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Lecture Notes in Energy 12 Breda Kegl Marko Kegl Stanislav Pehan Green Diesel Engines Biodiesel Usage in Diesel Engines Lecture Notes in Energy 12 For furthervolumes: http://www.springer.com/series/8874 ThiSisaFMBlankPage Breda Kegl (cid:129) Marko Kegl (cid:129) Stanislav Pehan Green Diesel Engines Biodiesel Usage in Diesel Engines BredaKegl MarkoKegl StanislavPehan FacultyofMechanicalEngineering UniversityofMaribor Maribor Slovenia ISSN2195-1284 ISSN2195-1292(electronic) ISBN978-1-4471-5324-5 ISBN978-1-4471-5325-2(eBook) DOI10.1007/978-1-4471-5325-2 SpringerLondonHeidelbergNewYorkDordrecht ©Springer-VerlagLondon2013 Thisworkissubjecttocopyright.AllrightsarereservedbythePublisher,whetherthewholeorpart of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation,broadcasting,reproductiononmicrofilmsorinanyotherphysicalway,andtransmissionor informationstorageandretrieval,electronicadaptation,computersoftware,orbysimilarordissimilar methodologynowknownorhereafterdeveloped.Exemptedfromthislegalreservationarebriefexcerpts inconnectionwithreviewsorscholarlyanalysisormaterialsuppliedspecificallyforthepurposeofbeing enteredandexecutedonacomputersystem,forexclusiveusebythepurchaserofthework.Duplication ofthispublicationorpartsthereofispermittedonlyundertheprovisionsoftheCopyrightLawofthe Publisher’s location, in its current version, and permission for use must always be obtained from Springer.PermissionsforusemaybeobtainedthroughRightsLinkattheCopyrightClearanceCenter. ViolationsareliabletoprosecutionundertherespectiveCopyrightLaw. The use of general descriptive names, registered names, trademarks, service marks, etc. in this publicationdoesnotimply,evenintheabsenceofaspecificstatement,thatsuchnamesareexempt fromtherelevantprotectivelawsandregulationsandthereforefreeforgeneraluse. While the advice and information in this book are believed to be true and accurate at the date of publication,neithertheauthorsnortheeditorsnorthepublishercanacceptanylegalresponsibilityfor anyerrorsoromissionsthatmaybemade.Thepublishermakesnowarranty,expressorimplied,with respecttothematerialcontainedherein. Printedonacid-freepaper SpringerispartofSpringerScience+BusinessMedia(www.springer.com) Contents 1 Introduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 2 DieselEngineCharacteristics. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5 2.1 InjectionCharacteristics. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10 2.1.1 ExperimentalTechniques. . . . . . . . . . . . . . . . . . . . . . . . 16 2.1.2 MathematicalModelingandSimulation. . . . . . . . . . . . . 19 2.2 FuelSprayCharacteristics. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27 2.2.1 ExperimentalTechniques. . . . . . . . . . . . . . . . . . . . . . . . 29 2.2.2 MathematicalModelingandSimulation. . . . . . . . . . . . . 30 2.3 EnginePerformance,Ecology,andEconomyCharacteristics. . . 36 2.3.1 ExperimentalTechniques. . . . . . . . . . . . . . . . . . . . . . . . 37 2.3.2 MathematicalModelingandSimulation. . . . . . . . . . . . . 43 2.4 Discussion. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 45 References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 48 3 GuidelinesforImprovingDieselEngineCharacteristics. . . . . . . . . 51 3.1 EngineManagement. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 51 3.2 ExhaustGasAfterTreatment. . . . . . . . . . . . . . . . . . . . . . . . . . 54 3.3 AlternativeFuels. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 63 3.3.1 WaterinDieselEmulsion. . . . . . . . . . . . . . . . . . . . . . . 64 3.3.2 NaturalGasandLiquefiedPetroleumGas. . . . . . . . . . . . 69 3.3.3 MethaneandPropane. . . . . . . . . . . . . . . . . . . . . . . . . . 69 3.3.4 DimethylEtherandDimethylCarbonate. . . . . . . . . . . . . 72 3.3.5 Fischer–TropschDiesel. . . . . . . . . . . . . . . . . . . . . . . . . 73 3.3.6 Hydrogen. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 74 3.3.7 Alcohols. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 75 3.3.8 VegetableOils,Bioethanol,andBiodiesel. . . . . . . . . . . . 76 3.4 Discussion. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 81 References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 89 v vi Contents 4 BiodieselasDieselEngineFuel. . . . . . . . . . . . . . . . . . . . . . . . . . . . 95 4.1 BiodieselSources. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 95 4.2 BiodieselProperties. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 97 4.2.1 MeasurementMethodsforBiodieselProperties. . . . . . . . 102 4.2.2 RequirementsforBiodieselProperties. . . . . . . . . . . . . . 108 4.2.3 PropertiesofBiodieselsfromVariousSources. . . . . . . . 108 4.2.4 ImprovementofBiodieselProperties. . . . . . . . . . . . . . . 115 4.3 Discussion. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 119 References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 122 5 EffectsofBiodieselUsageonInjectionProcessCharacteristics. . . 127 5.1 InjectionPressure. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 128 5.1.1 InfluenceofBiodieselProperties. . . . . . . . . . . . . . . . . . 129 5.1.2 InfluenceofEngine-OperatingRegime. . . . . . . . . . . . . . 132 5.1.3 InfluenceofTemperature. . . . . . . . . . . . . . . . . . . . . . . . 133 5.2 InjectionTiming. .. . . . . . . . . . . . . . . .. . . . . . . . . . . . . . .. . . 135 5.2.1 InfluenceofBiodieselProperties. . . . . . . . . . . . . . . . . . 136 5.2.2 InfluenceofEngine-OperatingRegime. . . . . . . . . . . . . . 138 5.2.3 InfluenceofTemperature. . . . . . . . . . . . . . . . . . . . . . . . 138 5.3 InjectionRate. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 139 5.3.1 InfluenceofBiodieselProperties. . . . . . . . . . . . . . . . . . 141 5.3.2 InfluenceofEngine-OperatingRegime. . . . . . . . . . . . . . 142 5.3.3 InfluenceofTemperature. . . . . . . . . . . . . . . . . . . . . . . . 143 5.4 Discussion. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 148 References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 151 6 EffectsofBiodieselUsageonFuelSprayCharacteristics. . . . . . . . 153 6.1 SprayPenetration. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 154 6.1.1 InfluenceofBiodieselProperties. . . . . . . . . . . . . . . . . . 154 6.1.2 InfluenceofEngineOperatingRegime. . . . . . . . . . . . . . 159 6.2 SprayAngle. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 164 6.2.1 InfluenceofBiodieselProperties. . . . . . . . . . . . . . . . . . 165 6.2.2 InfluenceofEngineOperatingRegime. . . . . . . . . . . . . . 167 6.3 SauterMeanDiameter. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 169 6.3.1 InfluenceofBiodieselProperties. . . . . . . . . . . . . . . . . . 170 6.3.2 InfluenceofEngineOperatingRegime. . . . . . . . . . . . . . 173 6.4 Discussion. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 174 References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 176 7 EffectsofBiodieselUsageonEnginePerformance,Economy, Tribology,andEcology. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 179 7.1 EnginePerformance,Economy,andTribologyCharacteristics. . . 180 7.1.1 InfluenceofBiodieselProperties. . . . . . . . . . . . . . . . . . 180 7.1.2 InfluenceofEngineType. . . . . . . . . . . . . . . . . . . . . . . . 189 7.1.3 InfluenceofEngineOperatingRegime. . . . . . . . . . . . . . 195 Contents vii 7.2 EngineHarmfulEmissions. . . . . . . . . . . . . . . . . . . . . . . . . . . . 197 7.2.1 InfluenceofBiodieselProperties. . . . . . . . . . . . . . . . . . 198 7.2.2 InfluenceofEngineType. . . . . . . . . . . . . . . . . . . . . . . . 203 7.2.3 InfluenceofEngineOperatingRegime. . . . . . . . . . . . . . 209 7.3 Discussion. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 214 References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 217 8 ImprovementofDieselEngineCharacteristicsbyNumeric Optimization. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 223 8.1 SystematicOptimization. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 223 8.1.1 OptimizationMethods. . . . . . . . . . . . . . . . . . . . . . . . . . 224 8.1.2 TransformingaPracticalOptimizationProbleminto theStandardForm. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 225 8.1.3 TheRoleoftheResponseEquation. . . . . . . . . . . . . . . . 228 8.2 EngineOptimizationforBiodieselUsage. . .. . . . . . . . . . . . .. . 229 8.2.1 ParameterizationoftheInjectionSystem. . . . . . . . . . . . 229 8.2.2 OptimizationofInjectionRateHistories. . . . . . . . . . . . . 235 8.2.3 OptimizationofFuelSprayAtomization. . . . . . . . . . . . . 242 8.3 ImplementationoftheOptimizationProcess. . . . . . . . . . . . . . . 248 8.3.1 OptimizationbyUsingBlack-BoxSimulationSoftware... 250 8.4 Discussion. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 253 References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 254 9 ConcludingRemarks. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 257 Index. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 259 Chapter 1 Introduction Moderndieselenginespowermuchoftheworld’sequipmentand,mostnotably,are prime movers commonly available today. Among personal and commercial vehicles, the diesel engines hold a significant market share worldwide. And their shareandpopularityarebothincreasing. Traditionally, diesel engines run on mineral diesel, which is produced from crude oil. This fact comes with several consequences, giving rise to various concerns, which cannot be put aside. In fact, they have to be, and in many areas theyalreadyare,addresseddecisivelyinordertoensurelong-termandsustainable useoftheseexcellentmachinesinthefuture. Thefirstconcernisthelimitedcrudeoilreserves.Crudeoilcoversabout37%of world’senergydemands(Fig.1.1)(AsifandMuneer2007;Dorianetal.2006;Kegl 2012;Kja¨rstadandJohnsson2009). World’s ultimate oil reserves are estimated at 2 trillion barrels, of which 900 billion barrels have already been consumed (Bentley 2002). This is the total volume that would have been produced when production eventually ceases. The globaldailyconsumptionofoilequalsabout75millionbarrels.Variouscountries areatdifferentstagesoftheirreservedepletioncurves.Manyofthem,suchasUSA, are past their midpoint and are in terminal decline, whereas others are close to midpointsuchasUKandNorway.Luckily,thefivemajorGulfproducers—Saudi Arabia, Iraq, Iran, Kuwait, and United Arab Emirates—are at an early stage of depletion.Anyhow,aquickcalculationrevealsthatatpresentproductionratesoil suppliesarepredictedtolastonlyabout40years.Thisestimatemightnotbevery accurate,butthischangesnothingonthefactthatwehavetosearchforalternative fuels,onwhichthedieselengineswillruninthefuture.Ofcourse,thesealternative fuels should preferably be environment-friendly and produced from renewable sources. Thesecondconcernistheimmensequantityoffuel,consumedbydieselengines allovertheworld.Avastmajorityofdieselenginesareengagedinroadtransport, which accounts for about 81 % of total energy used for transportation (Fig. 1.2) (Chapman 2007). Besides the road transport, diesel engines are also engaged in B.Kegletal.,GreenDieselEngines,LectureNotesinEnergy12, 1 DOI10.1007/978-1-4471-5325-2_1,©Springer-VerlagLondon2013 2 1 Introduction Fig.1.1 Sharesofglobalenergysources Fig.1.2 Energyconsumptionsharesinthetransportsector railwaytransport,navaltransport,electricitygeneration,andsoon.Anyhow,even if we manage to develop efficient alternative fuel production, the immense fuel volume,consumeddailybyworld’sdieselengines,willstillbeaproblem.Forthis reason,tryingtoreducethedieselenginefuelconsumptiontothelimitsofpossible shouldbeworthofeveryeffort. Thethirdconcernisrelatedtothechemicalprocessoftransformationofinternal fuel energy into mechanical work or, more precisely, to the exhaust emissions of this process. A diesel engine burns the fuel under high pressure and emits the burning products into the environment. Therefore, diesel engines are one of the significantcontributorstoenvironmentalpollutionworldwide,withlargeincreases expectedinvehiclepopulationandvehiclemilestraveled.Adieselengineproduces

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