Technical Report Documentation Page 1. Report Number 2. Government Accession No. 3. Recipient's Catalog No. TX-971 2969-1 F 4. Title and Subtitle 5. Report Date EV ALUA TION OF THE USE OF COAL COMBUSTION BY-PRODUCTS November 1996 IN HIGHWAY AND AIRFIELD PAVEMENT CONSTRUCTION 6. Performing Organization Code 7, Author(s) 8. Performing Organization Report No. Donald Saylak, Cindy K. Estakhri, Rajan Viswanathan, Dustin Tauferner, and Research Report 2969-1 F Harsha Chimakurthy 9. Perfonning Organization Name and Address lO, Work Unit No. Texas Transportation Institute The Texas A&M University System 11. Contract or Grant No. College Station, Texas 77843-3135 Study No. 7-2969 12. Sponsoring Agency Name and Address 13. Type of Report and Period Covered Texas Department of Transportation Final: Research and Technology Transfer Office September 1995 -August 1996 P. O. Box 5080 14. Sponsoring Agency Code Austin, Texas 78763-5080 15. Supplementary Notes Research performed in cooperation with the Texas Department of Transportation. Research Study Title: Evaluate the Use of Coal Combustion By-Products in Highway and Airport Pavement Construction 16. Abstract The objective of this study was to exploit the beneficiation and utilization of coal combustion by-products (CCBPs) as low-cost alternate aggregates and stabilizers in roadway and airfield construction. A literature review and laboratory investigation were performed to investigate the use ofCCBPs in three highway construction applications: (I) fly ash for subgrade stabilization, (2) flue gas desulfurized (FGD) gypsum and Gypsite for base and subbase construction materials, and (3) bottom ash (with sulfur modification) in asphaltic concrete mixtures. Results from field trials utilizing CCBPs in roadbases indicate good to excellent performance characteristics and negligible environmental impact. Class C and lime-enhanced Class F fly ashes were shown to be effective stabilizers for both clayey and sandy soils. The field trials showed that sulfate-resistant cements and Class C fly ashes provide a wide range of strengths in stabilized sulfate and sulfite roadbases. The use of sulfur improved the crushing strength and reduced the asphalt demand associated with bottom ash in asphaltic concrete mixtures. Sulfur modification required asphalt contents equal to and often less than for mixtures using conventional aggregates. Based on its availability, lower cost, safe use, and demonstrated performance, CCBP materials should find increasing use especially in those regions of Texas experiencing dwindling or non-existant aggregate sources. 17. Key Words 18. Distribution Statement Coal Combustion By-Products, Coal Ash, Fly Ash, No restrictions. This document is available to the public Bottom Ash, FGD Gypsum, Sulfur, Highway through NTIS; National Technical Information Service Construction 5285 Port Royal Road Springfield, Virginia 22161. 19. Security Classif.(of this report) 20. Security Classif.(of this page) 21. No. of Pages 22. Price Unclassified Unclassified 284 Fonn DOT F 1700.7 (8-72) Reproduction of completed page authorized EVALUATION OF THE USE OF COAL COMBUSTION BY-PRODUCTS IN mGHWA Y AND AIRFIELD PAV EMENT CONSTRUCTION by Donald Saylak Research Engineer Texas Transportation Institute Cindy K. Estak:hri Assistant Research Engineer Texas Transportation Institute Rajan Viswanathan Graduate Research Assistant Texas Transportation Institute Dustin Tauferner Graduate Research Assistant Texas Transportation Institute and Harsha Chimakurthy Graduate Research Assistant Texas Transportation Institute Research Report 2969-1F Research Study Number 7-2969 Research Study Title: Evaluate the Use of Coal Combustion By-Products in Highway and Airport Pavement Construction Sponsored by the Texas Depmnnent of Transportation November 1996 TEXAS TRANSPORTATION INSTITUTE The Texas A&M University System College Station, Texas 77843-3135 IMPLEMENTATION RECOMMENDATIONS The following are recommendations for implementing the use of coal combustion by products in highway and airfield pavement construction: 1. This project was proposed as Phase I of a two-phase study. It is recommended that Phase II (a field testing research program) be implemented at this time. It is recommended that a research project (either in-house or university-based) be established to design, monitor construction and performance of field test sections incorporating coal combustion by products into highway and airfield pavement construction as discussed in this report. It is anticipated that all test sections could be constructed in one year. Performance monitoring should be continued for a minimum of two years. 2. It is recommended that TxDOT construct the following test sections to evaluate the constructability and performance of coal combustion by-products in highway/airfield construction: CCBPs as Subgrade Stabilizers A-3 Soil: Test Section 1. 15% Class 'c' fly ash Test Section 2. 20% Class 'C' fly ash Test Section 3. 3% Quicklime and 8% Class 'F' fly ash A-7-6Soil: Test Section l. Control-4% Quicklime. Test Section 2. 2% Quicklime and 5% Class 'F' fly ash v Test Section 3. 10% Class 'C' fly ash. Test Section 4. 15% Class 'C' fly ash. CCBPs as Road Base Materials Test Section 1. Cement Stabilized or HVFA Cement Stabilized FGD. Test Section 2. Fly Ash (Class 'C') Stabilized FGD. Sulfur-Modified Bottom Ash (SMBA) Asphaltic Mixtures Researchers believe that 5MBA asphaltic mixtures have potential for use on general aviation runways and that this would be an excellent field test; however, it is recommended that an even smaller scale field experiment be developed first. It is recommended that a field experiment (100 meters in length) be placed at a location such as Texas A&M's Riverside Campus. The aggregate fraction of this mixture could be either 100010 bottom ash or 50% bottom ash as determined by the Project Director. Any of the mixture designs presented in Section IV would be a good starting point for development of a field trial. 3. Preliminary specifications are presented in Section V of this report. These should be evaluated and modified as needed during the field testing portion of a Phase II research program. vi DISCLAIMER The contents of this report reflect the views of the authors, who are responsible for the facts and the accuracy of the data presented herein. The contents do not necessarily reflect the official view or policies of the Texas Department of Transportation (TxDOT) or the Federal Highway Administration (FHWA ). This report does not constitute a standard, specification, or regulation, nor is it intended for construction, bidding, or permit purposes. vii TABLE OF CONTENTS Page UST OF FIGURES . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . xv LIST OF TABLES . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . xxii SUMMARY . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. xxv SECTION I - INTRODUCTION. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 1-1 BACKGROUND. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 1-1 Coal Combustion By-Product (CCBP) Production ... . . . . . . . . . . . . . . . . .. 1-1 Legislative Developments . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 14 CCBP MATERIALS ............................................ 1-7 Fly Ash, Bottom Ash, and Boiler Slag ............................ 1-7 Flue Gas Desulfurized Sulfates (Gypsum) and SuIfites (Gypsites) ........... 1-8 Elemental Sulfur ............................. ~ . . . . . . . . . . .. 1-9 Hydrated Fly Ash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1-10 RESEARCH PROGRAM ......................................... 1-10 Objectives .............................................. 1-11 Materials ............................................... 1-12 Report Organization .............. . . . . . . . . . . . . . ~ . . . . . . . . . . . . 1-12 REFERENCES - SECTION I ....................................... 1-15 SECTION IT - THE USE OF FLY ASH FOR SOIL STA BILIZAT ION . . . . . . . . . . .. 2-1 BACKGROUND . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 2-1 lITERATURE REVIEW ......................................... 2-2 Fly Ash .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 2-2 Soils .................................................. 2-3 Fly Ash and Lime-Fly Ash Stabilization ........................... 24 ix TABLE OF CONTENTS (Continued) Page MATERIALS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 2-6 Soils .................................................. 2-6 Fly Ash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-11 Lime . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-11 TEST DESCRIPTIONS .......................................... 2-14 MOISTURE-DENSITY RELATIONSHIP FOR A-3 SOIL .................... 2-17 UNCONFINED COMPRESSIVE STRENGTH FOR A-3 SOIL ................. 2-21 AITERBERG LIMITS FOR A-7-6 SOIL ............................... 2-24 MOISTURE-DENSITY RELATIONSHIP FOR A-7-6 SOIL ................... 2-24 UNCONFINED COMPRESSIVE STRENGTH FOR A-7-6 SOIL ............... 2-24 ONE-DIMENSIONAL EXPANSION FOR A-7-6 SOIL ...................... 2-27 SUMMARY OF FINDINGS AND RECOMMENDATIONS . . . . . . ............. 2-27 n ...................................... REFERENCES - SECTION 2-31 m - SECTION USE OF BY-PRODUCT GYPSUM IN ROADWAY CONSTRUCTION . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 3-1 BACKGROUND . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 3-1 By-Product Gypsum ........ . . . . . . . . . . . . . . . . . . . ~ . . . . . . . . . . .. 3-1 Coal Combustion By-products (CCBP) ............................ 3-2 Dry Bottom Ash and Boiler Slag ... . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 3-2 Flue-Gas Desulfurization Gypsum ............................... 3-2 Tn EXPERIENCE WITH BY- PRODUCT GYPSUM . . . . . . . . . . . . . . . . . . . . . .. 3-5 Fly Ash and Cement-Stabilized Gypsum ........................... 3-5 Problems Areas with By-Product Gypsum Construction ................. 3-11 Problems Areas with Gypsum Roadbase Construction .................. 3-11 x
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