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Fs ECONGNIC ON ) EXPLORATION GEOCHEMISTRY: DESIGN AND INTERPRETATION OF SOIL SURVEYS f : 3 : in cooperation with y Ans \ g } The Association of Exploration Geochemists B\ {kK 3) q 3 < REVIEWS IN ECONOMIC GEOLOGY Volume 3 W. K. Fletcher, S. J. Hoffman, M. B. Mehrtens * A. J. Sinclair & I. Thomson CONTENTS GETTING It RIGHT 1. Thomson THE SOIL SURVEY—DESIGNING AN EXPLORATION PROGRAM S.J. Hoffman Soll. SAMPLING S.J. Hoffman ANALYSIS OF SOIL SAMPLES W. K. Fletcher STATISTICAL INTERPRETATION OF SOIL GEOCHEMICAL DATA A. J. Sinclair MODELS, INTERPRETATION, AND FOLLOWUP S.J. Hoffman & L. Thomson CASE HISTORY AND PROBLEM. I THE TONKIN SPRINGS GOLD MINING DISTRICT, NEVADA, USA M. B. Mehrtens CASE HISTORY AND PROBLEM 2: CokD-Y-BRENIN PORPHYRY COPPER, NORTH WALES, GREAT BRITAIN M. B. Mehrtens CASE HISTORY AND PROBLEM 3: THE VOLCANOGENIC MASSIVE-SULFIDE TARGET S.J. Hoffman CASE HISTORY AND PROBLEM 4 THE VOLCANOGENIC MASSIVE SULFIDE, A SECOND EXAMPLE S.J. Hoffman CASE HISTORY AND PROBLEM 5: A COPPER PROPERTY S.J. Hoffman Series Editor: James M. Robertson REVIEWS IN ECONOMIC GEOLOGY (ISSN 0741-0123), Published Annually by the SOCIETY OF ECONOMIC GEOLOGISTS Printed by BookCrafters, Inc.. 140 Buchanan Street, Chelsea, MI 48118 Series Editor: James M, Robertson Additional copies of this volume may be obtained from The Economic Geology Publishing Company P.O. Box 637 University of Texas at 79968-0637 USA FI Paso, TX Paso (915) 533-1965 Vol Vol. Vol. 3: OF SOIL Vol. 4: ORE DEPOSITION ASSOCIATED WITH MAGMAS Reviews in Economic: Geology is a publication of the Society of Kcoaornic Geologists deaigoed to accompany the Society's Short ‘Goune series. Like the Short Courses, each volume provides intensive updates on vations applicd and academic topics for practicing eco: omic geologists amd peochemists in exploration, development, re- search. nad teaching. Volumes are produced annually in conjunction ‘with each new Short Coarse, firs serving 434 textbook for that course 46 subsequently made available to SEG. members and others at tmoent cont © Coppripht 1986, Society of Ecucomic Geologists Permission is granted to individuals to make single copies of chap fem or petnonal use in research. study, and teaching. aod Wo use short ‘qootations, illustrations, and tables {com Reviews in Economic Geol ‘47 for publication in scientific works. Such vies mast be appropei micly credited. Copying for general distribution, for promotion and advertising, lie creating new collective works, oF for other commer ‘ial parpones i ot permite without the specific written . opp anata pecitic writes permission ISBN 0-9613074-0-4 ISBN 0-9613074-1-2 (1986) (1989) ISBN 0-9613074-2-0 ISBN 0-9613074-3.9) Standing orders are porations who wish (0 au Reviews in Econo mailed wit aries, institutions, and cor new volume of iblished. An invoice is nding order, notify. the snypany (PUBCO) business office at ach Yolume. To place 2 Address Change. St CO business office weeks prior to mailing out a volum your mailing label for reference Replacement Policy, Missing vol ill be replaced without charge to standing-order holders who notify the PUBCO business. office within six weeks (six months for India and Australia) of the date & new Short Course is given and new vol hat the PUB» dress at least four omit a copy of me prostuced, Remittances should be made payable to PUBCO, Reviews in Economic Geology, and should be mailed to the PUBCO business office at the address given above. Also all other b tions should be addressed to that office ss communica: FOREWORD Volume 3 of Reviews in. Economic Geology—Exploration Geochemistry: Design and Interpretation of Soil Surveys represents a major effort by ‘and contribution from the Asso- Gation of Exploration Geochemists (AEG) and especially its Vancouver connection. The volume draws extensively on the cumulative teaching, research, and industry experience fits five authors, and it contains numerous ‘real-life’ exam- ples of exploration failures as well as successes, A prelim: Prcry version of this volume served as the text for a jointly Spansared Society of Economic Geologists (SEG)-AEG Short Course that was given in F , prior to the com bined winter meeting of the SEG and annual meetings of the Society of Mining Engineers and A.J.M.E. in Denver, Colorado. thas been a special pleasure to work with W. K. Fletcher (Department of Geological Sciences, U.B.C.) whose patience And sense of humor survived the herculean task of initial text and figure assembly, He met his deadlines despite the vagaries of changing figure specifications, colleagues’ schedules, and the Canadian Postal System. Volume 3 has benefited greatly from the professional attentions of Carol Hjeliming (New Mexico Bureau of Mines and Mineral Resources editing staff) who now serves 2 the part-time official assistant to the Series Editor. In addition’ to performing more traditional editorial chores, Carol has been instrumental in setting up the procedures and print codes that allowed us to utilize the computer-driven type= setting equipment of the University of New Mexico Printing Plant. Finally, I wish to acknowledge the continuing support, both moval and economic, of the New Mexico Bureau of Mines and Mineral Resources and its Director, Frank Kott= lowski. James M. Robertson Series Editor Socorro, N. Me April, 1987 CONTENTS sar FOREWORD THE ULTIMATE bbeala ti DIAMOND DRILL PREFACE, PROGRAI BIOGRAPHIES aC THE EprrHerMAt GoLo Depostr. . 3 Chapter 1—GETTING IT RIGHT, CONCLUDING SUMMARY «0... 33 INTRODUCTION ... .. 1 ANSWERS TO EPITHERMAL GOLD DEPOSIT i CHOICE OF METHODS 1 QUESTIONS . 33 OPTIMIZING SURVE 2 REFERENCES 38 BASIC OBJECTIVES - 2 Optimum Target Identificatio 2 cn) ter 3—SOIL SAMPLING Maximum Geochemical Contras 3 INTRODUCTION ..... Aico 5 THE SOIL SURVEY AS PART OF THE EXPLORATION Cost Effectivenes: 6 PROGRAM. ni cecgn anime JRVEY PARAMETERS 7 AN EXPLORATION EXAMPLE—THE “QUICK 10 DIRTY” VERSUS THE “SLOW AND 10 PROFESSIONAL” APPROACH .c10.000secsuecesees ML 10 GEOCHEMICAL FACTORS AFFECTING TRACE 10 ELEMENT DISTRIBUTION: SOIL 10 DESCRIPTIONS. , u SAMPLE TYPE. +++» W SAMPLE NUMBER ., .- DESCRIPTION OF THE A\ iW TOPOGRAPHY, . ASSUMED . 11 Sire DRAINAGE AND GROUNDWATES SEEPAGE Quesnions. i Ge OVERBURDEN ORIGIN % Soit PH . Su ORIENTATION STUDIES The Orientation Si A Literature Study A Theoretical Orientation SURVEY ORGANIZATION AND OPERATION PROBLEM 1; MOLYBDENUM IN SIERRA LEON! Owjectivi Ree 45 z OBJECTIVE... DESCRIPTION OF THE AREA, ASSUMED .....+50 ++ i QUESTIONS. EFE! 12 Soi HORIZON 13 Rock Tyre. CONTAMINATION COARSE FRAGMENTS. GAMMA COUNT AT SAMPLE SITE... Chapter 2—THE SOIL SURVEY—DESIGNING AN OTHER PARAMETERS—COMPOSITION ANDYOR SITE ~ EXPLORATION PROGRAM ee INTRODUCTION . PHASE 1—THE OFFICE THe UNCONFORMITY-1 RELATED Uns THe EprrHerMat Gop Deposit. PHA THE FIELD ORIENTATION VIS) THE UNCONFORMITY-RELATED URANIUM DEPOSIT .. Introduction Athabasca Basi Thelon Basin. Hornby Bay Basin The Preliminary Field V THe EprrirrMAt Got Derostr. CONTINUED OFFICE PLANNING .... THe UNc NORM Ret ATED Uranium Deroste THE REGIONAL EXPLOR: TION % THe UNCONFORMITY-RELATED URANIU! THE ErrHerMAL Goup Depostr . THE ROUTINE SOIL SURVEY ..... THE UNCONFORMITY-RELATED URAN' THE EprrtieRMat GOLD Depostr... APPENDIX I. 21 APPENDIX II 22 APPENDIX Ill 22 Chapter 4—ANALYSIS OF SOIL SAMPLES. 23. INTRODUCTION . 24 DISTRIBUTION OF 24 SAMPLE PREPARATION, . 25 SAMPLE DECOMPOSITION INTRODUCTION « ..+-5 STRONG DECOMPOSITION PARTIAL EXTRACTIONS ANALYTICAL METHOD QUALITY CONTROL AND RELIABILITY........-..... RANDOM ERRORS AND PRECISION . x SysreMAnic ERRORS . CONTAMINATION puseaszagaegees esezasgenneeez uM Deposit REVIEWS IN ECONOMIC GEOLOGY (ISSN 0741-0123) Volume 3 EXPLORATION GEOCHEMISTRY: DESIGN AND INTERPRETATION in cooperation with The Association of Exploration Geochemists ISBN 0-9613074-2-0 The Authors: W. K. FLETCHER S. J. HOFFMAN Department of Geological Sciences Selco Division 6339 Stores Road BP Resources Canada Limited University of British Columbia 700-890 West Pender Street Vancouver, BC Canada, V6T 2B4, Vancouver, BC Canada, V6C 1KS. A. J. SINCLAIR Department of Geological Sciences 6339 Stores Road University of British Columbia Vancouver, BC Canada, V6T 2B4. M. B. MEHRTENS U.S. Minerals Exploration Company 141 Union Boulevard, Suite 100 Lakewood, Colorado 80228 I. THOMSON Placer Development Limited 1055 Dunsmuir Street Vancouver, BC Canada, V7X IPI. Series Editor: JAMES M. ROBERTSON New Mexico Bureau of Mines & Mineral Resources Campus Station Socorro, NM 87801 QOCIRTY OR RCONQOMIC GRO! ORICTS AN EXPLORATION REFERENCES .. Chapter 5—-STATISTICAL. INTERPRETATION OF SOIL GEOCHEMICAL DATA Percentiles - 100 HistoGkAM a 100 CONTINUOUS DISTRIBUTION: ; 100 STANDARD NORMAL DISTRIBUTION 101 LOGNORMAL DISTRIBUTIONS - -« Firtinc A NORMAL Curve TO A HistoGRAM - CUMULATIVE DISTRIBUTIONS Connpence Limits F anv T Tests . Prosasitry GRAPHS: CORRELATION . INTRODUCTION «..-0<05senssenerss ANALYSIS OF A MATRIX OF CORRELATION COEFFICIENT Seeds seseees “CORRELATION” OF POPULATIONS «..-.-++ CorkeLaTions AMONG Prrcentace Dat. AUTOCORRELATION Reaeeses ret PosstpLe PROBLEMS IN| CORRELATION STUDIES .. SIMPLE LINEAR REGRESSION INTRODUCTION bee SUNOMARY OF FORMULAE. ..<.+.020200e000 5 SOME APPLICATIONS OF LINEAR REGRESSION Decree oF Fr « eacatensnee ERRoS IN Bort VARIABLES .. (CHI SQUARE DISTRIBUTION INTRODUCTION + GOopNess OF F1 Two-way Co FINAL REMARKS . REFERENCES: ENCY TABLES. ‘Chapter 6—MODELS, INTERPRETATION, AND. FOLLOWUP MODELS ... 5 rs Be erie tisos 17 GENERAL BACKGROUND ..... 17 LANDSCAPE GEOCHEMISTRY . 117 IpEAuze Mopeis EXAMPLES... APPLICATIONS « - INTERPRETATION ......-- LANDSCAPETOPOGRAPHY PH-EW/ELEMES Mositrry- ANOMALY FOLLOWUP. REFERENCES ... Chapter 7—CASE. HISTORY AND. PROBLEM 1: THE TONKIN SPRINGS GOLD MINING DISTRICT, NEVADA, U.S.A. «000 0ser4eree 9 Chapter 8—CASE HISTORY AND PROBLEM 2: COED-Y-BRENIN PORPHYRY COPPER, NORTH WALES, GREAT BRITAIN «...++++ Chapter 9—CASE HISTORY AND PROBLEM 3: THE VOLCANOGENIC MASSIVE-SULFIDE TARGET PRELIMINARY STUDIES 139 FIELD ORIENTATION. 139 CONTINUED OFFIC PLANNING 141 PROPERTY EVALUATION .- 141 ‘ANOMALY FOLLOWUP—DRILL TI TING. . ANSWERS. SUMMAI = 146 REFERENCES ..- 146 Chapter 10—CASE HISTORY AND PROBLEM 4: THE VOLCANOGENIC MASSIVE SULFIDE, A SECOND EXAMPLE PRELIMINARY STUDIES... 147 FIELD OBSERVATIONS ... ¥ CONTINUED OFFICE PLANNING - PROPERTY EVALUATION ... ANOMALY FOLLOWUP-—DRIL! ANSWERS... SUMMARY... Chapter 11—CASE HISTORY AND PROBLEM 5: A COPPER PROPERTY PRELIMINARY STUDIES FIELD ORIENTATION. NortH Cirque - Nori CREEK. . Norm Tir. = TABLETOP HIGHLANDS Souti CIRQUE. Main VALLEY LORATION OFFICE PLANNING JALUATION .. GEOLOGY .. 2 5 (GEOPHYSICAL SURVEYS Son, GEOCHEMISTRY PSOE ANOMALY FOLLOWUP—DRIL ANSWERS. ...-05000005 . SUMMAR' Ri z TABLES OF CONVERSION FACTORS . Inside back cover PREFACE The principles and practical considerations underlying utilization of soils as a medium for exploration geochem- istry are well described in several textbooks, Moreover, not only are soil surveys routinely undertaken in such diverse environments as tropical Tntereae and arctic permafrost, soils are probably the most frequently collected and ana- lyzed medium in exploration geochemistry. What, then, is the justification for devoting the third volume in the Society of Economic Geologists Reviews in Economic Geology to this apparently routine, well established prospecting method? Unfortunately, it is the experience of the contributors to this volume that effectiveness of soil surveys is often com- promised when the conceptual simplicity of the method leads to its unthinking application, For example, failure to appreciate the characteristics of the geochemical environ- ments of a landscape can lead to collection of the wrong sample material or choice of unsuitable methods of sample preparation and analy imilarly, emphasis on speed rather than quality of sampling, rigid adherence to standard lab- oratory methods, and simplistic interpretations of high yal- ues can result in exploration dollars being wasted on false anomalies while genuine, but more subtle, anomalies go unrecognized or are assigned low priorities. In contrast to the foregoing, rational application of soil surveys depends on the successful selection and linkage of appropriate meth- ods of sample collection, analysis, and interpretation—often on the basis of an initial orientation survey. Decisions must be made at each step and an error at any single step may jeopardize the entire exploration effort, Chapters in this volume discuss each step in the soil survey from sample collection through analysis and statis- tical interpretation of the data to selection of targets for followup. Factors to be considered and the decisions that must be made are illustrated by numerous examples and case histories. However, rather than presenting the case histories in a simple narrative fashion, we have attempted to challenge the reader, by asking questions as each case history unfolds, to become a participant in the process. In some—but not al we have: answers (or our opinions as to what reasonable ans\ might be). The case histories are largely from our ownt rience and many reflect our geographical ; northern glaciated A We do not believe this to | deficiency insofar as this volume is intended not as pai prehensive guidebook to interpretation of soil. but as an troduction to undertaking surveys in a 1 and logical fashion, Indeed this volume will be a success if its omissions provoke you into asking similar (though not necessarily the same) questions of your own geochemical, landscapes and soil pede ACKNOWLEDGEMENTS—In Heepare this volume the authors were assisted by many individuals and organiza- tions who ey contributed ie time, technical facil- ities, experience, and comments. We are especiail eful to carteapedlve enpiee for their Suppartand fre to use company oe ay tories: kite when Choe ‘were not entirely flattering. many who encouraged and assisted, the following deserve oe mention: Riofinex and CARGO | Partners for giving M. B. Mehrtens use of the Coed Brenin and Tonkin Springs case histories, respectivel Selco, D. K. Mustard, C, M. H, Jennings and G. G. for their assistance to Stan Hoffman; and Placer ‘ment Limited for their support of lan Thomson's contri- butions, Donna M. Baylis greatly assisted K. Fletcher in Chi and preparing the text, Finally, we must acknowl edge the patience of Jamie Robertson, Series Editor, Reoiews int Economic Geology, and the support of both the Association. of Exploration Geochemists and the Society of Economic Geologists. . W. K. Fletcher Chairman Short Course Committee Association of Exploration Geochemists BIOGRAPHIES W. K. FLETCHER received both his B.Sc. in Geology and Ph.D. in Applied Geochemistry at the Imperial College of Science and Technology, University of London. He joined the tment of Geological Sciences, University of British rolumbia in 1968 and is now an Associate Professor. During Jeaves of absence he has been Chief seochemist to MIN- DECO (Zambia) and Geochemist and Team Leader to the United Nations Project at the Southeast Asia Tin Research ‘and Development Centre in Malaysia. He is an author of more than fifty scientific papers on applied geochemistry fand of a textbook Analytical Methods in Geochemistry Pros- pecting. He is a former council member of the Association ‘of Exploration Geochemists and is the current Chairman of the association's Short Course Committee. STAN J. HOFFMAN received his B.Sc. in Geology and Chemistry from McGill University and his M.Sc. and Ph.D. in exploration geochemistry at the University of British Columbia. He has more than twenty y’ of field-related experience working for a number of mineral exploration companies including INCO, Amax, Rio Tinto and BP Min- erals. He is currently Senior Geochemist for the Selco Divi- sion of BP Resources Canada Limited and is based in Vancouver. He has actively advanced use of geochemistry ‘by the mineral exploration community through short courses, organization of symposia (GOLD-81 and GEOEXPO/86) and compilation of a manual on “Writing Geochemical Repo {Association of Exploration Geochemists, Special Volume 12). He is a Member of Council of the Association of Explo- ration Geochemists and President of the AEG for 1987-1988. MIKE B. MEHRTENS has a B.Sc. in Geology and received his Ph.D. in Applied Geochemistry (1966) from the Imperial College of Science and ‘Technology, University of London. He has been employed in mining and exploration for base and precious metals in Zambia, South Africa, the United Kingdom, Saudi Arabia, and Panama. He is currently Pres- ident of U.S. Minerals Exploration Company (USMX) based. in Denyer, Colorado ALASTAIR J. SINCLAIR, P. Eng., has had 24 years of teaching, research, and consultancies in the mineral indus- try. He has taught economic geology, geological data anal- ais, and geostatistics during a 22-year career in the partment of Geological Sciences, The University of Brit- ish Columbia, where he is now Professor and Head of Department. During that period he has been involved in a broad range of local and international consulting for numer- ous mining companies as well as the Provincial government and the United Nations, particularly in the fields of mineral property evaluation, mineral exploration data analysis, and geostatistical ore reserve estimation. His research and field work since the late 1950's has led to more than 100 scientific and technical publications, many of which have direct appli- cation to exploration for and evaluation of mineral deposits, Dr. Sinclair has served in executive capacities for a variety of professional organizations including The Canadian Insti- tute of Mining and Metallurgy, The Mineral Deposits Divi- sion of the Geological Association of Canada, and the Society of Economic Geologists and is active in the Association of Professional Engineers of British Columbia. IAN THOMSON received his Ph.D. in Applied Geochem- istry for research at Imperial College of Science and Tech- nology, University of London. On graduation he joined Barringer Research Limited where, over an eight-year period, he was involved in the development of field and analytical techniques in geochemistry, and consulting and project work in Canada, the U.S.A., Central and South America, the southwest Pacific islands and the Middle East. In 1978 he joined the Ontario Geological Survey where, for three years, he was involved in a number of studies including deep- overburden-till sampling in the Abitibi Clay Belt and an examination of the impact of acid rain on the geochemistry of lakes. He joined Placer Development Limited in 1981 as Senior Geochemist and later became Manager Western Can- ada Exploration based in Vancouver. In 1987 he joined Pan Orvana Resources as Chief Geologist. He is a former Pres- ident of the Association of Exploration Geochemists and the Canadian Geoscience Council and is author of numer- ous publications on applied geochemistry. Chapter 1 GerTinG It RIGHT I. Thomson INTRODUCTION Asmineral exploration becomes increasingly difficult, costly and competitive, success is essential; there is no room for waste or inefficiency. Exploration must be truly cost effec tive. The present book is concerned ultimately with the interpretation of geochemical surveys. However the data to be interpreted are the product of the field survey and thus only as good as the work that went into these earlier phases. The truism “garbage in—garbage out” is as relevant here as anywhere. Every exploration geochemical survey has three com: ponent parts (1) Sampling (2) Analysis (3) Interpretation These are independent yet interdependent functions. Failure to execute one step correctly will negate all efforts in the succeeding steps. By and large the function that is most costly, and ‘certainly most difficult to repeat, is the field survey. Any deficiences at this stage will have fatal effects on the remainder of the project. Analysis of the sam- ples is, indeed, costly and an area of necessary concem. However, if samples have been collected properly it is not unreasonable to suppose that they can be reanalyzed should this be deemed necessary or useful. Ultimately interpre- tation, provided that sampling and analysis are reliable, is an exercise that can be repeated many times using a variety of techniques or models depending on supplementary information available and the skills and prejudices of var- ious geologists or geochemists. The design and execution of a geochemical survey is thus crucial to its success. Surveys can be, and are, optimized to find specific targets in particular environments. Such fine tuning requires an understanding of applied geochemistry, knowledge of the environment in which the survey will be carried out and an appreciation of the target being sought Before considering these points in more detail, itis worth defining the nature of a geochemical survey in more general terms and establishing clearly the role of the survey in an exploration program The basic premise of exploration geochemistry is that the systematic sampling and analysis of naturally occurring materials will reveal features indicative of the presence of potentially economic mineralization. This is a simple statement for it begs the questions—what mal should be sampled?; how and for what entities should these samples be analyzed?; and what features will be revealed? We will consider these points in more detail in later Sections. The key wording here is “systematic sampling and anal- ysis.” Regular and consistent application of a technique across ‘a property should produce a common database, a synoptic picture of the distribution of elements or compounds, that ‘will meet the twin objectives of any exploration survey: (1) Identification of targets likely to represent dain! significant mineralization. (2) Confident elimination of barren ground. Itis thus important to know both the advantages and the limitations of any survey or survey Lat A good geo- chemist should be able to interpret every feature on a geo- chemical map: the lows as well as the highs. This is not always the case. A frightening number of dollars have been Spent on conventional soil surveys over areas of deep trans- ported overburden. The resulting geochemical patterns are Spiel, flat and uninteresting. Many interpretations have concluded, wrongly, that the absence of a geochemical response proves that these areas haye no economic poten- tial. This is a false assumption since such a survey technique is inappropriate for these conditions. It is the experience of the writers of this manual that, today, the majority of geochemical surveys are carried out mechanically with litte thought of the suitability of the techniques employed. Frequently a stock “recipe” is used— “B" horizon soils, sieve to minus 80 mesh, anah for so many elements, look for the high numbers. Relatively little effort is required to significantly increase the effectiveness of your surveys. CHOICE OF METHODS From the outset, the selection of any technique is depend- enton the mineralogy and geochemistry of the ta sought. The composition of a mineral body will determine the elements that can be used, Copper is clearly ideal for a copper deposit, but for arsenic to be useful in a gold search: it must be present in the gold mineralization. Newey is only useful for mercury-bearing bodies of mineralization, etc, ete. Further, the mineralogy of the target, in combi- > Cuarrer 1 ion with the secondary environment, will determine the ae ‘of dispersion. For camp copper dispersion is both Thydromorphic and ‘mechanical while tin, typically, is almost entirely mechanical as grains of cassiterite, with a further contribution from tin in biotite and other accessory min: erals. The second ‘of the target int to consider is the relative disposition jis may be characterized (Figure By as io) wutcropping ore, (2) partially outcropping ore, (3) burie paged a vba cover, and (4) blind ore bodies completely concealed within their host rocks. Clearly, dif- ferent techniques are required for these various conditions, Direct surficial sampling will be effective in cases (1) and (2) although rather different geochemical responses should be anticipated. Cases (3) and (4) demand optimized tech- niques that will see through cover, search beneath cover, sniff gases seeping from mineralization, detect leakage or identify halos in the surrounding, rocks. SAPONTION OF ORE OFFONITS FIGURE 1.1—The variable disposition of mineral deposits with respect to the present day daylight surface, For explanation see text, Then there is the scale of application. Geochemical sur- veys are used at various stages in mineral exploration with four levels of intensity readily appreciated: (1) Regional—recognition of mineral belts or min- ing camps. 2) Local-—identification of targets for evaluation. (3) Property—defining the limits of mineralized und (4) Deposit—location of individual ore bodies. As shown in Figure 1.2 these also represent increasing levels of effort, complexity of problem, sophistication of technology, expenditure per unit area and, frequently, the Sequence of an exploration program. Techniques applicable at the regional scale, with broadly spaced samples, are incapable of providing the definition necessary at the prop- erty and deposit scale. Conversely, the very detailed sam- pling and sophistication of technology used to locate individual ore bodies are far too tedious and costly to apply at the local and regional scale. y i oe MSITY OST PER UNIT AREA HEGIONAL LOCAL _PROPERTY__OEFOSUT 318 ourctor as Ele arian ale ‘OUTCROP. ae ASTSy zz Re Si wuRED 5 ak Ke bd [9 nino = ——— INCREASING LEVELS FIGURE 1.2—Some factors influencing the choice of mineral ex- ploration survey techniques. Ultimately there is the need to integrate geochemistry with the overall exploration strategy. Depending on the character of the target, level of application, surficial envi- ronment and availability of personnel, geochemistry may take a lead or supporting role in an exploration program. Occasionally it may have no place at all, Frequently. it is misapplied with surveys run to see what happens, to satisly contractual or assessment work commitments or simply because they are always run. Such surveys are very rarely truly successful Howy, then, are geochemical surveys optimized within a particular exploration program? OPTIMIZING SURVEY TECHNIQUES To optimize a geochemical survey a variety of techniques are available to the geochemist. The collective experience of some 50 years of exploration geochemistry can be brought to bear on the problem at hand. It is, however, necessary to be quite clear about what is wanted in an individual survey. The key feature is identified by Hawkes and Webb (1962) as RELIABILITY, which refers to the probability of obtaining and recognizing indications that an orebody is/is not present within a survey area. In constructing a reliable survey method, four characteristics are deemed desirable and represent the Basic Survey Objectives Basic Objectives Optimum target identification A target, if present, should be clearly visible in the geo- chemical data. It may be characterized by an increase or decrease in abundance of certain elements or a diagnostic association of elements, Regardless of the details, it should be easily distinguishable from the remainder of the survey data, a feature achieved by - i

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