96 Springer Series in Solid-State Sciences Edited by Manuel Cardona Springer Series in Solid-State Sciences Editors: M. Cardona P. Fulde K. von Klitzing H.-J. Queisser Managing Editor: H. K.Y. Lotsch Volumes 1-89 are listed at the end of the book 90 Earlier and Recent Aspects of Superconductivity Editors: J. G. Bednorz and K. A. Miiller 91 Electronic Properties of Conjugated Polymers III Basic Models and Applications Editors: H. Kuzmany, M. Mehring, and S. Roth 92 Physics and Engineering Applications of Magnetism Editors: Y. Ishikawa and N. Miura 93 Quasicrystals Editors: T. Fujiwara and T. Ogawa 94 Electronic Conduction in Oxides By N. Tsuda, K. Nasu, A. Yanase, and K. Siratori 95 Electronic Materials A New Era in Materials Science Editors: J. R. Chelikowsky and A. Franciosi 96 Electron Liquids By A. Isihara 97 Localization and Confinement of Electrons in Semiconductors Editors: F. Kuchar, H. Heinrich, and G. Bauer 98 Magnetism and the Electronic Structure of Crystals By V. A. Gubanov, A. I. Liechtenstein, and A.V. Postnikov 99 Electronic Properties of High-Tc Superconductors and Related Compounds Editors: H. Kuzmany, M. Mehring, and J. Fink 100 Electron Correlations in Molecules and Solids By P. Fulde 101 High Magnetic Fields in Semiconductor Physics III Quantum Hall Effect, Transport and Optics By G. Landwehr 102 Conjugated Conducting Polymers Editor: H. Kiess 103 Molecular Dynamics Simulations Editor: F. Yonezawa 104 Products of Random Matrices in Statistical Physics By A. Crisanti, G. Paladin, and A. Vulpiani 105 Self-Trapped Excitons By K. S. Song and R. T. Williams 106 Physics of High-Temperature Superconductors Editors: S. Maekawa and M. Sato 107 Electronic Properties of Polymers Orientation and Dimensionality of Conjugated Systems Editors: H. Kuzmany, M. Mehring, and S. Roth 108 Site Symmetry in Crystals Theory and Applications By R. A. Evarestov and Y. P. Smirnov 109 Transport Phenomena in Mesoscopic Systems By H. Fukuyama, T. Ando 1 10 Symmetry and Optical Phenomena in Superlattices and Other Heterostructures By E. L. Ivchenko, G. E. Pikus III Low-Dimensional Electronic Systems New Concepts By. G. Bauer, F. Kuchar, H. Heinrich Akira Isihara Electron Liquids With 116 Figures Springer-Verlag Berlin Heidelberg New York London Paris Tokyo Hong Kong Barcelona Budapest Professor Akira Isihara, Ph. D. JlDECO of Bardstown, Inc., 901 Withrow Court, Bardstown, KY 40004, USA Series Editors: Professor Dr., Dres. h. c. Manuel Cardona Professor Dr., Dr. h. c. Peter Fulde Professor Dr., Dr. h. c. Klaus von Klitzing Professor Dr., Dres. h. c. Hans-Joachim Queisser Max-Planck-Insitut flir Festkorperforschung, Heisenbergstrasse 1, W -7000 Stuttgart 80, Fed. Rep. of Germany Managing Editor: Dr. Helmut K. V. Lotsch Springer-Verlag, Tiergartenstrasse 17, W-6900 Heidelberg, Fed. Rep. of Germany ISBN-I3: 978-3-642-97305-5 e-ISBN-13: 978-3-642-97303-1 DOl: 10.1007/978-3-642-97303-1 Library of Congress Cataloging-in-Publication Data. Isihara, A. (Akira). Electron liquids 1 Akira Isihara. p. cm. - (Springer series in solid-state sciences; v. 96) Includes bibliographical references and index.ISBN·ll 978-3-642-97305-5(Berlin: acid-free paper).ISBN-ll 978-3-M2-97305-5 (New York: acid-free paper) 1. Solid state physics. 2. Electronic structure. 3. Electron-hole droplets. 4. Plasma (Ionized gases) 1. Title. II. Series. QC176.l75 1993 530.4'12-dc20 92-20407 This work is subject to copyright. All rights are reserved, whether the whole or part of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcast ing, reproduction on microfilms or in any other way, and storage in data banks. Duplication of this publication or parts thereof is permitted only under the provisions of the German Copyright Law of September 9, 1965, in its current version, and permission for use must always be obtained from Springer-Verlag. Violations are liable for prosecution under the German Copyright Law. © Springer-Verlag Berlin Heidelberg 1993 Softcover reprint of the hardcover 15t edition 1993 The use of general descriptive names, registered names, trademarks, etc. in this publication does not imply, even in the absence of a specific statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. 54/3140 -5 4 3 2 1 0 -Printed on acid-free paper VI Preface Press, Gordon & Breach Science Publishers, Inc., and lOP Publishing Ltd. The author's original work in this book was supported by the National Science Foundation and the Office of Naval Research. Buffalo, NY A.Isihara July 1992 Preface The study of electronic properties reveals a common basis for a variety of systems, including gaseous plasmas, ionic solutions, metals, and semiconduc tors. This study started with one-electron properties in free space, as discussed in solid-state books. However, significant progress has been made recently in more realistic and complicated cases with interactions, confinements, im purities, and fields. Moreover, the recent discoveries of the quantum Hall ef fect, high-Tc superconductors, and localization phenomena, along with the in troduction of low-dimensional materials have opened new areas and have led to a tremendous number of articles in existing journals and even new specialized journals. This book has been written to provide a new, comprehen sive review on electronic properties in such diverse areas and materials. The title indicates emphasis on electron correlations. Chapter 1 starts with an introductory description of electron systems, including classification, characterization, and models. It provides the reader with a general account of the amazingly diverse electron systems. It is followed by discussions on strong ly coupled gaseous plasmas, electron-hole liquids, magnetic response, low dimensional systems, heavy Fermions, high-Tc superconductivity, localization, and the quantum Hall effect. For simplicity the natural unit in which h = 1 and 2m = 1 is used, par ticularly for complicated expressions, m being the electron mass. However, or dinary units are restored whenever desirable. This restoration can easily be made by considering dimensions. Each chapter has been written so as to be self-contained, so that the reader can start at any chapter without going through previous chapters. Nevertheless, an effort has been made to maintain uniformity and coherence as a single book. The author had an opportunity to meet with Professor Cardona who visited Buffalo in the spring of 1989. The present book has emerged as a result of his encouragement and stimulation. The patience and efforts of Dr. Lotsch have also contributed to its completion. The author is especially grateful to At sushi and Hikaru who gave him many constructive suggestions. He is indebted to various investigators, physical societies, and publishers for permission to reproduce figures. These include the American Physical Society, the Physical Society of Japan, Progress of Theoretical Physics, Nature, Physica Status Solidi, Pergamon Press, Inc., North-Holland Publishing Company, Plenum Contents 1. General Description of Electron Systems . . . . . . . . . . . . . . . . . . . . . . . 1 1.1 Classification of Electron Systems ......................... 1 1.2 Low-Dimensional Electron Systems ........................ 5 1.2.1 1Wo-Dimensional Electron Systems ................... 5 1.2.2 One-Dimensional Electron Systems ................... 10 1.3 Characteristic Lengths ................................... 13 1.4 Fermi Liquid Theory .................................... 15 1.5 Tight Binding, Anderson and Hubbard Models ............. 18 2. Dielectric Function ......................................... 21 2.1 RPA Dielectric Function ................................. 21 2.2 Beyond the RPA ........................................ 27 2.2.1 Monte Carlo Calculations ........................... 27 2.2.2 Hubbard's Attempt... . ... . ....... .............. . ... 29 2.2.3 Phenomenological Consideration of e(q, w) ........... 30 2.2.4 Self-Consistent Approach ........................... 31 2.2.5 Excess Energy ..................................... 35 2.3 Plasmon Dispersion ..................................... 36 3. One-Component Plasmas at High Temperatures ................ 43 r 3.1 e and Series .......................................... 43 3.2 Quantum Effects at High Temperatures .................... 50 3.3 Short-Distance Correlations .............................. 54 4. Low Temperature Plasmas ................................... 57 4.1 Asymptotic Correlations ................................. 57 4.1.1 Long-Distance Correlations and the Effect of Impurities ...................................... 57 4.1.2 Ladder Diagram Contribution ....................... 59 4.2 Correlation Energy in Three Dimensions ................... 62 4.2.1 Ideal Gas Contribution ............................. 63 4.2.2 First-Order Exchange Contribution ................... 64 4.2.3 Ring Diagram Contribution ......................... 64 4.2.4 Direct Calculation of the Ring Energy ................ 66 4.2.5 Second-Order Exchange Contribution . . . . . . . . . . . . . . . . . 67 4.2.6 Correlation Energy ................................. 68 4.3 Correlation Energy of 2D Electrons ....................... 69 VIII Contents 5. Electron - Hole Liquids ..................................... 73 5.1 Excitons ............................................. 73 5.2 Phase Diagram ....................................... 80 5.3 2D Electron-Hole Plasma ............................. 84 6. Correlation in a Magnetic Field ............................. 91 6.1 Spatial Correlation in a Magnetic Field .................. 91 6.2 Magnetic Response in Three Dimensions ................. 97 6.2.1 Exchange Effect at High Temperatures ............. 97 6.2.2 Ideal Electron Gas at Low Temperatures ........... 99 6.2.3 Exchange Effects at Low Temperatures ............. 100 6.2.4 Correlation Effects .............................. 102 6.2.5 Local Field Correction ........................... 108 6.3 Effective g-Factor in Si Inversion Layers ................. 109 6.4 Coulomb Effects on 2D de Haas-van Alphen Oscillations. 114 6.4.1 Chemical Potential .............................. 114 6.4.2 Exchange Effect ................................ 116 6.4.3 Correlation Contribution . . . . . . . . . . . . . . . . . . . . . . . . . 118 6.4.4 de Haas-van Alphen Oscillations ................. 119 6.5 Field Induced SDW States of ID Conductors. . . . . . . . . . . . . 123 7. Electronic Specific Heat .................................... 129 7.1 Correlation Effects .................................... 129 7.1.1 Lidiard Approximation .......................... 129 7.1.2 Exchange and Correlation Effects ................. 131 7.1.3 Specific Heat of 2D Electrons .................... 135 7.2 Magnetothermal Effect in Two Dimensions ............... 137 7.3 Heavy Fermions ...................................... 142 8. Magnetoconductivity in 1\vo Dimensions ..................... 151 8.1 Magnetoconductivityof 2D Electrons. . . . . . . . . . . . . . . . . . . . 151 8.2 Memory Function Formalism ........................... 159 8.3 Anomalous Cyclotron Resonance ....................... 163 9. Localization .............................................. 171 9.1 Anderson Localization and Scaling ...................... 171 9.2 Weak Localization .................................... 176 9.2.1 Interference Effect .............................. 176 9.2.2 Magnetic Field Effects ........................... 180 9.3 Interaction Effect ..................................... 185 10. Hopping, Percolation and Conductance Fluctuations ........... 193 10.1 Hopping and Percolation .............................. 193 10.2 Universal Conductance Fluctuations in 1D Systems ........ 203 10.3 Conductance of TTF/TCNQ ........................... 210 Contents IX 11. High TcSupercouductivity .................................. 215 11.1 Electron Pairing in BCS Theory ........................ 215 11.2 Properties of High Tc Superconductors .................. 218 11.2.1 2-1-4 Compounds ............................... 218 11.2.2 1-2-3 Compounds ............................... 220 11.2.3 Copperless Oxides .............................. 222 11.2.4 Characteristic Properties ......................... 223 11.3 Theoretical Consideration .............................. 227 12. Integral Quantum Hall Effect ............................... 233 12.1 Quantization of Hall Conductivity of 2D Electrons ....... 233 12.2 Localization and Scaling ............................... 242 12.3 Theoretical Interpretation .............................. 246 13. Fractional Quantum Hall Effect ............................. 253 13.1 Experimental Results .................................. 253 13.2 Ground State of the FQHE ............................ 258 13.3 Elementary Excitations and Off-Diagonal Long Range Order .................... 264 Appendix .................................................... 271 A.1 Pair Distribution Function ............................. 271 A.2 Classical and Quantum Chains ......................... 277 A.3 Ring Diagram Formulas ............................... 284 A.4 Density Functional Approach ........................... 287 References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 291 Subject Index . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 303 A high-purity germanium crystal is cut into a 4 mm disk and stressed at the top by a nylon screw. The sample is immersed in liquid helium at 2 K and excited from the far side by an argon-ion laser. The electrons and holes produced by photoexcitation condense into electron-hole droplets and are drawn into the region beneath the screw, where the energy gap is lowered by a local strain. The droplets coalesce into a single large drop at the strain maximum, or energy maximum. Bright emis sion from the drop is produced by the radiative recombination of electrons and holes at about 1.75!lm wavelength, which is detected with an infrared vidicon tube. [J.P. Wolfe, W.L. Hansen, E. E. Haller, R. S. Markiewicz, C. Kittel, C. D. Jeffries: Phys. Rev. Lett. 34, 1292 (1975)]
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