Satoru Kaneko · Paolo Mele Tamio Endo · Tetsuo Tsuchiya Katsuhisa Tanaka · Masahiro Yoshimura David Hui Editors Carbon-related Materials — in Recognition of Nobel Lectures by Prof. Akira Suzuki in ICCE Carbon-related Materials— in Recognition of Nobel Lectures by Prof. Akira Suzuki in ICCE Satoru Kaneko • Paolo Mele • Tamio Endo Tetsuo Tsuchiya • Katsuhisa Tanaka Masahiro Yoshimura • David Hui Editors Carbon-related Materials— in Recognition of Nobel Lectures by Prof. Akira Suzuki in ICCE Editors Satoru Kaneko Paolo Mele Kanagawa Institute of Industrial Science Muroran Institute of Technology and Technology, KISTEC Muroran, Japan Ebina, Kanagawa, Japan Tetsuo Tsuchiya Tamio Endo Advanced Coating Technology Research Sagamihara Surface Treatment Laboratory Center Sagamihara, Japan National Institute of Advanced Industrial Science and Technology (AIST) Katsuhisa Tanaka Tsukuba, Ibaraki, Japan Department of Material Chemistry Kyoto University Masahiro Yoshimura Kyoto, Kyoto, Japan Promotion Centre for Global Materials Research (PCGMR) David Hui Department of Material Science and Department of Mechanical Engineering Engineering National Cheng Kung University of New Orleans University New Orleans, LA, USA Tainan, Taiwan Professor Emeritus Tokyo Institute of Technology Tokyo, Japan ISBN 978-3-319-61650-6 ISBN 978-3-319-61651-3 (eBook) DOI 10.1007/978-3-319-61651-3 Library of Congress Control Number: 2017949484 © Springer International Publishing AG 2017 This work is subject to copyright. All rights are reserved by the Publisher, whether the whole or part of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilms or in any other physical way, and transmission or information storage and retrieval, electronic adaptation, computer software, or by similar or dissimilar methodology now known or hereafter developed. The use of general descriptive names, registered names, trademarks, service marks, etc. in this publication does not imply, even in the absence of a specific statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. The publisher, the authors and the editors are safe to assume that the advice and information in this book are believed to be true and accurate at the date of publication. Neither the publisher nor the authors or the editors give a warranty, express or implied, with respect to the material contained herein or for any errors or omissions that may have been made. The publisher remains neutral with regard to jurisdictional claims in published maps and institutional affiliations. Printed on acid-free paper This Springer imprint is published by Springer Nature The registered company is Springer International Publishing AG The registered company address is: Gewerbestrasse 11, 6330 Cham, Switzerland Preface I am not a specialist in studies on carbon-related materials. I attended the International Conference on Composites/Nano Engineering (ICCE), 23 July 2015, in Chengdu, China, on the invitation of Professor David Hui, University of New Orleans. I delivered a Nobel Lecture on “Cross-Coupling Reactions of Organoboranes: An Easy Way for Carbon-Carbon Bonding.” There I made many friends, including Professor Tamio Endo, Sagamihara Surface Lab, and he asked me to write the preface for this book. In 1963 I joined the research group of Professor Herbert C. Brown, who received the Nobel Prize in Chemistry 1997, at Purdue University, Indiana, US, as a postdoc- toral associate, fascinated by the interesting new reaction of hydroboration. After a 2-year stay at Purdue, I returned to Hokkaido University, where I began studying organic synthesis using organoboron compounds. We recognized the potential of organoboranes as intermediates in organic synthesis. Our discoveries of halobora- tion and cross-coupling reactions are fundamental contributions to the organic chemistry of boron and synthetic methodology. The cross-coupling reaction is widely used for the stereodefined construction of carbon–carbon bonding in multifunctional systems. I have retired from the univer- sity, but I am very happy to have a chance to meet many young researchers at inter- national meetings to discuss this chemistry. I hope this book is useful for such young chemists. Hokkaido University Akira Suzuki Sapporo, Japan v Introduction This book is published in recognition of Nobel Lectures delivered by Akira Suzuki (Emeritus Professor of Hokkaido University, Nobel Prize in Chemistry 2010) and the Special Symposia on Carbon-Related Materials in ICCE-23 (2015) and 24 (2016). The International Conference on Composites/Nano Engineering (ICCE) <http:// www.icce-nano.org/> was established by David Hui (University of New Orleans) in 1994 in New Orleans (USA). Subsequently, this Conference has been held every year, initially in the US but latterly all over the world. A few tens of participants attended at the beginning, but recently their numbers have increased to 400-600. In this way, ICCE has been greatly developed and extended throughout the world because of the great efforts of David Hui and major committees. This year (2017) we celebrated the silver jubilee of ICCE, ICCE-25 (2017), in Rome. The Special Symposium “Oxide Nanocomposites and Heterostructures” was founded in New Orleans for ICCE-10 (2003) by Tamio Endo (Mie University, Japan), Kazuhiro Endo (AIST, Japan), and Team Harmonized Oxides (THO) <http://www.nims.go.jp/nqe/sa/tho/>. THO is a Japanese non-profit association, set up by T. Endo and K. Endo to organize various international activities. We had only one THO Special Symposium in ICCE-10, but the numbers increased to around 20 in the subsequent 14 years. In the last 4 years THO have organized a few Special Symposia in ICCE such as “Materials Chemistry” and “Materials for Sustainable Energy.” This is also a feature of the progress of ICCE. In this development of ICCE, we (THO) invited Prof. Akira Suzuki to ICCE- 23 (2015) in Chengdu (China) to deliver the Nobel Lecture in Organic Chemistry on “Cross-Coupling Reactions of Organoboranes: An Easy Way for Carbon- Carbon Bonding.” The lecture was very interesting and instructive, inspiring all the participants. Most of them working in the field of inorganic materials were inspired to make use of C–C bonding approaches in their work on inorganic mate- rials. This strong impact induced us to invite him again in ICCE-24 (2016) in Haikou (China), and he kindly accepted our invitation. He presented the second Nobel Lecture in the same field, and we again spent very valuable time together. These two Nobel Lectures by Prof. Suzuki drove THO to arrange the “Suzuki Special Symposium on Carbon-Related Materials” in ICCE-23 (2015) and vii viii Introduction ICCE-24 (2016). Many outstanding presentations were given during these two Special Symposia. The symposium organizers (T. Endo, S. Kaneko, P. Mele, K. Tanaka, T. Tsuchiya, M. Yoshimura, and K. Yasui) were pleased by the disclo- sure of such excellent papers to such a wide scientific community. This is why we invited our distinguished colleagues to share their results, and why we publish this book entitled “Carbon-Related Materials in Recognition of Nobel Lectures by Prof. Akira Suzuki in ICCE.” Commemorative photographs taken during ICCE-23(2015) in Chengdu, China and ICCE-25 (2016) in Haikou (China) are shown here. Figure 1 shows Prof. Akira Suzuki giving his Nobel Lecture. Figure 2 shows THO organizers, some of the edi- tors of this book, and Prof. Suzuki after his Nobel Lecture. Figure 3 shows a dinner scene during the Conference, with THO organizers, editors of this book, and Ms. Shun Ying Hui (wife of Prof. David Hui, a Manager of ICCE). At every ICCE Conference we have had very enjoyable mealtimes with representative guests. Figure 4 shows a typical scene at the Conference banquet. On every occasion the singing of the traditional Japanese song “Sakura Sakura” took place, led by Japanese delegates but warmly including foreign delegates. We consider these events of singalongs, dinners, and banquets with the participants of ICCE as very important in the acquisition of international friendship and world peace. This is another purpose and policy of the THO team and ICCE Conferences. We are planning to publish books relating to the best Special Symposia held in ICCE and aspire to the further development of ICCE. May 1st, 2017 Tamio Endo (Sagamihara Surface Lab., Japan/ICCE Co-Technical Chair) Satoru Kaneko (Kanagawa Inst. Indus. Sci. Tech. Japan/ICCE Editorial Board) Paolo Mele (Muroran Inst. Tech., Japan/ICCE Co-Technical Chair) David Hui (University of New Orleans, USA/ICCE Chair) Introduction ix Fig. 1 Prof. Akira Suzuki giving his Nobel Lecture at ICCE-24 (2016) in Haikou, Hainan Island, China Fig. 2 Team Harmonized Oxides (THO) organizers, some of the editors of this book, and Prof. Suzuki after his Nobel Lecture at ICCE-23 (2015, Chengdu, China) x Introduction Fig. 3 Dinner scene during ICCE-23 (2015, Chengdu, China), with THO organizers, editors of this book, and Ms. Shun Ying Hui (wife of Prof. David Hui, a Manager of ICCE) Fig. 4 Singalong during the Conference banquet of ICCE-24, Haikou (2016, China) Contents Part I Graphene and Nanocarbon Materials The Synthesis and the Catalytic Properties of Graphene-Based Composite Materials ...................................................................................... 3 Baojiang Jiang and Chaoyang Li Optical Characterization of Graphene and Its Derivatives: An Experimentalist’s Perspective ................................................................. 27 Dinh-Tuan Nguyen, Ya-Ping Hsieh, and Mario Hofmann Submerged Liquid Plasma for the Formation of Nanostructured Carbon ............................................................................ 61 Masahiro Yoshimura and Jaganathan Senthilnathan Lab-on-a-Graphene: Functionalized Graphene Transistors and Their Application for Biosensing ........................................................... 79 Takao Ono, Yasushi Kanai, Yasuhide Ohno, Kenzo Maehashi, Koichi Inoue, and Kazuhiko Matsumoto Production of Single- and Few-Layer Graphene from Graphite .............. 91 Shinya Yamanaka, Mai Takase, and Yoshikazu Kuga Graphene-Based Coatings for Dental Implant Surface Modification ....... 103 Alina Pruna, Daniele Pullini, and Andrada Soanca Part II Carbon Composites and Thin Films Effect of CNT on the Mechanical Properties of Composite Materials and Structures ....................................................... 119 N. Naveh, Y. Seri, Y. Portnoy, D. Levin, and B. Muravin Energy Absorption Capability of Hybrid Fibers Reinforced Composite Tubes ............................................................................................ 145 Yuqiu Yang, Yan Ma, Jing Xu, and Hiroyuki Hamada xi
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