Ceramics science and technology. / Volume 2, Properties

891 Pages·2010·17.276 MB·English

by  Riedel, Ralf, Chen, I-Wei

Edited by
Ralf Riedel and I-Wei Chen
Ceramics Science and Technology
Volume 2: Properties
This page intentionally left blank
Edited by
Ralf Riedel and I-Wei Chen
Ceramics Science and
Technology
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Edited by
Ralf Riedel and I-Wei Chen
Ceramics Science and Technology
Volume 2: Properties
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V
Contents
Preface XXI
List of Contributors XXIII
I CeramicMaterialClasses 1
1 CeramicOxides 3
Dus4anGalusekandKatarínaGhillányová
1.1 Introduction 3
1.2 AluminumOxide 4
1.2.1 CrystalStructure 4
1.2.2 NaturalSourcesandPreparationofPowders 5
1.2.2.1 High-Temperature/Flame/LaserSynthesis 6
1.2.2.2 ChemicalMethods 6
1.2.2.3 MechanicallyAssistedSynthesis 6
1.2.3 Solid-StateSinteredAlumina 7
1.2.3.1 SubmicrometerandTransparentAlumina 7
1.2.4 Liquid-PhaseSintered(LPS)Aluminas 8
1.2.5 PropertiesofPolycrystallineAlumina 11
1.3 MagnesiumOxide 13
1.3.1 CrystalStructureandPropertiesofSingle-CrystalMgO 14
1.3.2 NaturalSourcesandProduction 14
1.3.3 PolycrystallineMagnesia 15
1.4 ZincOxide 15
1.4.1 CrystalStructureandPropertiesofSingle-CrystalZnO 16
1.4.2 NaturalSourcesandProduction 16
1.4.3 Properties 16
1.4.4 Applications 17
1.4.4.1 ZnO-BasedVaristors 17
1.4.4.2 OtherApplicationsofZnOCeramics 19
1.5 TitaniumDioxide 20
1.5.1 CrystalStructureandPropertiesofSingle-CrystalTiO 20
2
CeramicsScienceandTechnologyVolume2:Properties.EditedbyRalfRiedelandI-WeiChen
Copyright(cid:2)2010WILEY-VCHVerlagGmbH&Co.KGaA,Weinheim
ISBN:978-3-527-31156-9
VI Contents
1.5.2 NaturalSourcesandProduction 22
1.5.2.1 SynthesisofAnatase 22
1.5.2.2 SynthesisofRutile 23
1.5.2.3 SynthesisofBrookite 23
1.5.3 PropertiesofTiO Polymorphs 24
2
1.5.4 PolycrystallineTitania 24
1.5.5 ApplicationsofTiO 25
2
1.6 ZirconiumOxide 27
1.6.1 CrystalStructureandPropertiesofSingleCrystals 28
1.6.2 NaturalSourcesandProduction 29
1.6.2.1 PhaseTransformationofZirconia 31
1.6.3 PartiallyStabilizedZirconia 32
1.6.3.1 Mg-PSZ 32
1.6.3.2 Ca-PSZ 34
1.6.3.3 Y-PSZ 34
1.6.3.4 CeriaandOtherRareEarth-StabilizedZirconias 34
1.6.4 TetragonalZirconiaPolycrystals(TZP) 35
1.6.5 Zirconia-ToughenedAlumina(ZTA) 37
1.6.6 ApplicationsofZirconia 38
1.6.6.1 ThermalBarrierCoatings 38
1.6.6.2 SolidElectrolytes 39
1.6.6.3 FuelCells 41
1.6.6.4 Bioceramics 42
1.7 CeriumOxide 43
1.7.1 CrystalStructureandPropertiesofSingle-CrystalCeO 43
2
1.7.2 NaturalSourcesandProduction 44
1.7.3 Properties 45
1.7.4 Applications 46
1.7.4.1 Abrasives 46
1.7.4.2 SolidElectrolytes 46
1.7.4.3 Catalysts 47
1.8 YttriumOxide 48
1.8.1 CrystalStructureandPropertiesofSingleCrystalYttriumOxide 48
1.8.2 NaturalSourcesandPreparation 48
1.8.3 Properties 49
1.8.4 Applications 50
References 51
2 Nitrides 59
PavolS4ajgalík,ZoltánLenc4és4,andMiroslavHnatko
2.1 SiliconNitride 59
2.1.1 Introduction 59
2.1.2 AmorphousSiliconNitride 60
2.1.3 SiliconNitrideSingleCrystals:Structure 60
2.1.3.1 a-andb-Si N 60
3 4
Contents VII
2.1.3.2 g-Si N 61
3 4
2.1.4 SiliconNitrideSingleCrystals:MechanicalProperties 63
2.1.4.1 a-Si N 63
3 4
2.1.4.2 b-Si N 63
3 4
2.1.4.3 g-Si N 64
3 4
2.1.5 SiliconNitride-BasedMaterials 64
2.1.6 OxynitrideGlasses 65
2.1.6.1 PropertiesofOxynitrideGlasses 66
2.1.7 PolycrystallineSi N 66
3 4
2.1.8 Lu-DopedSi N Ceramics 67
3 4
2.1.9 SiAlONCeramics 68
2.1.9.1 a-andb-SiAlONs 68
2.1.9.2 Si N OandO0-SiAlON 70
2 2
2.2 BoronNitride 71
2.2.1 CrystallographicStructures 71
2.2.1.1 HexagonalBoronNitride 71
2.2.1.2 CubicBoronNitride 72
2.2.1.3 WurtziticBoronNitride 72
2.2.2 SynthesisofBN 72
2.2.3 PropertiesofBN 73
2.2.3.1 h-BN 73
2.2.3.2 c-BNandw-BN 73
2.3 AluminumNitride 74
2.3.1 Structure 74
2.3.2 Synthesis 74
2.3.3 Properties 75
2.4 TitaniumNitride 75
2.4.1 Structure 75
2.4.2 Synthesis 75
2.4.3 Properties 76
2.5 TantalumNitride 77
2.6 ChromiumNitride 77
2.7 TernaryNitrides 78
2.7.1 TernarySiliconNitrides 78
2.7.1.1 MgSiN 78
2
2.7.1.2 OtherAlkalineEarthSiliconNitrides 79
2.7.1.3 LaSi N 79
3 5
2.7.1.4 LiSi N 80
2 3
2.8 Light-EmittingNitrideandOxynitridePhosphors 80
References 81
3 GalliumNitrideandOxonitrides 91
IsabelKinskiandPaulF.McMillan
3.1 Introduction 91
3.2 GalliumNitrides 94