................................................................................20
PART II. MAJOR ENTRIES...........................................................................................23
1. ACRYLIC.........................................................................................................................25
2. polyACRYLONITRILE..................................................................................................30
3. ALKYD............................................................................................................................34
4. poly AMIDE.....................................................................................................................38
5. BISPHENOL A - EPICHLOROHYDRIN EPOXY.....................................................47
6. BISPHENOL A polySULFONE.....................................................................................52
7. polyBUTADIENE............................................................................................................56
8. polyBUTADIENE - ACRYLONITRILE.......................................................................64
9. BUTYL (polylSOBUTYLENE - ISOPRENE).............................................................72
10. polyAi-BUTYL ACRYLATE................... 77
11. polyw-BUTYL METHACRYLATE...............................................................................81
12. CELLULOSE ACETATE...............................................................................................88
13. CELLULOSE NITRATE................................................................................................96
14. polyCHLOROPRENE....................................................................................................101
15. polyCHLOROSTYRENE...............................................................................................109
16. polyCHLOROTRIFLUOROETHYLENE.....................................................................114
17. COAL.............................................................................................................................116
18. poly2,6-DIMETHYL-l,4-PHENYLENE OXIDE........................................................120
19. polyDIMETHYLSILOXANE........................................................................................125
20. EPOXY..........................................................................................................................148
21. polyETHYL ACRYLATE.............................................................................................153
22. ETHYL CELLULOSE..................................................................................................158
23. polyETHYLENE...........................................................................................................161
24. polyETHYLENE OXIDE.............................................................................................178
25. polyETHYLENE - PROPYLENE................................................................................193
26. ETHYLENE - PROPYLENE - DIENE terpolymer...................................................199
27. polyETHYLENE TEREPHTHALATE.......................................................................202
28. polyETHYLENE - VINYL ACETATE......................................................................207
29. polyETHYL METHACRYLATE.................................................................................214
30. HYDROXYPROPYL CELLULOSE...........................................................................219
31. polylSOBUTYLENE....................................................................................................222
32. polylSOPRENE............................................................................................................242
33. polyMETHYL ACRYLATE.......................................................................................259
34. polyMETHYL METHACRYLATE............................................................................265
35. poly PROPYLENE.........................................................................................................284
36. SILICONE...................................................................................................................293
37. poly STYRENE..............................................................................................................297
38. poIySTYRENE - ACRYLONITRILE.........................................................................343
39. polySTYRENE - BUTADIENE...................................................................................347
40. polySTYRENE - DIVINYLBENZENE......................................................................357
41. polyTETRAFLUOROETHYLENE..............................................................................361
42. polyVINYL ACETATE...............................................................................................362
43. polyVINYL ACETATE - VINYL ALCOHOL...........................................................376
44. polyVINYL ACETATE - VINYL CHLORIDE.........................................................378
45. polyVINYL ACETATE - VINYL CHLORIDE - VINYL ALCOHOL...................382
46. polyVINYL ALCOHOL...............................................................................................384
47. polyVINYL CHLORIDE..............................................................................................388
48. polyVINYL CHLORIDE - PLASTICIZER...............................................................403
49. polyVINYL METHYL ETHER..................................................................................411
PART III. FULL ALPHABETICAL LISTING...........................................................417
PART IV. BIBLIOGRAPHY.........................................................................................711

Part I: Introduction