Frontiers of Nano-Optoelectronic Systems NATO Science Series A Series presenting the results of scientific meetings supported under the NATO Science Programme. The Series is published by IOS Press, Amsterdam, and Kluwer Academic Publishers in conjunction with the NATO Scientific Affairs Division Sub-Series I. Lif e and Behavioural Sciences IOS Press II. Mathematics , Physics and Chemistry Kluwer Academic Publishers III. Computer and Systems Science IOS Press IV. Earth and Environmental Sciences Kluwer Academic Publishers The NATO Science Series continues the series of books published formerly as the NATO ASI Series. The NATO Science Programme offers support for collaboration in civi l science between scientists of countries of the Euro-Atlantic Partnership Council. The types of scientific meeting generally supported are "Advanced Study Institutes" and "Advanced Research Workshops", and the NATO Science Series collects together the results of these meetings. The meetings are co-organized bij scientists from NATO countries and scientists from NATO's Partner countries - countries of the CIS and Central and Eastern Europe. Advanced Study Institutes are high-level tutorial courses offering in-depth study of latest advances in afield. Advanced Research Workshops are expert meetings aimed at critical assessment of a field, and identification of directions for future action. As a consequence of the restructuring of the NATO Science Programme in 1999, the NATO Science Series was re-organized to the four sub-series noted above. Please consult the following web sites for information on previous volumes published in the Series. http://www. nato. i nt/science http://www.wkap.nl http://www.iospress.nl http://www.wtv-books.de/nato-pco.htm Series II: Mathematics, Physics and Chemistry - Vol. 6 Frontiers of Nano-Optoelectronic Systems edited by Lorenzo Pavesi INFM and Department of Physics, University ofTrento, Italy and Eugenia Buzaneva Kyiv National Taras Shevchenko University, Ukraine Springer-Science+Business Media , B.V. Proceedings of the NATO Advanced Research Workshop on Frontiers of Nano-Optoelectronic Systems: Molecular-Scale Engineering and Processes Kiev, Ukraine May 22-26, 2000 A C.I.P. Catalogue record for this book is available from the Library of Congress. ISBN 978-0-7923-6746-8 ISB N 978-94-010-0890-7 (eBook) DOI 10.1007/978-94-010-0890- 7 Printed on acid-free paper All Rights Reserved ©2000 Springe r Science+Business Media Dordrecht Originally published by Kluwer Academic Publishers in 2000 Softcover reprint of the hardcover 1st edition 2000 No part of the material protected by this copyright notice may be reproduced or utilized in any form or by any means, electronic or mechanical, including photocopying, recording or by any information storage and retrieval system, without written permission from the copyright owner. TABLE OF CONTENTS Preface .................................................................................................................................. ix Photograph of Participants ..................................................................................................... x Introduction ........................................................................................................................... xi Part I. Fundamentals of Nano-Scale Science for Photonics applications Nanophotonics: nanoscale optical science and technology .................................................... I Paras N. Prasad, Yuzhen Shen, Abani Biswas and JejJWiniarz Three-dimensional nanostructures with electron and photon confinement. ......................... II Sergei V Gaponenko Dielectric-polymer nanocomposite and thin film photonic crystals: .................................... 23 Towards three-dimensional photonic crystals with a bandgap in the visible spectrum C. M Sotomayor Torres, T Maka, S. G. Romanov, Manfred Muller and RodolJZentel Quantum wires and quantum dots for optoelectronics: ...................................................... .41 recent advances with epitaxial growth on nonplanar substrates Eli Kapon Quantum dot lasers ............................................................................................................... 65 H Schweizer,] Wang, U Griesinger, M Burkard, ] Porsche, M Geiger, F. Scholz, T Riedl and A. Hangleiter Part II. Low dimensional silicon for photonics Nanostructured silicon as an active optoelectronic material ................................................ 85 Leigh T Canham Silicon light emitters: ........................................................................................................... 99 Preparation, properties, limitations and integration with microelectronic circuitry P. M Fauchet, S. Chan, H A. Lopez and K. D. Hirchman Visible light emission from a new material system: .......................................................... 121 SilSi0 superlattices in optical microcavities 2 L. Pavesi, G. Pucker, Z. Gaburro, M Cazzanelli and P. Bellutti Silicon nanostructures in Si/SiOz superlattices for light emission applications: ................ 137 possibilities and limits A. G. Nassiopoulou, T Ouisse and P. Photopoulos vi First principles optical properties oflow dimensional silicon structures .......................... 147 Stefano Ossicini and Elena Degoli Silicon nanostructures and their interactions with erbium ions ......................................... 161 F Priolo, G. Franzo and F Iacona Part III. Biomolecular Technologies Nicks, nodes, and new motifs for DNA nanotechnology .................................................. 177 Nadrian C. Seeman, Chengde Mao, Furong Liu, Ruojie Sha, Xiaoping Yang, Lisa Wenzler, Xiaojun Li, Zhiyong Shen, Hao Yan, Phiset Sa-Ardyen, Xiaoping Zhang, Wanqiu Shen, Jeff Birac, Philip Lukeman, Yariv Pinto, Xiaojun Li, Jing Qi, Bing Liu, Hangxia Qiu, Shouming Du, Hui Wang, Weiqiong Sun, Yinli Wang, Tsu-Ju Fu, Yuwen Zhang, John E. Mueller and Junghuei Chen Interaction of biomaterials with porous silicon .................................................................. 199 S. C. Bayliss, L. D. Buckberry and A. Mayne Part IV. Molecular-Scale Engineering: polymers and carbon-based nanostructures Polydiacetylene PTS: a molecular quantum wire with exceptional optical properties ...... 209 Carlos G. Trevifio-Palacios, George Stegeman, Mingguo Liu, Fumiyo Yoshino, Ser- gey Poliakov, Lars Friedrich, Steven R. Flom, JR. Lindle and FJ Bartoli The electronic structure of carbon-based nanostructures: ................................................. 227 fuIIerenes, onions and tubes J Fink, M Knupfer, T Pichler and M S. Golden Carbon nanostructure: ........................................................................................................ 243 characterization by optics and resonance Raman scattering H. Kuzmany,M Hulman and W Plank Encapsulation of Transition Metals into Carbon Nanoclusters ......................................... 259 Supapan Seraphin Part V. New technologies for producing nano-systems Development of coating technologies using nano particles ............................................... 275 Yasuo Mihara Surface atomic scale engineering by deposition of mass selected clusters: ....................... 291 STM and helium scattering analysis R. Schaub, H. J6dicke, W Harbich, J Buttet and R. Monot Vll Visible and infrared photoluminescence from deposited germanium-oxide clusters and from Ge nanocrystals ................................................................................................ 303 Atsushi Nakajima, Minoru Fujii, Shinji Hayashi and Koji Kaya New directions in nanotechnology: Imprint techniques ..................................................... 319 -e. H. Scheer,H. Schulz and D. Lyebyedyev Self-assembly ofnanoblocks and molecules in optical thin-film nanostructures ............... 331 N I. K9vfyukhova, E. V. Buzaneva. A. D. Gorchinsky, P. J Dllivier, B. R. Martin, e. e. Waraksa and T. E. Mallouk Part VI. Nano- and Molecular-Scale Characterization Soft X-ray spectroscopy as a probe of the electronic structure ofnanostructured solids .. 347 Stefan Eisebitt and Wolfgang Eberhardt Optical spectroscopy of carrier relaxation and transport in III/V semiconductor structures .......................................................................................................................... 363 Etienne Goovaerts and Chris van Hoof Near-field scanning optical spectroscopy of quasi-one dimensional semiconductor nanostructures .................................................................................................................... 377 Ch. Lienau, V. Emiliani, T. Guenther, F. Intonti, T. Elsaesser, R. Notzel and K. H. Ploog Optical characteristics ofnanostructured III-V compounds ............................................... 393 e. I.M Tiginyany, Schwab, A. Sarua, G. Irmer, J Monecke, I. Kravetsky, J Sigmund and NL. Hartnagel Scanning probe microscopy (STM, AFM) investigation of carbon nanotubes ................ .405 L.P. Biro Molecular spectroscopy of nanoparticles .......................................................................... 421 v.Ye. Pogorelov, v.P. Bukalo and Yu. A. Astashkin Part VII. Novel Circuit Architecture of Nano-Optoelectronic Systems Exploring the ultimate limits of control: ............................................................................ 431 Quantum networks for non-classical information processing G. Mahler and A. Dtte Chaos in quantum machines ............................................................................................... 443 Ilki Kim and Guenter Mahler viii Problems and perspectives in quantum-dot based computation ........................................ .455 M Macucci, G. Iannaccone, S. Francaviglia,M Governale, M Ghirlanda and C. Un garelli List of Participants ........................................................................................................... 467 Index .................................................................................................................................. 475 PREFACE Since their discovery, low dimensional materials have never stopped to intrigue scientists, whether they are physicists, chemists, or biochemists. Investigations of their nature and functions have always been and still are numerous and as soon as a solution is found for a given question, another one is raised. The coupling of nano-materials with photonics, i. e. nano-photonics, has produced a boiling pot of idea, problems, discovery and applications. This statement is abundantly illustrated in the present book. The interest in nano-optoelectronic materials and systems is very widespread, what gives a really international and multicultural flavour to nano-optoelectronic meetings. One of them was organized by our-self in May 2000 in Kiev as a NATO Advanced Research Workshop and EC-Spring School. The arrival of the new millennium provides an obvious transition point at which many aspects of nano-science and nano-engineering of nano photonic systems can be assessed with respect to the research progresses made in the pre ceding decades and to the challenges that lie ahead in the coming decades. This book was planed to mark this with the objective of presenting a collection of papers from experts, which provide broad perspectives on the state-of-the-art in the various disciplines of nano science and nano-engineering and on the directions for future research. The content of this book provides a snapshot, at a particular point in time, on such different subjects such as photonic band gap crystals, semiconductor quantum dot and wire lasers, silicon optoelec tronics, carbon-based nanostructures physics, polymer based nano-composite and quantum wires, DNA nano-technology and silicon bio-compatibility, nano-scale optical characteriza tion, spray and cluster deposition, self-assembly, imprint technology, quantum computing and quantum dots based computation. While the snapshot archived in the following pages is inevitably ephemeral in view of the rapid pace of regrouping within novel nano optoelectronic systems, it is hoped that the perspectives offered here would significantly in fluence nano-sciences and nano-engineering for decades to come. It should be noted that the success of our multidisciplinary meeting and of this Book was guaranteed in advance by the enthusiastic work of the organizing commitee: L. P. Biro (Hungary), N. Garcia (Spain), S. Ossicini (Italy), P. N. Prasad (USA), C. M. Sotomayor Torres (Germany) and G. Stegeman (USA). We thank all the authors who responded ea gerly to this demanding task and promptly delivered high quality manuscripts. The timely publication of this book would have not been possible without the efficient and cheerful help of our editorial assistants, Dr. Viviana Mulloni and Dr. Olexandr Gorchinsky. We are most grateful to them for all their efforts. We gratefully acknowledge the generous support of the NATO Scientific Affairs Di vision, of the Directorate-General Information Society of the European Commission, and of our Universities which made the workshop and this resulting book possible. We also ex press our gratitude to all those have contributed to the workshop, and to Kluwer for efficient publication. Lorenzo Pavesi Eugenia Buzaneva Trento, Italy, August 2000 Kiev, Ukraine, August 2000 IX
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