Computational and experimental analysis of functional materials

560 Pages·2017·105.489 MB·English

by  Reshetnyak, Oleksandr, Zaikov, Gennadiĭ

COMPUTATIONAL AND
EXPERIMENTAL ANALYSIS OF
FUNCTIONAL MATERIALS

AAP Research Notes on Polymer Engineering
Science and Technology
COMPUTATIONAL AND
EXPERIMENTAL ANALYSIS OF
FUNCTIONAL MATERIALS
Edited by
Oleksandr V. Reshetnyak, DSc
Gennady E. Zaikov, DSc
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Library and Archives Canada Cataloguing in Publication
Computational and experimental analysis of functional materials / edited by Oleksandr Reshetnyak, DSc, Gennady E.
Zaikov, DSc.
(AAP research notes on polymer engineering science and technology series)
Includes bibliographical references and index.
Issued in print and electronic formats.
ISBN 978-1-77188-342-9 (hardcover).--ISBN978-1-315-36635-7 (PDF)
1. Polyanilines--Synthesis. 2. Polymeric composites. I. Zaikov, G. E. (Gennadii Efremovich), 1935-, editor
II. Reshetnyak, Oleksandr, author, editor III. Series: AAP research notes on polymer engineering science and
technology series
TP1180.P552C64 2017 668.9 C2016-907864-7 C2016-907865-5
Library of Congress Cataloging-in-Publication Data
Names: Reshetnyak, Oleksandr, editor. | Zaikov, G. E. (Gennadiæi Efremovich), 1935- editor.
Title: Computational and experimental analysis of functional materials / editors, Oleksandr Reshetnyak, DSc,
Gennady E. Zaikov, DSc.
Description: Toronto : Apple Academic Press, [2017] | Includes bibliographical references and index.
Identifiers: LCCN 2016054503 (print) | LCCN 2016057620 (ebook) | ISBN 9781771883429 (hardcover : alk. paper)
| ISBN 9781315366357 (ebook)
Subjects: LCSH: Polyanilines. | Conducting polymers. | Materials science.
Classification: LCC TP1180.P552 C66 2017 (print) | LCC TP1180.P552 (ebook) | DDC 620.1/9204297--dc23
LC record available at https://lccn.loc.gov/2016054503
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This book is dedicated to the memory of
Professor Eugen P. Koval’chuk, DSc
(1939–2012)

ABOUT THE EDITORS
Oleksandr V. Reshetnyak, DSc
Oleksandr Reshetnyak, DSc, is Head of the Department of Physical and
Colloid Chemistry of Ivan Franko National University of Lviv (Lviv,
Ukraine). He is the author of two monographs and more than 150 publica-
tions in various journals and conference proceedings. His scientific activity
is in the fields of physical chemistry of nanosystems, conductive polymers
and its composites, electrochemistry of organic compounds, and chemi- and
electrochemiluminescence. He is a member of the Editorial Board of the
Visnyk Lviv University Journal (Series: Chemistry) (Lviv, Ukraine) as well
as a member of the Editorial Board of the bimonthly scientific and technical
international journal Materials Science. He is also an active member of the
Taras Shevchenko Scientific Society (Lviv, Ukraine).
Contact address:
6 Kyryla & Mefodiya Str., Lviv, 79005, Ukraine
Tel: (+38) (032) 2600–397
Fax: (+38) (032) 2600–397
E-mail: [e-mail]; [e-mail].
Gennady E. Zaikov, DSc
Gennady Zaikov, DSc, is Head of the Department of the Kinetics of Chem-
ical & Biological Processes at the N. M. Emanuel Institute of Biochemical
Physics at the Russian Academy of Sciences (Moscow, Russia) and Professor
at Moscow State Academy of Fine Chemical Technology (Russia) as well
as Professor at Kazan National Research Technological University (Kazan,
Russia). He is also a prolific author, researcher, and lecturer.
Contact address:
4 Kosygin Str., Moscow, 119991, Russia
Tel: [phone]
Fax: [phone]
E-mail: [e-mail]

CONTENTS
List of Contributors .......................................................................................xi
List of Abbreviations ...................................................................................xiii
Supporting Institutions ................................................................................xix
Preface ........................................................................................................xxi
1. Polyanilines: The Role of Particles of Radical Nature in Obtaining
of Polymers/Copolymers with a System of Conjugated π-Bonds ...............1
O. V. Reshetnyak, M. M. Yatsyshyn, and L. I. Bazylyak
2. Morphology of Polyaniline’s Films Electrochemically Deposited
on the Surface of Al-Based Amorphous Metal Alloys ................................61
М. М. Yatsyshyn, L. М. Boichyshyn, I. I. Demchyna, and Yu. A. Hnizdiukh
3. Electrooptic Phenomena in Conjugated Polymeric Systems Based
on Polyaniline and Its Derivatives ...............................................................91
О. I. Aksimentyeva, О. I. Konopelnyk, and D. О. Poliovyi
4. An Investigation of Monomolecular Films of Polyanilines .....................151
I. Ye. Opaynych, О. I. Aksimentyeva, and Yu. Yu. Horbenko
5. Epoxy–Polyaniline Composites: Synthesis, Structure, Properties .........179
V. P. Zakordonskiy, О. I. Aksimentyeva, and A. I. Krupak
6. Thermochromic Effect in the Films of Conjugated Polyaminoarenes ...219
О. I. Konopelnyk and О. I. Aksimentyeva
7. Polyaniline in Chemo-and Biosensorics: Overview .................................243
Ya. S. Kovalyshyn and O. V. Reshetnyak
8. Corrosion Protection of Aluminum and Al-Based Alloys by
Polyaniline and Its Composites ..................................................................287
О. V. Reshetnyak and М. M. Yatsyshyn
9. Synthesis and Physico–Chemical Properties of Composites of
Conjugated Polyaminoarenes with Dielectric Polymeric Matrices ........331
О. I. Aksimentyeva, О. I. Konopelnyk, G. V. Martyniuk, and O. M. Yevchuk
10. Polyanilines: Generation of Electrochemiluminescence ..........................371
О. V. Reshetnyak