Development of press forming techniques for thermoplastic composites Investigation of a multiple step forming approach Francisco Saraiva MSc Thesis in Aerospace Engineering Structural Integrity & Composites Development of press forming techniques for thermoplastic composites Investigation of a multiple step forming approach by Francisco Saraiva toobtainthedegreeofMasterofScience attheDelftUniversityofTechnology, tobedefendedpubliclyonFridayMarch17,2017at01:30PM. Studentnumber: 4413725 Thesiscommittee: Ir.J.Sinke, TUDelft,Supervisor Dr.ir.R.C.Alderliesten, TUDelft,Chairman Dr.ir.O.K.Bergsma, TUDelft Dr.ir.J.M.J.F.vanCampen, TUDelft Anelectronicversionofthisthesisisavailableathttp://repository.tudelft.nl/. Summary Thermoplasticcompositesareveryattractiveforaerospacestructuresduetotheirhighspecificstrength andstiffness,enhancedtoughnessandhightemperatureresistance. Oneofthemanufacturingmeth- odsusedtoproducethermoplasticcompositepartsispressforming.Pressformedpartstypicallyhave constantthicknessandfibreorientation. However,compositepartsmaybeoptimizedbytailoringthe stiffnessandstrength,therebyreducingstructuralweight. Inthisthesis,theprocessingtechniquesfor thismanufacturingmethodweredevelopedbyinvestigatingthefeasibilityofamultiplestepforming approachfortheproductionofpartswithvariablethicknessandfibreorientation.Thismanufacturing approachwasprovenfrombothaformabilityandstructuralintegrityviewpoints.Byusinganefficient blankholdersystemwithclampsandsprings,thermoplasticcompositelaminatescanbemultiplestep formedintothree-dimensionalshapeswithnooccurrenceofvisualformingdefectssuchaswrinkling, fibre buckling or ply folding. Furthermore, good quality bonds can be achieved between laminates formedandco-consolidatedindifferentsteps. ToachieveahighdegreeofbondingbetweenGF/PEI composite laminates, the co-consolidation process window was estimated to be between 270ºC and 300ºC.Theuseofapost-consolidationstageinahotpresswasneededtoimprovethedegreeofbond- ing between co-consolidated laminates formed in different steps, which led to very long production cycle times. For future research, the maximum temperature limit of the metal mould should be in- creasedandtoolingactivecoolingmechanismsmustbeincorporatedtoallowthemouldtoberapidly cooleddown,therebydecreasingproductioncycletimes. Withtheseimplementations,abetterinsight onthefeasibilityoftheprocessinanindustrialenvironmentmaybegained. iii Contents ListofFigures vii ListofTables xi ListofAcronyms xiii ListofSymbols xv 1 Introduction 1 1.1 ResearchQuestions. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 1.2 ThesisOutline . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 2 LiteratureReview 5 2.1 DeformationMechanisms . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6 2.1.1 Intra-plyshear . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6 2.1.2 Fibrestraightening . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7 2.1.3 Inter-plyslippage. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7 2.1.4 Tool-plyslippage . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8 2.1.5 Resinpercolation. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9 2.1.6 Transversesqueezeflow . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9 2.2 Processvariants. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9 2.2.1 Matcheddieforming . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9 2.2.2 Rubberforming . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10 2.2.3 Diaphragmforming . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11 2.3 Formabilityofthermoplasticcomposites . . . . . . . . . . . . . . . . . . . . . . . . . . . 12 2.4 Processinduceddeformations. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13 2.5 Effectsofstampinginmaterialmechanicalandphysicalproperties. . . . . . . . . . . . . 14 2.6 Discussion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15 3 DesignoftheExperimentalSetup 17 3.1 Experimentalsetupassemblies . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18 3.1.1 Rig. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18 3.1.2 Blankholder . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19 3.1.3 Pressassembly. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20 3.2 Designchoicesandconsiderationsofthepressassembly . . . . . . . . . . . . . . . . . . 21 3.2.1 Extensioncylinder . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22 3.2.2 Topmountingplate. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22 3.2.3 Rubbermouldandrubbermouldbox. . . . . . . . . . . . . . . . . . . . . . . . . . . 22 3.2.4 Metalmould . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 25 3.2.5 Constrainingblocks . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 25 3.2.6 Bottommountingplate. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 26 3.2.7 Heatingplate. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27 3.3 Overviewofthepressassembly. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31 4 MultipleStepFormingofGF/PEIWovenCompositeLaminates 33 4.1 ExperimentalProcedure . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34 4.1.1 Materialsandblankpreparation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34 4.1.2 PressForming . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 35 4.1.3 Temperaturemeasurements . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37 4.1.4 Microscopy. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37 v vi Contents 4.2 ResultsandDiscussion. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 38 4.2.1 Temperaturecurves . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 38 4.2.2 Formingbehaviour. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 43 4.2.3 Demonstrator . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 48 4.2.4 Microscopy. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 49 4.3 Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 50 5 ModeIInterlaminarFractureToughnessofCo-ConsolidatedGF/PEIComposites 51 5.1 ExperimentalProcedure . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 53 5.1.1 Preconsolidatedlaminates . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 53 5.1.2 Co-consolidatedlaminates . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 54 5.1.3 Specimenpreparation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 55 5.1.4 Microscopy. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 56 5.2 Methodology . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 57 5.2.1 Orthogonalarrayexperiment. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 57 5.2.2 DoubleCantileverBeamtests . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 58 5.2.3 Statisticalanalysis . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 60 5.3 ResultsandDiscussion. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 62 5.3.1 DCBtestresults . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 62 5.3.2 ANOMresults . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 65 5.3.3 ANOVAresults. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 66 5.3.4 Interactionplots . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 66 5.4 Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 69 6 Multiplestepformingandpost-consolidationofGF/PEIcompositelaminates 71 6.1 ExperimentalProcedure . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 72 6.1.1 Materialsandblankpreparation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 72 6.1.2 Multiplestepformingprocess. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 72 6.1.3 Post-consolidationprocess . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 73 6.1.4 Specimenpreparation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 75 6.2 ResultsandDiscussion. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 76 6.2.1 DCBtestresults . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 76 6.2.2 Qualitativeanalysisofpost-consolidatedformedshape. . . . . . . . . . . . . . . . . . 77 6.3 Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 78 7 ConclusionsandRecommendations 79 A Designinganorthogonalarrayexperiment 83 B Statisticalmethods-AnalysisofMeansandAnalysisofVariance 85 B.1 Analysisofmeans(ANOM) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 85 B.2 Analysisofvariance(ANOVA) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 86 C DoubleCantileverBeamTestDataandLoad-DisplacementCurves 89 C.1 PreconsolidatedSpecimens . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 89 C.2 Co-consolidatedSpecimensRun1. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 91 C.3 Co-consolidatedSpecimensRun2. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 93 C.4 Co-ConsolidatedSpecimensRun3 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 94 C.5 Co-ConsolidatedSpecimensRun4 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 95 C.6 Co-ConsolidatedSpecimensRun5 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 96 C.7 Co-ConsolidatedSpecimensRun6 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 97 C.8 Co-ConsolidatedSpecimensRun7 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 98 C.9 Co-ConsolidatedSpecimensRun8 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .100 C.10 Co-ConsolidatedSpecimensRun9 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .101 C.11 Post-consolidatedspecimensfrommultiplestepformedshape . . . . . . . . . . . . . . .102 C.12 Preconsolidatedspecimensfromnewmaterial . . . . . . . . . . . . . . . . . . . . . . . .103 Bibliography 105 List of Figures 1.1 Boeing787materialstructuralweightdistribution[1] . . . . . . . . . . . . . . . . . . . . 1 1.2 Comparisonofthermosetandthermoplasticpolymerstructures[3] . . . . . . . . . . . . 2 1.3 Tandempresslineconfiguration[8]. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 1.4 Multiplestepformingapproachforthemanufacturingofavariablethicknesspart . . . 3 2.1 Stagesofthepressformingprocess[11] . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5 2.2 Intra-plyshearinfabriclayer[12] . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6 2.3 Intra-plyshearinUDplies[9] . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7 2.4 Processwindowof90ºbends[23] . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10 2.5 Schematicexplanationofthebalancebetweentheapparentintra-ply(IR),frictional(FR), andbending(BR)rigidityoftheplies[35] . . . . . . . . . . . . . . . . . . . . . . . . . . . 12 3.1 Overviewofexperimentalsetup . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18 3.2 (a) Rig with integrated IR-panels, ventilation system, moving frame, (b) rail and glass platesusedtoprotectIR-lamps . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19 3.3 (a) Blankholder holding the laminate through springs and crocodile clamps and (b) loadedintothemovingframeoftherig . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20 3.4 Overviewofthepressassembly . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20 3.5 Explodedviewofthepressassembly(obs: rubbermouldnotdepicted) . . . . . . . . . . 21 3.6 Topmountingplate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22 3.7 Rubbermouldandtheexistinggapswithrespecttothemetalmould . . . . . . . . . . . 23 3.8 Materialruptureuponformingwithhighclampingpressures[20] . . . . . . . . . . . . . 24 3.9 Schematicrepresentationofmouldclosingsequence . . . . . . . . . . . . . . . . . . . . . 24 3.10 Laminatedeformations[34] . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 24 3.11 Metalmould . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 25 3.12 Constrainingblockpreventingmetalmouldfrombeingreleasedfrommountingplate . 26 3.13 Metalmouldconstrainedbyblocksandrubberpads . . . . . . . . . . . . . . . . . . . . . 26 3.14 (a)Schematicand(b)realrepresentationofmetalstripsactingasstoppers . . . . . . . . 26 3.15 GuidingPins . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27 3.16 Insulatingblockaroundmetalmould . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27 3.17 Heatingplatewithfiveheatingelements . . . . . . . . . . . . . . . . . . . . . . . . . . . 28 3.18 Heatingplatecavitiestoinsertthermalswitches . . . . . . . . . . . . . . . . . . . . . . . 29 3.19 Schematicrepresentationofelectricalcircuitintegratedintheheatingplate . . . . . . . 29 3.20 Technicalrepresentationofelectricalcircuitintegratedintheheatingplate . . . . . . . . 29 3.21 Powercontroller . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 30 3.22 Overviewofpressassembly . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31 3.23 GuidingpinsfixedtothetopmountingplateandM12boltsusedtofixthebottompress assemblytothepress . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 32 4.1 Layupschematicrepresentation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34 4.2 ConsolidationtemperatureandpressureprofilesofGF/PEIlaminate . . . . . . . . . . . 34 4.3 Blankcuttinglayout . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 35 4.4 Pressformingstagesandindicationoflaminateandmoulds’temperatures. . . . . . . . 36 4.5 Thermocouplesinstrumentedatthebottomsurfaceofthemetalmouldandatthecenter ofthelaminatetobeformedinthefirststep . . . . . . . . . . . . . . . . . . . . . . . . . . 37 4.6 Dataacquisitionsystemandthermocoupleinstrumentedonthesidewalloftherubber mould. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37 4.7 Experimentalrunnº1&Formingstepnº1-Laminateandmoulds’temperaturecurves . 38 4.8 Heatsourcesduringtheconsolidationstageofapressformingprocess . . . . . . . . . . 39 vii viii ListofFigures 4.9 Experimentalrunnº2&Formingstepnº1-Laminateandmoulds’temperaturecurves . 40 4.10 Experimentalrunnº3&Formingstepnº1-Laminateandmoulds’temperaturecurves . 41 4.11 Experimentalrunnº3&Formingstepnº2-Interfaceandmoulds’temperaturecurves . 41 4.12 Experimentalrunnº4&Formingstepnº1-Laminateandmoulds’temperaturecurves . 42 4.13 Experimentalrunnº4&Formingstepnº2-Interfaceandmoulds’temperaturecurves . 42 4.14 Blankspringbackandreleasefromthemouldinexperimentalruns1and2 . . . . . . . 44 4.15 Blanksformedin1stformingsteponruns3and4 . . . . . . . . . . . . . . . . . . . . . . 44 4.16 Largercornerradiiatthetwoedgesoftheformedshape . . . . . . . . . . . . . . . . . . 45 4.17 Constraint of rubber mould’s sides in order to reduce non-uniform pressure distribu- tions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 45 4.18 Multiplestepformedshapewith2ndblankco-consolidatedto1stblank. . . . . . . . . . 46 4.19 FormingscenarioA,whereblankdoesn’tmakecontactwithmetalmould’ssurfacedur- ingforming . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 46 4.20 FormingscenarioB,whereblankmakescontactwithmetalmould’ssurfaceduringthe entireformingprocess . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 46 4.21 Run3-Multiplestepformedshapewith(a)novisualformingdefects,but(b)withvery weakbond . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 47 4.22 Demonstratorpartafter(a)1stand(b)2ndformingsteps,showingaccuratedimensional controlandalignmentwithrespecttothemould . . . . . . . . . . . . . . . . . . . . . . . 48 4.23 Demonstratorpartmanufacturedviathreeformingsteps . . . . . . . . . . . . . . . . . . 48 4.24 Cross-sections of co-consolidated flanges in runs (a) 3 and (b) 4 (10x magnification), showingnoevidenceofaninterfacebetweenco-consolidatedlaminates . . . . . . . . . 49 5.1 Threemodesofloadingadelamination: (a)opening,(b)shearingand(c)tearing[60] . . 51 5.2 LongitudinaltensilefailureinSBStestspecimen . . . . . . . . . . . . . . . . . . . . . . . 52 5.3 Layupof14-plylaminatewithKaptonfilminsertedatthemidplane . . . . . . . . . . . 53 5.4 TemperatureandpressureprofilesofGF/PEIpreconsolidatedspecimens . . . . . . . . 53 5.5 Productionsequenceof14-plyco-consolidatedplateswith(a)layupandconsolidation of7-plylaminate,(b)stackingoftwo7-plypreconsolidatedlaminateswith(c)aKapton insertattheinterface . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 54 5.6 Co-consolidationrun3-Programmedtemperatureandpressureprofiles . . . . . . . . . 55 5.7 Co-consolidationrun3-Measuredtemperature . . . . . . . . . . . . . . . . . . . . . . . 55 5.8 Specimencuttinglayout . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 55 5.9 Excessadhesiveafterpost-curing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 56 5.10 DCBspecimenconfiguration . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 56 5.11 (a) DCB test load-displacement curve and (b) delamination resistance curve showing higherG propagationvaluesthaninitiationvalues. . . . . . . . . . . . . . . . . . . . . 58 IC 5.12 Areaunderload-displacementcurveofDCBtestedspecimen . . . . . . . . . . . . . . . 59 5.13 (a)Schematicandreal(b)representationsofthevariablet. . . . . . . . . . . . . . . . . . 60 5.14 DCBtestresultsofpreconsolidatedandco-consolidatedlaminates . . . . . . . . . . . . 62 5.15 Thicknessresultsforpreconsolidatedandco-consolidatedlaminates . . . . . . . . . . . 63 5.16 Microscopycross-sectionsof14-plypreconsolidatedlaminateat320ºCwithlargeareas offibre-fibrecontactatthemidplaneinterface(2.5xmaginification) . . . . . . . . . . . . 64 5.17 Microscopycross-sectionsof14-plyco-consolidatedlaminateat270ºCwithsmallareas offibre-fibrecontactatthemidplaneinterface(2.5xmaginification) . . . . . . . . . . . . 64 5.18 Microscopycross-sectionsof14-plyco-consolidatedlaminateat300ºCwithlargeareas offibre-fibrecontactatthemidplaneinterface(2.5xmaginification),butpossiblylower thanpreconsolidatedlaminates’. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 64 5.19 G VISvsTime,TemperatureandPressurescatterplots . . . . . . . . . . . . . . . . . . 65 IC 5.20 MaineffectsplotsforG VISoutput . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 65 IC 5.21 InteractionplotsforG VISoutput . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 67 IC 5.22 Maineffectsplotsforthicknessoutput . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 68 6.1 Multiplestepformingprocessfollowedbyapost-consolidationstep . . . . . . . . . . . 71 6.2 Blankcuttinglayout . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 72
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