Fabrication of Long-Length and Bulk High- Temperature Superconductors Related titles published by The American Ceramic Society Ceramic Materials and Multilayer Bectronic Devices (CeramicTransactions,Volume ISO) Edited by K.M. Nair,A.S. Bhalla, S.-l. Hirano, D. Suvorov,W. Zhu, and R. Schwartz ©2004, ISBN 1-57498-205-2 Morphotropk Phase Boundary Perovskites, High Strain Piezoelectrks, and Dielectric Ceramics (CeramkTransactionsVolume 136) Edited by Ruyan Guo, K. M. Nair,Winnie K. Wong-Ng, Amar Bhalla, Dwight Viehland, D. Suvorov, Carl Wu, and S-l. Hirano ©2003, ISBN I-57498-151-158 Processing of High-Temperature Superconductors (CeramicTransactions,Volume 140) Edited by Amit Goyal, Winnie Wong-Ng, Masato Murakami, and Judith Driscoll ©2003, ISBN I -57498-155-2 Recent Developments in Electronic Materials and Devices (CeramkTransactions, Volume 131) Edited by K.M. Nair,A.S. Bhalla, and S.-l. Hirano, ©2002, ISBN 1-57498-145-5 Dielectric Materials and Devices Edited by K.M. Nair, Amar S. Bhalla,Tapan K. Gupta, Shin-lchi Hirano, Basavaraj V. Hiremath, Jau-Ho jean, and Robert Pohanka ©2002. ISBN 1-57498-118-8 The Magic of Ceramics By David W. Richerson ©2000, ISBN 1-57498-050-5 Bectronic Ceramic Materials and Devices (Ceramic Transactions,Volume 106) Edited by K.M. Nair and A.S. Bhalla ©2000, ISBN I -57498-098-X For information on ordering titles published by The American Ceramic Society, or to request a publications catalog, please contact our Customer Service Department at: Customer Service Department PO Box 6136 Westerville, OH 43086-6136, USA 614-794-5890 (phone) 614-794-5892 (fax) [email protected] Visit our on-line book catalog at www.ceramics.org. Fabrication of Long-Length and Bulk High- Temperature Superconductors Proceedings of the Fabrication of Long-Length and Bulk High-Temperature Superconductors held at the 105th Annual Meeting offhe American Ceramic Society, April 27-30, 2003, in Nashville,Tennessee Edited by Ruling Meng University of Houston Amit Goyal Oak Ridge National Laboratory Winnie Wong-Ng National Institute of Standards and Technology Kaname Matsumoto Kyoto University Herbert C. Freyhardt Institut für Matellphysik, Universität Gottingen Published by The American Ceramic Society PO Box 6136 Westerville, Ohio 43086-6136 www.ceramics.org Proceedings of the Fabrication of Long-Length and Bulk High-Temperature Superconductors held at the 105th Annual Meeting oflhe American Ceramic Society, April 27-30, 2003, in Nashville, Tennessee Copyright 20O4,The American Ceramic Society. All rights reserved. Statements of fact and opinion are the responsibility of the authors alone and do not imply an opinion on the part of the officers, staff, or members of The American Ceramic Society.The American Ceramic Society assumes no responsibility for the statements and opinions advanced by the contributors to its publications or by the speakers at its programs. Registered names and trademarks, etc., used in this publication, even without specific indication thereof, are not to be considered unprotected by the law. No part of this book may be reproduced, stored in a retrieva lsystem, or transmitted in any form or by any means, electronic, mechanical, photocopying, microfilming, recording, o rother- wise, without prior written permission from the publisher Authorization to photocopy for internal or personal use beyond the limits of Sections 107 and 108 of the U.S. Copyright Law is granted by the American Ceramic Society, ISSN 1042-1122 provided that the appropriate fee is paid directly to the Copyright Clearance Center ;Inc., 222 Rosewood Drive, Danvers, MA 01923 USA, www.copyright.com. Prior to photocopying items for educational classroom use, please contact Copyright Clearance Center, Inc. This consent does not extend to copying items for general distribution or for advertising or promotional purposes or to republishing items in whole or in part in any work in any format Please direct republication or special copying permission requests to the Senior Director, Publications,The American Ceramic Society, PO Box 6136,Westerville, Ohio 43086-6136, USA. COVER PHOTO: "Cross sectional view of the 19 filament hexagonal tube with SrZr03 oxide barrier" is courtesy of Se-Jong Lee, DeukYong Lee.Yo-Seung Song, and Kyung-Hwan Ye and appears as figure 2 in their paper "Preparation of SrZr03Thin Films on Bi(2223) Tapes for the Reduction in AC Losses," which begins on page 95. For information on ordering titles published by The American Ceramic Society, or to request a publications catalog, please call 614-794-5890. 4 3 2 1-07 06 05 04 ISSN 1042-1122 ISBN 1-57498-204-4 Contents Preface ix Coated Conductors Solution Buffer Layers forYBCO Coated Conductors 3 S. Sathyamurthy M. Paranthaman, H.-Y. Zhai, S. Kang, C. Cantoni, S. Cook L Heatherly A. Goyal, H.M. Christen, Md.S. Bhuiyan, and K. Salama Scale Up of High Performance High Temperature Superconductors 9 V Selvamanickam,Y Li, H.G. Lee, X. Xiong,Y Qiao, J. Reeves, Y Xie, A. Knoll, and K. Lenseth Inclined-Substrate Pulsed Laser Deposition of Yttria-Stabilized ZirconiaTemplate Film forYBCO Coated Conductors 15 B. Ma, M. Li, B.L Fisher; RE. Koritala, RM. Baunceanu, S.E. Dorris, and U. Balachandran Evaluating Superconducting YBCO Film Properties Using X-Ray Photoelectron Spectroscopy 23 Paul N. Barnes, Justin C.Tolliver,Timothy J. Haugan, Sharmila M. Mukhopadhyay and John T Grant Development of Low-Cost Alternative Buffer Layer Architectures forYBCO Coated Conductors 33 M. Parans Paranthaman.T Aytug, H.Y Zhai, H.M. Christen, D.K. Christen, A. Goyal, L Heatherly, and D.M. Kroeger Improvement of the Texture in AG Substrates for High Temperature Superconductor Deposition 43 D.M. Liu, M.L Zhou, E.D. Li.W. Liu,YC. Hu. B. Zong, M. Liu andTY Zuo Chemically Coated Buffer Layers Deposited on Rolled Ni Substrates for HTS Coated Conductors 51 YX. Zhou, S. Bhuiyan, H. Fang and K. Salama Development of Conductive La Sr MnO Buffer Layers for 07 03 3 Cu-Based RABiTS .'...' 59 Tolga Aytug, M. Parans Paranthaman, Amit Goyal, Albert Gapud, Noel Rutten Hong Ying Zhai and David K. Christen v Pulsed Laser Deposition ofYBCO with Yttrium Oxide Buffer Layers 63 Rama M. Nekkanti, Paul N. Barnes, Lyle B. Brunke.Timothy J. Haugan, Nick A.Yust, Iman Maartense, John R Murphy, Srinivas Sathiraju, Juliana M. Evans, Justin C.Tolliver, and Kenneth R. Marken Jr BSCCO-Based Conductors, MgB and Other HTS 2 Materials High Transport Properties in Iron-Clad MgB Wires and Tapes . 75 2 H. Fang, S. Padmanabhan,Y.X. Zhou, RT. Putman, and K. Salama Flux Loss Measurments of Ag-Sheated Bi-2223 Tapes 83 Mi-Hye Jang, W. Wong-Ng, R. Shull, LR Cook DeaSik Suh, andTaekuk Ko Preparation of SrZr0 Thin Films on Bi(2223) Tapes for the 3 Reduction in AC Losses 95 Se-Jong Lee, DeukYong Lee.Yo-Seung Song and Kyung-Hwan Ye New Seeding Method for Texturing Y-Ba-Cu-O Bulk Superconductor: Multiple Seeded Melt Growth 103 YX. Zhou, H. Fang, K. Salama and U. Balachandran Control of Microstructure Analytical Transmission Electron Microscopy of Thick YBa^UjO^ Films on RABiTS 113 Keith J. Leonard, Sukill Kang, Byeongwon Kang, Amit Goyal and Donald M. Kroeger Thickness Dependence of JS inYBCO,TL-22l2 and HG-I2I2 C Thick Films 123 J.Z.Wu, R. Emergo and X Wang Damaged Effect in HTS Irradiated by U Fission Fragments ... 135 Alberto Gandini and Roy Weinstein Effect of YBaCuO Morphology and Size in Semisolid Melt 2 s on Growth Rate ofYBajCUjO^ Single Crystals 145 Oratai Jongprateep and Fatih Dogan Flux Pinning and Properties of Solid-Solution (XNdJ^XBajxCUjO^ Superconductors Processed in Air and Partial Oxygen Atmospheres 151 TJ. Haugan, J. M. Evans, J. C.Tolliver, I. Maartense, RN. Barnes, WWong-Ng, LR Cook, and R.D. Shull VI Phase Relations in the BaO-R0 -CuO Systems 163 2 3 x WWong-Ng, LRCook, and J. Suh Studies on Nanoparticulate Inclusions in Y-123 Thin Films.... 177 SSathiraju, RTMurray.Tj.Haugan, RM.Nekkanti, LBrunke, I.Maartense, ALCampbell, J.RMurphy, J.CTolliven RN.Barnes Index 185 The discovery of high-temperature superconductivity (HTS) 16 years ago has been hailed as one of the most exciting advancements in modern physics. However, the full impact of HTS will only be realized with the suc- cess of large-scale applications. For most large-scale bulk applications of HTS, jong-length flexible wires that can carry a large amount of supercur- rent are required. During the last decade, remarkable progress has been made in processing HTS conductors for large-scale applications. For exam- ple, kilometer-length Bi-containing (BSCCO) first-generation wires/tapes have been successfully fabricated. Significant improvement in the perform- ance of the YBa Cu O (YBCO) - based second-generation wires/tapes 2 3 x (coated conductors) has also been achieved in short-length (up to 10 meters) tapes. Substrate fabrication techniques that have received consid- erable attention include IBAD (ion-beam-assisted deposition), RABiTS (rolling assisted bi-axially textured substrates), and ISD (inclined substrate deposition). Epitaxial growth of YBCO and other oxides on these sub- strates can be accomplished by a variety of techniques including pulsed laser deposition (PLD), electron beam evaporation, sputtering, chemical combustion vapor deposition (CCVD), jet vapor deposition, ex-situ BaF 2 processing, ex-situ sol-gel techniques, and liquid phase epitaxy (LPE). A worldwide research target is the development of practically scalable tech- niques for the fabrication of long-length, YBCO thick films. Another major focus area is that of the growth of thick YBCO films without massive degra- dation of the superconducting properties. For bulk applications, large crystal-like superconductor pucks, which are often produced by melt-textured techniques, are required. Applications of melt-textured YBCO materials, which exhibit large-domain lévitation, include frictionless bearings for flywheels, contact-less transportation, damping devices, flux-trap magnets, magnetic shields, and current leads. Various important processing issues concerning melt-textured HTS are still not yet fully understood. Furthermore, strategic research on microstruc- tural issues such as weak-links, flux pinning, grain boundaries, and phase dia- grams is still needed for the development of materials in both bulkand wire/tape form. This proceedings volume contains papers presented at the Fabrication of Long-Length & Bulk HTS Conductors symposium during the 105th Annual Meeting of The American Ceramic Society (ACerS), April 27-30, 2003 in Nashville.Tennessee. The symposium featured the above-mentioned issues pertaining to the processing of HTS materials, and also the current status and potential of the YBCO-based coated conductors and the BSCCO- IX based conductors (especially Bi-2223 and Bi-2212) already in production. MgB based wires for lower temperature applications were also highlighted. 2 The papers are divided into three sections: (I) coated conductors, (2) BSCCO-based conductors, MgB , and other HTS materials, and (3) control 2 of microstructure.The order in which the papers appear in this proceedings volume and the division into which they are organized may be different from that of their presentation at the meeting. It is hoped that this comprehensive volume will be a good summary of the latest developments in high-temper- ature superconductor research as well as good source material for researchers and managers working in this field. We acknowledge the service provided by the session chairs and appreciate the valuable assistance from the ACerS programming coordinators. We are also in debt to Greg Geiger and Bill Jones for their involvement in editing and producing this book. Special thanks are due to the speakers, authors, manu- script reviewers, and ACerS officials for their contributions. Ruling Meng Amit Goyal Winnie Wong-Ng Kaname Matsumoto H. C. Freyhardt x Fabrication of Long-Length and Bulk High-Temperature Superconductors Edited by Ruling Meng, Amit Goyal, Winnie Wong-Ng, Kaname Matsumoto and Herbert C. Freyhardt Copyright O 20O4, The American Ceramic Society Coated Conductors