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THIRD EDITION GAS Turbine Combustion Alternative Fuels and Emissions THIRD EDITION GAS Turbine Combustion Alternative Fuels and Emissions Arthur H. Lefebvre and Dilip R. Ballal Boca Raton London New York CRC Press is an imprint of the Taylor & Francis Group, an informa business CRC Press Taylor & Francis Group 6000 Broken Sound Parkway NW, Suite 300 Boca Raton, FL 33487-2742 © 2010 by Taylor and Francis Group, LLC CRC Press is an imprint of Taylor & Francis Group, an Informa business No claim to original U.S. Government works Printed in the United States of America on acid-free paper 10 9 8 7 6 5 4 3 2 1 International Standard Book Number-13: 978-1-4200-8605-8 (Ebook-PDF) This book contains information obtained from authentic and highly regarded sources. Reasonable efforts have been made to publish reliable data and information, but the author and publisher cannot assume responsibility for the validity of all materials or the consequences of their use. The authors and publishers have attempted to trace the copyright holders of all material reproduced in this publication and apologize to copyright holders if permission to publish in this form has not been obtained. If any copyright material has not been acknowledged please write and let us know so we may rectify in any future reprint. Except as permitted under U.S. Copyright Law, no part of this book may be reprinted, reproduced, transmit- ted, or utilized in any form by any electronic, mechanical, or other means, now known or hereafter invented, including photocopying, microfilming, and recording, or in any information storage or retrieval system, without written permission from the publishers. For permission to photocopy or use material electronically from this work, please access www.copyright. com (http://www.copyright.com/) or contact the Copyright Clearance Center, Inc. (CCC), 222 Rosewood Drive, Danvers, MA 01923, 978-750-8400. CCC is a not-for-profit organization that provides licenses and registration for a variety of users. For organizations that have been granted a photocopy license by the CCC, a separate system of payment has been arranged. Trademark Notice: Product or corporate names may be trademarks or registered trademarks, and are used only for identification and explanation without intent to infringe. Visit the Taylor & Francis Web site at http://www.taylorandfrancis.com and the CRC Press Web site at http://www.crcpress.com Contents Preface ..................................................................................................................xvii Authors .................................................................................................................xix 1. Basic Considerations ......................................................................................1 1.1 Introduction ...........................................................................................1 1.2 Early Combustor Developments .........................................................2 1.2.1 Britain ........................................................................................3 1.2.2 Germany ....................................................................................5 1.2.2.1 Jumo 004 ....................................................................5 1.2.2.2 BMW 003 ...................................................................6 1.2.3 The United States .....................................................................6 1.3 Basic Design Features ...........................................................................8 1.4 Combustor Requirements ....................................................................9 1.5 Combustor Types ................................................................................10 1.5.1 Tubular ....................................................................................11 1.5.2 Tuboannular ...........................................................................11 1.5.3 Annular ...................................................................................12 1.6 Diffuser .................................................................................................14 1.7 Primary Zone .......................................................................................15 1.8 Intermediate Zone ...............................................................................16 1.9 Dilution Zone .......................................................................................17 1.10 Fuel Preparation ..................................................................................18 1.10.1 Pressure-Swirl Atomizers ....................................................18 1.10.2 Airblast Atomizer .................................................................19 1.10.3 Gas Injection ..........................................................................20 1.11 Wall Cooling ........................................................................................20 1.11.1 Wall-Cooling Techniques ....................................................22 1.12 Combustors for Low Emissions ........................................................23 1.13 Combustors for Small Engines ..........................................................26 1.14 Industrial Chambers ...........................................................................28 1.14.1 Aeroderivative Engines .......................................................31 References .......................................................................................................33 Bibliography ....................................................................................................33 2. Combustion Fundamentals ........................................................................35 2.1 Introduction .........................................................................................35 2.1.1 Deflagration ............................................................................35 2.1.2 Detonation...............................................................................35 2.2 Classification of Flames ......................................................................36 2.3 Physics or Chemistry? ........................................................................37 v vi Contents 2.4 Flammability Limits ...........................................................................37 2.5 Global Reaction-Rate Theory .............................................................38 2.5.1 Weak Mixtures .......................................................................39 2.5.2 Rich Mixtures .........................................................................39 2.6 Laminar Premixed Flames ................................................................41 2.6.1 Factors Influencing Laminar Flame Speed ........................41 2.6.1.1 Equivalence Ratio ...................................................41 2.6.1.2 Initial Temperature ................................................42 2.6.1.3 Pressure ...................................................................42 2.7 Laminar Diffusion Flames.................................................................42 2.8 Turbulent Premixed Flames ..............................................................43 2.9 Flame Propagation in Heterogeneous Mixtures of Fuel Drops, Fuel Vapor, and Air ................................................................45 2.10 Droplet and Spray Evaporation .........................................................49 2.10.1 Heat-Up Period ......................................................................50 2.10.2 Evaporation Constant ...........................................................51 2.10.3 Convective Effects ................................................................52 2.10.4 Effective Evaporation Constant ..........................................52 2.10.5 Spray Evaporation .................................................................54 2.10.6 Some Recent Developments ................................................54 2.11 Ignition Theory ....................................................................................55 2.11.1 Gaseous Mixtures .................................................................55 2.11.2 Heterogeneous Mixtures .....................................................56 2.12 Spontaneous Ignition .........................................................................64 2.13 Flashback ..............................................................................................69 2.14 Stoichiometry .......................................................................................70 2.15 Adiabatic Flame Temperature ...........................................................71 2.15.1 Factors Influencing the Adiabatic Flame Temperature ....................................................................71 2.15.1.1 Fuel/Air Ratio ......................................................71 2.15.1.2 Initial Air Temperature ......................................71 2.15.1.3 Pressure ................................................................72 2.15.1.4 Inlet-Air Vitiation ................................................72 Nomenclature .................................................................................................73 References .......................................................................................................74 Bibliography ....................................................................................................77 3. Diffusers .........................................................................................................79 3.1 Introduction .........................................................................................79 3.2 Diffuser Geometry ..............................................................................81 3.3 Flow Regimes ......................................................................................82 3.4 Performance Criteria ..........................................................................83 3.4.1 Pressure-Recovery Coefficient .............................................84 3.4.2 Ideal Pressure-Recovery Coefficient ...................................84 Contents vii 3.4.3 Overall Effectiveness .............................................................85 3.4.4 Loss Coefficient ......................................................................85 3.4.5 Kinetic-Energy Coefficient ...................................................86 3.5 Performance .........................................................................................86 3.5.1 Conical Diffusers ...................................................................87 3.5.2 Two-Dimensional Diffusers .................................................88 3.5.3 Annular Diffusers ..................................................................89 3.6 Effect of Inlet Flow Conditions .........................................................90 3.6.1 Reynolds Number ..................................................................91 3.6.2 Mach Number ........................................................................91 3.6.3 Turbulence ..............................................................................92 3.6.4 Swirl .........................................................................................93 3.7 Design Considerations .......................................................................93 3.7.1 Faired Diffusers .....................................................................93 3.7.2 Dump Diffusers .....................................................................97 3.7.2.1 Influence of Liner Depth Ratio .............................98 3.7.3 Splitter Vanes ..........................................................................99 3.7.4 Vortex-Controlled Diffuser ................................................100 3.7.5 Hybrid Diffuser ....................................................................101 3.7.6 Diffusers for Tubular and Tuboannular Combustors .......................................................................104 3.7.7 Testing of Diffusers .............................................................105 3.8 Numerical Simulations.....................................................................106 Nomenclature ...............................................................................................108 References .....................................................................................................109 4. Aerodynamics..............................................................................................113 4.1 Introduction .......................................................................................113 4.2 Reference Quantities .........................................................................114 4.3 Pressure-Loss Parameters ................................................................114 4.4 Relationship between Size and Pressure Loss ..............................117 4.5 Flow in the Annulus .........................................................................118 4.6 Flow through Liner Holes................................................................120 4.6.1 Discharge Coefficient ..........................................................120 4.6.2 Initial Jet Angle ....................................................................123 4.7 Jet Trajectories ....................................................................................124 4.7.1 Experiments on Single Jets .................................................124 4.7.2 Penetration of Multiple Jets ................................................126 4.8 Jet Mixing ...........................................................................................129 4.8.1 Cylindrical Ducts .................................................................129 4.8.2 Rectangular Ducts ...............................................................131 4.8.2.1 Influence of Density Ratio ...................................132 4.8.3 Annular Ducts ......................................................................133 viii Contents 4.9 Temperature Traverse Quality ........................................................133 4.10 Dilution Zone Design .......................................................................135 4.10.1 Cranfield Design Method ..................................................136 4.10.2 NASA Design Method .......................................................137 4.10.3 Comparison of Cranfield and NASA Design Methods ...............................................................137 4.11 Correlation of Pattern Factor Data ..................................................138 4.12 Rig Testing for Pattern Factor ..........................................................140 4.13 Swirler Aerodynamics ......................................................................140 4.14 Axial Swirlers ....................................................................................142 4.14.1 Swirl Number ......................................................................143 4.14.2 Size of Recirculation Zone .................................................144 4.14.3 Flow Reversal ......................................................................145 4.14.4 Influence of Swirler Exit Geometry ..................................146 4.15 Radial Swirlers...................................................................................146 4.16 Flat Vanes Versus Curved Vanes ....................................................147 Nomenclature ...............................................................................................147 References .....................................................................................................149 5. Combustion Performance .........................................................................153 5.1 Introduction .......................................................................................153 5.2 Combustion Efficiency .....................................................................153 5.2.1 The Combustion Process ....................................................154 5.3 Reaction-Controlled Systems ..........................................................154 5.3.1 Burning Velocity Model ......................................................155 5.3.2 Stirred Reactor Model .........................................................159 5.4 Mixing-Controlled Systems .............................................................160 5.5 Evaporation-Controlled Systems ....................................................161 5.6 Reaction- and Evaporation-Controlled Systems ...........................165 5.7 Flame Stabilization ...........................................................................167 5.7.1 Definition of Stability Performance...................................167 5.7.2 Measurement of Stability Performance ............................168 5.7.3 Water Injection Technique ..................................................170 5.8 Bluff-Body Flameholders .................................................................173 5.8.1 Experimental Findings on Bluff-Body Flame Stabilization ..........................................................................173 5.8.1.1 Homogeneous Mixtures ......................................173 5.8.1.2 Heterogeneous Mixtures .....................................177 5.8.2 Summary of Experimental Findings ................................179 5.9 Mechanisms of Flame Stabilization ...............................................179 5.9.1 Homogeneous Mixtures .....................................................181 5.9.2 Heterogeneous Mixtures ....................................................182 5.10 Flame Stabilization in Combustion Chambers .............................183 Contents ix 5.10.1 Influence of Mode of Fuel Injection .................................184 5.10.2 Correlation of Experimental Data ....................................185 5.11 Ignition ...............................................................................................188 5.12 Assessment of Ignition Performance .............................................189 5.13 Spark Ignition ....................................................................................190 5.13.1 The High-Energy Ignition Unit ........................................190 5.13.2 The Surface Discharge Igniter ..........................................191 5.13.2.1 Igniter Performance ..........................................192 5.13.2.2 Igniter Design ....................................................193 5.13.2.3 Igniter Life ..........................................................194 5.14 Other Forms of Ignition ...................................................................195 5.14.1 Torch Igniter ........................................................................195 5.14.2 Glow Plug .............................................................................196 5.14.3 Hot-Surface Ignition ...........................................................196 5.14.4 Plasma Jet .............................................................................197 5.14.5 Laser Ignition ......................................................................197 5.14.6 Chemical Ignition ...............................................................198 5.14.7 Gas Addition .......................................................................199 5.14.8 Oxygen Injection .................................................................199 5.15 Factors Influencing Ignition Performance .....................................199 5.15.1 Ignition System ...................................................................200 5.15.1.1 Spark Energy ......................................................200 5.15.1.2 Spark Duration ...................................................200 5.15.1.3 Sparking Rate .....................................................202 5.15.1.4 Igniter Location ..................................................202 5.15.2 Flow Variables .....................................................................203 5.15.2.1 Air Pressure ........................................................203 5.15.2.2 Air Temperature ................................................204 5.15.2.3 Air Velocity .........................................................205 5.15.2.4 Turbulence ..........................................................206 5.15.3 Fuel Parameters ...................................................................207 5.15.3.1 Fuel Type .............................................................207 5.15.3.2 Fuel/Air Ratio ....................................................207 5.15.3.3 Spray Characteristics ........................................208 5.15.3.4 Fuel Temperature ...............................................209 5.16 The Ignition Process .........................................................................209 5.16.1 Factors Influencing Phase 1 ...............................................210 5.16.2 Factors Influencing Phase 2 ...............................................210 5.16.3 Factors Influencing Phase 3 ...............................................211 5.17 Methods of Improving Ignition Performance ...............................211 5.17.1 Correlation of Experimental Data ....................................212 Nomenclature ...............................................................................................214 References .....................................................................................................216

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