Functional Supramolecular Architectures: For Organic Electronics and Nanotechnology, 2 Volume Set

1017 Pages·10.562 MB·English

by  Samorı P., Cacialli F. (Ed.)

Edited by @WILEY-YCH
Paolo Samor' and Franco Cacialli
Functional
Supramolecular
Arch itectu res
For Organic Electronics and Nanotechnology
Volume 1
Editedby
PaoloSamor`ıand
FrancoCacialli
FunctionalSupramolecular
Architectures
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Edited by
Paolo Samorì and Franco Cacialli
Functional Supramolecular Architectures
for Organic Electronics and Nanotechnology
Volume 1
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VII
Contents
Preface XXIII
ListofContributors XXV
Volume1
PartOne ModelingandTheory 1
1 ChargeTransportinOrganicSemiconductors:AMultiscaleModeling 3
NicolasMartinelli,YoannOlivier,LucaMuccioli,AndreaMinoia,
PatrickBrocorens,Mari-CarmenRuizDelgado,ClaudioZannoni,
DavidBeljonne,RobertoLazzaroni,Jean-LucBrédas,andJérômeCornil
1.1 Introduction 3
1.2 OrganicSingleCrystals 6
1.2.1 MolecularParametersforChargeTransport 6
1.2.2 InfluenceofIntermolecularVibrations 9
1.2.3 ChargeMobilityValues 13
1.3 TetrathiafulvaleneDerivatives 15
1.4 PolythiopheneDerivatives 18
1.5 PhthalocyanineStacks 22
1.5.1 StructuralProperties 22
1.5.2 ChargeTransportProperties 25
1.6 PolymerDielectrics 27
1.6.1 ElectrostaticDisorder 29
1.6.2 ChargeMobilityValues 29
1.7 Outlook 31
References 33
2 MonteCarloStudiesofPhaseTransitionsandCooperativeMotion
inLangmuirMonolayerswithInternalDipoles 39
ChristopherB.George,MarkA.Ratner,andIgalSzleifer
2.1 Introduction 39
2.2 ComputationalDetails 40
FunctionalSupramolecularArchitectures.EditedbyPaoloSamorìandFrancoCacialli
Copyright(cid:2)2011WILEY-VCHVerlagGmbH&Co.KGaA,Weinheim
ISBN:978-3-527-32611-2
VIII Contents
2.3 ResultsandDiscussion 42
2.3.1 UnchargedSystem 42
2.3.2 ChargedSystem 45
2.4 Summary 49
References 51
3 MoleculesonGoldSurfaces:WhatTheyDoandHowThey
GoAroundtoDoIt 55
NadjaSändigandFrancescoZerbetto
3.1 Introduction 55
3.2 ASimpleDescriptionoftheGeometricalStructureofMetals 57
3.3 ASimpleDescriptionoftheGeometricalStructureofMolecules 58
3.4 ElectronegativityGovernsChemicalInteractions:ChargeEquilibration,
QEq,Models 58
3.5 ASimpleDescriptionoftheInteractionbetweenMetalSurfaces
andMolecules 59
3.6 PresenceofanExternalElectricPotentialorField 60
3.7 GeneralityoftheModelandItsTransferability 60
3.8 ThiolatesonGold 61
3.9 AdsorptionofaLargeMolecule:C 65
60
3.10 SimplePackingProblems 67
3.11 ThePresenceofanElectrostaticPotential 69
3.12 ChallengesandConclusion 71
References 72
PartTwo SupramolecularSyntheticChemistry 79
4 ConjugatedPolymerSensors:Design,Principles,
andBiologicalApplications 81
MindyLevineandTimothyM.Swager
4.1 Introduction 81
4.1.1 Amplification 81
4.1.2 RoleofDimensionalityandSensoryMechanism 82
4.2 WaterSolubility 83
4.2.1 ConjugatedPolyelectrolytes 83
4.2.2 NonspecificBinding 84
4.2.3 NonionicWater-SolublePolymers 86
4.3 ProteinDetection 89
4.3.1 Introduction 89
4.3.2 ProteaseDetection 89
4.3.3 KinaseandPhosphataseDetection 93
4.3.4 LectinDetection 94
4.3.5 OtherProteinDetection 95
4.3.6 ProteinConformationDetection 96
4.4 DNADetection 97
Contents IX
4.4.1 Polythiophene-BasedDNADetection 97
4.4.2 FRET-BasedDNADetection 98
4.5 BacteriaDetection 101
4.5.1 Introduction 101
4.5.2 Mannose-ContainingPolymers 102
4.5.3 DetectionofBacterialExcretionProducts 103
4.6 Electron-DeficientPolymers 104
4.6.1 FluorinatedPPEs 104
4.7 Aggregation-BasedDetection 106
4.7.1 Introduction 106
4.7.2 DetectionviaPolymerQuenching 106
4.7.3 DetectionviaLow-EnergyEmission 108
4.8 Temperature-ResponsiveFluorescentPolymers 112
4.8.1 Introduction 112
4.8.2 Examples 112
4.9 NonhomogeneousDetectionSchemes 115
4.9.1 Introduction 115
4.9.2 CPsAdsorbedonSurfaces 116
4.9.3 CPParticlesfromCollapsedPolymerChains 119
4.10 MechanismofEnergyTransfer 122
4.10.1 Theory 122
4.10.2 ModificationstoFörsterTheory 123
4.10.3 EvidenceforDexter-TypeEnergyMigration 123
4.11 ConclusionsandFutureDirections 127
References 128
5 ChromophoricPolyisocyanideMaterials 135
BramKeereweer,ErikSchwartz,StéphaneLeGac,RoelandJ.M.Nolte,
PaulH.J.Kouwer,andAlanE.Rowan
5.1 Introduction 135
5.2 PolyisocyanideMaterials 137
5.3 PerylenePolyisocyanidesinDevices 143
5.4 TFTDevices 147
5.5 MorphologyControlinPerylene/CrystalSystems 147
5.6 PostmodificationofPolyisocyanopeptides 149
5.7 TowardLargerLengthScales:PolyisocyanopeptideBrushes 151
5.8 SummaryandOutlook 152
References 152
6 FunctionalPolyphenylenesforSupramolecularOrdering
andApplicationinOrganicElectronics 155
MartinBaumgartenandKlausMüllen
6.1 Introduction 155
6.2 ConjugatedPolymers 156
6.2.1 LinearandLadderizedPolyphenylenes 156