Characterization and Assessment of Irrigation Water Quality in relation to Nitrate, Fluoride and Boron of Western Madhya Pradesh – A case study of Mandsaur District THESIS Submitted to the Rajmata Vijayaraje Scindia Krishi Vishwa Vidyalaya, Gwalior (M.P.) In partial fulfilment of the requirement for the degree of MASTER OF SCIENCE In AGRICULTURE (SOIL SCIENCE & AGRICULTURAL CHEMISTRY) By Rambalwan Jatav Department of Soil Science & Agricultural Chemistry, Rajmata Vijayaraje Scindia Krishi Vishwa Vidyalaya College of Agriculture, Indore (M.P.) Indore (M.P.) 2013 CERTIFICATE – I This is to certify that the thesis entitled “Characterization and Assessment of Irrigation Water Quality in relation to Nitrate, Fluoride and Boron of Western Madhya Pradesh – A case study of Mandsaur District” submitted in partial fulfilment of the requirements for the degree of MASTER OF SCIENCE IN AGRICULTURE (DEPARTMENT OF SOIL SCIENCE & AGRICULTURAL CHEMISTRY) of Rajmata Vijayaraje Scindia Krishi Vishwa Vidyalaya, Gwalior is a record of the bonafied research work carried out by Mr. Rambalwan Jatav, ID No. A/GW/222/2005 under my guidance and supervision. The subject of the thesis has been approved by the Student’s Advisory Committee and the Director of Instruction. No part of the thesis has been submitted for any other degree or diploma (Certificate awarded etc.) or has been published. All the assistance and help received during the course of the investigation has dully been acknowledged by him. Place: Indore Date: (Dr. V. K. Khaddar) Chairman of the Advisory Committee THESIS APPROVED BY THE STUDENT’S ADVISORY COMMITTEE Chairman : Dr. V. K. Khaddar ……………………… Member : Dr. U.R. Khandkar .............................. Member : Dr. K. S. Kumar ……………………… CERTIFICATE – II This is to certify that the thesis entitled “Characterization and Assessment of Irrigation Water Quality in relation to Nitrate, Fluoride and Boron of Western Madhya Pradesh – A case study of Mandsaur District” submitted by Mr. Rambalwan Jatav, ID No. A/GW/222/2005 to the Rajmata Vijayaraje Scindia Krishi Vishwa Vidyalaya, Gwalior, in partial fulfilment of the requirements for the degree of Master of Science in Agriculture (Department of Soil Science & Agricultural Chemistry) College of Agriculture, Indore, has been, approved after evaluation by the External Examiner and by the Student’s Advisory Committee after an oral examination on the same. Place: Indore Date: (Dr. V. K. Khaddar) Chairman of the Advisory Committee MEMBERS OF THE ADVISORY COMMITTEE Chairman : Dr. V. K. Khaddar ………………………. Member : Dr. U.R. Khandkar ………………………. Member : Dr. K. S. Kumar ………………………. Head of the Department: Dr. U.R. Khandkar …………………….... Dean: Dr. A. M. Rajput ………………………. Director of Instructions: Dr. R.L. Rajput ……………………… ACKNOWLEDGEMENT I take it to be my proud privilege to avail this opportunity to express my sincere and deep sense of gratitude chairman of my advisory committee Dr. V. K. Khaddar, Asso. Professor (Soil Science and Agricultural Chemistry) for his stimulating guidance, constructive suggestions, keen and sustained interest and incessant encouragement bestowed during the entire period of investigation, as well as critically going through the manuscript. I am gratified to record sincere thanks to the members of the advisory committee; Dr. U. R. Khandkar, Principal Scientist and Head of the Section, (Department of Soil Science and Agricultural Chemistry), Dr. K. S. Kumar, Professor, (Department of Agricultural Statistics), for their generous gestures and valuable suggestions in planning and execution of this study. I am privileged to express sincere and deep sense of gratitude to Dr. A. M. Rajput, Dean, College of Agriculture, Indore for his due attention and encouragement during the study period and also for providing me the necessary facilities during the course of study. It is pertinent to record sincere gratitude to Dr. K. S. Bangar, Dr. S. K. Sharma, Dr. S. P. K. Unni, Professor, (Department of Soil Science and Agricultural Chemistry), for their valuable suggestions and commendable help rendered during the course of investigation. I feel delighted to acknowledge my friend and fellow Pawan Solanki, Nisha Swami, Sushma Parmar, Pankaj Patidar, Kapil Jat, Mukesh Jhaniya, Narayan Patel, Devilal Chouhan, Gyanprakash Pandey, Hukum Singh Rawat, Harish Patidar, Dharmendra Yadav, Govind Shingh Pethari, Shivnath Kudare, Deepak Solanki, Siddharth Lashkari, Yashwardhan Patel, Rahul Dhaketa, Ankush Gupta, Shivpal Piperdey, Ravindra Yadav, Shahid Kurreshi and Vikram Nigole, all my friends for their everlasting help and encouragement during the Course of investigation. I say heartly thanks to my seniors Sanjay Dubey sir, Rajesh Jain sir, H. R. Jatav sir, Sandeep Pandagare sir, Jitendra Hanotiya sir, R. L. Sisodiya sir for their everlasting help and encouragement during the course of investigation. I feel short of words to express my gratitude to my parents Shri Sitaram Jatav and Smt. Shanti Bai Jatav, my elder brother Ramhari Narve and my younger sister Ku. Manisha Jatav and my Grandmother Smt. Tulsi Bai Jatav for their utmost Co-operation, love and encouragement during the course of this work. Place - Indore Date - (Rambalwan Jatav) CONTENTS Number Title Page I INTRODUCTION 1-3 II REVIEW OF LITERATURE 4-28 III MATERIAL AND METHODS 29-34 IV RESULTS /EXPERIMENTAL FINDINGS 35-79 V DISCUSSION 80-89 SUMMARY, CONCLUSION AND VI 90-93 SUGGESTIONS FOR FURTHER WORK BIBLIOGRAPHY I-XIII APPENDIX i-xiii VITA List of Table Table Title Page no. No. 3.1 Details of water samples of different location in Mandsaur District. 31 3.2 Classification of irrigation water quality as per Minhas et al. (1998) of 33 CSSRI, Karnal, (Haryana). 3.3 Classes of groundwater quality as per Richards (1954) 34 4.1 Number of ground water samples collected from different Tehsil of 35 Mandsaur District. 4.2 Distribution of ground water samples according to wells/Tubwells 36 depth of Mandsaur District. 4.3 Chemical Composition of Ground water samples of Mandsaur Tehsil. 37 4.4 Range, mean and SD value of ground water samples of Mandsaur 40 Tehsil 4.5 Chemical Composition of Ground water samples of Malhargarh Tehsil. 41 4.6 Range, mean and SD value of ground water samples of Malhargarh 42 Tehsil 4.7 Chemical Composition of Ground water samples of Sitamau Tehsil. 44 4.8 Range, mean and SD value of different parameters of irrigation water 45 samples of Sitamau Tehsil 4.9 Chemical Composition of Ground water samples of Suwasra Tehsil. 46 4.10 Range, mean and SD value of different parameters of irrigation water 48 samples of Suwasra Tehsil 4.11 Chemical Composition of Ground water samples of Garoth Tehsil. 49 4. 12 Range, mean and SD value of different parameters of irrigation water 52 samples of Garoth Tehsil 4.13 Chemical Composition of Ground water samples of Bhanpura Tehsil. 54 4R.a1n4 Range, mean and SD value of different parameters of irrigation water 5 5 samples of Bhanpura Tehsil 4.15 Range, mean and SD value of water samples of Mandsaur District 56 4.16 Frequency distribution of water samples into different categories of 57 water quality in Mandsaur District 4 . 1 7 Classification of ground water samples of Mandsaur Tehsil according 58 to Richards (1954) 4.18 Distribution of ground water samples according to EC (dSm-1) and 60 SAR (mmolL-1)1/2 of Mandsaur Tehsil 4.19 Classification of ground water samples of Malhargarh Tehsil 60 according to Richards (1954) 4.20 Distribution of ground water samples according to EC (dSm-1) and 61 SAR (mmolL-1)1/2 of Malhargarh Tehsil 4.21 Classification of ground water samples of Sitamau Tehsil according to 62 Richards (1954) 4.22 Distribution of ground water samples according to EC (dSm-1) and 63 SAR (mmolL-1)1/2 of Sitamau Tehsil 4.23 Classification of water samples of Suwasra Tehsil according to 63 Richards (1954) 4.24 Distribution of ground water samples according to EC (dSm-1) and 64 SAR (mmolL-1)1/2 of Suwasra Tehsil 4.25 Classification of ground water samples of Garoth Tehsil according to 65 Richards (1954) 4.26 Distribution of ground water samples according to EC (dSm-1) and 67 SAR (mmolL-1)1/2 of Garoth Tehsil 4.27 Classification of ground water samples of Bhanpura Tehsil according 67 to Richards (1954) 4.28 Distribution of ground water samples according to EC (dSm-1) and 68 SAR (mmolL-1)1/2 of Bhanpura Tehsil 4.29 Distribution of ground water samples according to EC (dSm-1) and 69 SAR (mmolL-1)1/2 of Mandsaur District. 4.30 Distribution of ground water samples according to pH 70 4.31 Distribution of ground water samples according to EC 71 4.32 Distribution of ground water samples according to Sodium 72 concentration 4.33 Distribution of ground water samples according to Sodium 73 Adsorption Ratio (SAR) 4.34 Distribution of ground water samples according to Residual Sodium 74 Carbonate (RSC) 4.35 Distribution of ground water samples according to Chloride 75 4 .36 Distribution of Nitrate in ground water samples according to water quali7ty6 quality guidelines 4.37 Distribution of Boron in ground water samples according to water 77 quality guidelines 4.38 Distribution of Fluoride in ground water samples according to water 78 quality guidelines 4.39 Correlation Coefficient (r) among different parameters of irrigation 80 water samples List of Figure Figure Title After no. Page No. 3.1 Location of Mandsaur District in M.P. 29 3.2 Irrigation water Classes (Richards, 1954) 34 4.1 Distribution of ground water samples according to pH 68 4.2 Distribution of ground water samples according to EC 69 4.3 Distribution of ground water samples according to Sodium 70 concentration 4.4 Distribution of ground water samples according to SAR 71 4.5 Distribution of ground water samples according to RSC 72 4.6 Distribution of Nitrate in ground water samples 74 4.7 Distribution of Boron in ground water samples 75 4.8 Distribution of Fluoride in ground water samples 76 5.1 Samples of irrigation water under different Tehsil of Mandsaur 80 District. ABBREVIATION S. NO. Legends Description 1 Ca2+ Calcium 2 CO2- Carbonate 3 3 HCO- Bi-carbonate 3 4 dSm-1 Desi Siemen per meter 5 EC Electrical conductivity 6 ESP Exchangeable sodium percentage 7 et al. Alied (and other) 8 i.e.(viz) That is (in reference to) 9 K+ Potassium 10 Kg Kilogram 11 L Liter 12 I Liter 13 Cl- Chloride 14 Me Milli equivalent 15 Mmol Milli mol 16 Max. Maximum 17 Mg2+ Megnesium 18 min. Minimum 19 Mm Millimeter 20 Na+ Sodium 21 Ppm Patrs per million 22 RSC Residual sodium carbonate 23 SAR Sodium Adsorption Ratio 24 SD Standard deviation 25 SO— Sulphate 4 26 % Percent 27 ** Significant at 0.05% 28 TW Tube well 29 W Well 30 F- Fluoride 31 B Boron 32 NO- Nitrate 3
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