Handbook of Adhesive Technology, Third Edition

659 Pages·2018·53.55 MB·English

by  Antonio Pizzi

Handbook of Adhesive Technology
Third Edition

Handbook of Adhesive Technology
Third Edition

Edited By
A. Pizzi and K. L. Mittal
CRC Press
Taylor & Francis Group
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Library of Congress Cataloging- in- Publication Data
Names: Pizzi, A. (Antonio), 1946- editor. | Mittal, K. L., 1945- editor.
Title: Handbook of adhesive technology / editors, A. Pizzi & K.L. Mittal.
Description: Third edition. | Boca Raton : CRC Press, 2018. | Includes
bibliographical references.
Identifiers: LCCN 2017026609| ISBN 9781498736442 (hardback : alk. paper) |
ISBN 9781351647267 (epub) | ISBN 9781498736473 (web pdf) | ISBN
9781351637763 (mobi/kindle)
Subjects: LCSH: Adhesives. | Sealing (Technology)
Classification: LCC TP968 .H347 2018 | DDC 668/.3--dc23
LC record available at https://lccn.loc.gov/2017026609
Visit the Taylor & Francis Web site at
http://www.taylorandfrancis.com
and the CRC Press Web site at
http://www.crcpress.com
Contents
Preface ..............................................................................................................................................ix
Editors ...............................................................................................................................................xi
List of Contributors ........................................................................................................................xiii
Part 1 Fundamental aspects
Chapter 1 Theories and Mechanisms of Adhesion .......................................................................3
Douglas J. Gardner
Chapter 2 Surface Mechanical (Physical) Treatments Prior to Bonding ....................................19
Janette Brezinová, Anna Guzanová, and Dagmar Draganovská
Chapter 3 Plasma Surface Treatment to Enhance Adhesive Bonding ........................................67
Nitu Bhatnagar
Chapter 4 Applications of Nanoparticles in Adhesives: Current Status .....................................95
Farid Taheri
Part 2 adhesive Classes
Chapter 5 Protein Adhesives .....................................................................................................145
Charles R. Frihart and Linda F. Lorenz
Chapter 6 Rubber-Based Adhesives ..........................................................................................177
A.A. Shybi, Siby Varghese, Hanna J. Maria, and Sabu Thomas
Chapter 7 Elastic Adhesives ......................................................................................................201
Johann Klein and Christina Despotopoulou
Chapter 8 Phenolic Resin Adhesives ........................................................................................223
Antonio Pizzi
Chapter 9 Natural Phenolic Adhesives Derived from Tannins and Lignin ..............................263
Antonio Pizzi
v
vi Contents
Chapter 10 Urea and Melamine Aminoresin Adhesives ............................................................283
Antonio Pizzi
Chapter 11 Polyurethane Adhesives ...........................................................................................321
Dennis G. Lay, Paul Cranley, and Antonio Pizzi
Chapter 12 Reactive Acrylic Adhesives ......................................................................................349
Emmanuel Pitia and John Hill
Chapter 13 Anaerobic Adhesives ................................................................................................367
David Birkett and David Condron
Chapter 14 Aerobic Acrylic Adhesives .......................................................................................385
Nigel Sweeney
Chapter 15 Biobased Acrylic Adhesives .....................................................................................395
Nigel Sweeney
Chapter 16 Silicone Adhesives and Sealants ..............................................................................405
Jerome M. Klosowski
Chapter 17 Epoxy Adhesives ......................................................................................................415
Anna Rudawska
Chapter 18 Bio-Sourced Epoxy Monomers and Polymers .........................................................443
Sylvain Caillol, Bernard Boutevin, and Jean-Pierre Pascault
Chapter 19 Pressure-Sensitive Adhesives ...................................................................................471
István Benedek
Part 3 applications of adhesives
Chapter 20 Adhesives in the Wood Industry ..............................................................................511
Manfred Dunky
Chapter 21 Bioadhesives in Drug Delivery ................................................................................575
Inderbir Singh and Paramjot
Contents vii
Chapter 22 Adhesives in Dentistry .............................................................................................591
Erdem Özdemir
Chapter 23 New Adhesive Technologies in the Footwear Industry ............................................603
Elena Orgilés-Calpena, Francisca Arán-Aís, Ana M. Torró-Palau,
and César Orgilés-Barceló
Chapter 24 Adhesives in the Automotive Industry .....................................................................619
Klaus Dilger and Michael Frauenhofer
Index ..............................................................................................................................................635

Preface
This volume constitutes the Third Edition of the popular book Handbook of Adhesive Technology
which made its debut in 1994 and the second edition appeared in 2003.
Adhesives are used in a myriad of applications to bond similar or dissimilar materials. The
applications of adhesives range from mundane DIY (Do-It-Yourself) projects to bonding composite
materials to fabricate structural elements. The use of adhesives is ubiquitous and adhesives find
their utility in a legion of varied and diverse industries, e.g., construction, aerospace, automotive,
packaging, microelectronics, dentistry, and medical (surgical procedures).
As a matter of fact, adhesive bonding is a branch of the general discipline called “zygology” (the
science of joining). The popularity of the use of adhesives for bonding is owing to the fact that adhe-
sive bonding offers many advantages vis-à-vis other methods of joining, e.g., riveting, welding, sol-
dering, nailing which, inter alia, can be enumerated as: uniform distribution of stress, lightweight
assemblies, cost effectiveness, and no danger from corrosion as is the case with nails.
Recently, there has been a flurry of R&D activity in ameliorating the existing adhesive products
and to come up with new and improved adhesives with desirable new functionalities and perfor-
mance characteristics. The holy grail in the field of adhesive bonding is the durability of adhesively
bonded joints against the deleterious effect of water. Water has been called the “God’s cruelest
liquid” or the worst enemy of adhesion. Also, there is presently an accelerated pace of research to
understand and control the factors affecting the performance of adhesively bonded joints.
This book (Third Edition) containing 24 chapters written by internationally renowned authors
is profusely illustrated and copiously referenced. It differs from its predecessor volumes in many
respects and its particular and important characteristics are: some completely new chapters are
included; some topics are the same but written by other subject matter experts with different per-
spective; and some topics are the same but these have been revised and updated. These days the
mantras are: nano, green, renewable, sustainable, biobased and biomimetic, and some new as well
as certain chapters on established adhesives address these catchwords.
The book is divided into three parts as follows: Part 1: Fundamental Aspects; Part 2: Adhesive
Classes; and Part 3: Applications of Adhesives. The topics covered include: theories and mecha-
nisms of adhesion; surface mechanical (physical) treatments prior to bonding; plasma surface treat-
ment to enhance adhesive bonding; applications of nanoparticles in adhesives; protein adhesives,
rubber-based adhesives; elastic adhesives; phenolic resin adhesives; natural phenolic adhesives
derived from tannins and lignin; urea and melamine aminoresin adhesives; polyurethane adhesives;
reactive acrylic adhesives; anaerobic adhesives; aerobic acrylic adhesives; biobased acrylic adhe-
sives; silicone adhesives; epoxy adhesives; biosourced epoxy resins; pressure-sensitive adhesives
and products; adhesives in the wood industry; bioadhesives in drug delivery; adhesives in dentistry;
new adhesive technologies in the footwear industry; and adhesives in the automotive industry.
This compendium contains a wealth of information in the arena of adhesives and adhesive bond-
ing and represents a commentary on the current state of the knowledge and R&D activity in the
domain of adhesives—a fascinating class of materials. Anyone interested centrally or tangentially
in adhesives should find this volume of much interest and value. The field of adhesive bonding
is veritably inter-, multi- and transdisciplinary, so researchers in seemingly different disciplines
should find the information compiled here useful, particularly it should appeal to polymer scientists,
surface chemists, materials scientists, adhesionists and those who need to use adhesives.
The editors sincerely hope that this Third Edition will receive the same warm welcome from
the scientific and technological community as its predecessors. Here we have attempted to take due
cognizance of the many important aspects of adhesives and adhesive bonding.
ix