Atomic Data for Fusion [light atoms] Vol 1 (data tables, charts)

707 Pages·1990·24.967 MB·English

O ,. 0RNL--6 086/VI
DE91 000527
Physics Division
ATOMIC DATA FOR FUSION
VOLUME 1
COLLISIONS OF H, H2,He and Li ATOMS and IONS
' with
ATOMS and MOLECULES
C. F. Barnett
Oak Ridge National Laboratory
Published and Ed,]ted by
Controlled Fusion Atomic Data Center
O H.T. Hunter and M. I. Kirkpatrick
Series Technical Editors
I. Alvarez, C. Cisneros, University of Mexico, ,
and R. A. Phaneuf
Contributing Editors
Date Published- July 1990
Prepared for the
Office of Fusion Energy
U.S. Department of Energy
Washington, DC 20545
Budget Activity No. AT 05 30 04 0
Prepared by the
OAK RIDGE NATIONAL LABORATORY
Oak Ridge, Tennessee 37831-6372
operated by
'MARTIN MARIETTA ENERGY SYSTEMS, INC.
for the
U. S. DEPARTMENT OF ENERGY
under contract DE-AC05-84OR21400 _ _ '_i ......r.
Printed in the United States of America. Available from
National Technical Information Service
U.S. Department of Commerce
5285 Port Royal Road, Springfield, Virginia 22161
NTIS pr=ce codes--Printed Copy: A-99Microfiche A0]
This reportwas preparedasanaccountofworksponsored byanagencyofthe
UnitedStatesGovernment.NeithertheUnitedStatesGovernmentnoranyagency
thereof, noranyof theiremployees,makesanywarranty,expressorimplied,or qlF
assumesany legalliabilityorresponsibilityforthe accuracy,completeness,or
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I
iii
ATOMIC DATA FOR FUSION
VOL. 1
COLLISIONS OF H, li2, }le, AND bi ATOMS AND
IONS WITH ATOMS AND MOLECULES
Foreword ........................... xiil
Series Preface ........................ xv
Abstract ............................ xvli
Introduction .......................... I-i
A. Electron Capture Collisions
H + H -> H- + H+ ........................ A-2
H + H2 -> H"_ + H2. ....................... A-8
• . A-10
H + He -> H- + He+ • .....................
H + Li -> H- + Li+ ....................... A-16
H + H- -> H- + H ........................ A-20
H. + H -> H + H. ........................ A-22
H. + H2 -> H .......................... A-28
H* + H2 -> H- . ......................... A-30
H_ + He -> H + He. ....................... A-32
H. + He -> H- + He2+ ....................... A-38
H. + Li -> H + Li. .............. ......... A-40
A-44
@ H. + H- -> H- + H. .....................
H_ + H- -> 2H ........................... A-46
H* + He + -> o(He 2. Total) ................. A-48
H. + }le. -> H + He2_ ..................... A-54
H2+ + H -> H2 + H+ ....................... A-58
H2+ + H2 _> H2 . . . ...................... A-58
I]2+ + He -.> H2 4 He+ ......... .............. • A-58
H2.(u) + H2 _> H2 .... ..................... A-60
He. + H -> He + H+ ....................... A-62
He+ + H--> He + H ....................... A-86
He. + H2 -> He .......................... A-68
He. + He -> He + He+ ...................... A-70
He. + Li -> He 4 Li. . . . : .................. A-76
He. + He* -> He + He2* ..................... A-86
He2. + He+ -> He* + He2+(Partial & Total) ............ A-84
He2. + H- -> He. + H ..................... A-86
He2. + H -> He+ + H. ............... ....... A-88
He2+ 4 H2 -> He. . . . .................. A-94
He2* + H2 -> He ......................... A-96
He2. + He -> He. 4 He + ...................... A-98
He2+ + He -> He + He2+ . .................... A-J04
He2. + Li -> He+ + Li_ ..................... A-I10
He2_ + Li -> }le + Li2. ..................... A-I14
l
iv
q
B. Electron Capture into Excited States Q
H_ + H -> H(2s) + H+ ............... ........ B-2
H* + H -> H(2p) + H' • ................. B-8
H+ + H2 -> H 2_) .................... B-14
H. + H2 -> H 2p) ..................... B-14
H. + H2 -> H Lyman-a Total) .............. B-16
H. + H2 -> H Balmer-_) ................. B-18
H+ + H2 -> H Balmer-B) ................ B-18
H. + H2 -> H 3s) ..................... B-20
H* + H2 -> H 3p) ...................... B-20
H. + H2 -> H 3d) . • ................... B-20
H+ + He -> H 2s) + He* ................... B-22
H* + He-> H 2p) + He' B-28
H. + He -> H Balmer-_) + He + B-34
H. + He -> H 3s) 4 He* .................... B-40
H. + He -> H(3p) + He" • ................. B-46
H* + He -> H(3d) + He+ .................. B-52
H+ + [ai -> H(2s) + bi+ • ................. B-58
H+ + bi -> H(2p) + Li* • ................. B-58
H+ + Li -> H(3s) + Li* .................. B-60
H+ 4 Li -> H(3p) + Li_ .................. B-60
H. + Li -> H(3d) + Li+ .................. B-60
He+ + H2 -> H(21S + 23S) .................. B-62
He. + H2-> He(21P) ...................... B-64
He+ + H2 -> He(31p) ...................... B-64
He+ 4 H2 -> He[x = 44"7.1 nra) ................ B-66
He+ + H2 -> He(x = 587.6 nra) ............... B-66
He+ + H2 -> He(x = 667.8 nra) ................ B-66
He* 4 He -> He(21S 4 23S) + He+ .............. B-68
He+ _ He -> He(21p) + He+ ................. B-74
He+ + He -> He(31S) + He* • ................ B-80
He+ + He -> He(31p) + He" • ................. B-80
He+ + He -> He(31D) + He+ ................. B-80
He_ + h3 -> He(33S) + He* • ................. B-82
He* + He -> He(33p) + He+ .................. B-82
He+ + He -> He(33D) + He* • .................. B-82
He. + He -> He(41S) + He+ .................... B-84
He* + He -> He(41P) + He_ • .................. B-84
He+ + He -> He(41D) + He4 ................... B-84
He+ + He -> He(43S) + He+ • .................. B-86
He+ + He -> He(43p) + He' • ............... B-86
He+ + He -> He(43D) + He" • • ................. B-86
He+ + Li -> He(53.7 nm) + Li+ ................ B-88
He+ + Li -> He(58.4 l_n) + Li+ .................. B-88
He2+ + H -> He_(2s) + H* .................. B-90
He2. + H -> He+(2p) + H* • ................ B-96
He2+ + H .-> He_(Ly1_lan-a) + H+ • ................ B-lO2
He2+ + H-> He.(Lyman-B) + H_ • ................ B-lO2
He2+ + H -> He+(L_allan-_') + H+ ................. B-J02
He2. + H-> He.(Balmer-a) + H_ ................ B-J02
He2. + H -> He+(3p) + H.
He2_ + H -> He+(3s+3d) + H*................................... BB--110044
He2+ + H -> He.(4p) + H. ................ _ . . B-104
He2+ + H2 -> He+(2s) ....... .............. B-J06
He2+ + H2 -> He.(2p) ..................... B-lO6
He2* + H2-> He.(LY man-=) ...... '. ............ B-lO8
He2+ + H2-> He+(b_.an-B) ................... B-lO8
I
V
O B. Electron Capture into Excited States (Cont'd]
He2. + H2 -> He+(Ly111an-Y) .......... . ........... B-IO8
He2+ + H2 -> He+(Balnler-a) . . . B--108
He2. + H2 -> He+(3p) ................... . . B-IlO
He2+ + H2 -> He_(3s+3d) . . . . ........... B-IlO
He2. + H2 -> He+(4p) ....................... B-IlO
He2+ + He -> He+(2s) + He+ ................ , B-112
He2+ + i,i -> He+(2p) + [si+ . ................. B-.II8
He2+ + [,i-> He+(3p) + bi+ ...... .... . . . ....... B-I18
He2. + Li -> He+(4p) + Li! . . .......... . . . . B-118
He2+ + bi -> He+(3s+3d) + Li+ . . ., .............. B-II8
He2. + bi -> He+(4S+4d) + Li_ .................. B-II8
He2+ + Li -> He+(Ly_llan-a) + 5i+ ............. . . . . B'I20
He2. + Li -> He+(b]nllan-B) + Li. ........... ..... B-120
He2. + Li -> He+(by]llan-7) + Li_ ................. B-120
He2+ + Li -> He+(Salnler-_) + bi+ . ...... ........... B-122
Hez+ + Li -> He+(Ba].mer-_]) _• Li. . ............. . . . B-122
He2+ + 5i -> He+(Ballner-1) + Li+ . .... ............ B-122
He2. + Li -> He+(Ba]nler-o) + Li+ . . . ........ . . B-122
C. E×citatiol ! and Spectral bine Emission
H + H-> H(2s) .... ...................... eZ2
-> H(2p) ......................... C-2
-> H(3s) .......................... C-4
-> H(3p) ............. . . ........... C-4
-> H(3d) ....................... C-4
O -> H(Balnler-a) ...................... C-4
H + H2 -> H(2s) [projectile ] .................. C-6
-> H(2p) [projectile] .... .......... C-6
-> (2s) [target] . . ................. . . C-6
-> (2p) [target] ............. ......... C-6
-> (L_nan-a) .... .............. C-8
-->> HH((33sp)+3d i ......................................... ....... " ' CC--1l0O
-> H(Balmer-_) ...................... C- 12
-> H(4s) . ................... .... (i!-14
-> H(4p+4d) ...................... C-14
-> H(Balmer-8) ........................ C-14
H(2s) + H2 -> H(b_allan-a) ..... . . .... .... . . C-16
-> H(3s) ....................... C-18
-> H(Bahner-c,) .................. C-18
H(2s) + He -> H(L_allan-¢,) ........ ............ C-20
-> H(3s) . . . .................... C-22
-> H(Balnler-a) ..................... C-22
H + He -> H(h_nnan-a) ...................... C-24
-> H(2s) ..... ................... C-30
-> H(2p) ..... . ................. C-30
-> H(3s) ..................... <:-32
-> H(3p) .... ..... . .......... C-32
-> H(3d) ....... ............... C-32
-> H(3p43di .................... C-32
-> H(Balnler-a) ................... C-34
--> H(Balmei-_) ................... C-34
~> H(4s) .................. .... C-36
-> He(31P) ...................... C-38
O -> H(4p+4d) ...................... C-36
!
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C. Excitation and Spectral Lille Eluissio,l (Cont'dl. O
H + He -> He(33P) .......... . • .......... . • C-38
-> He(33D) .................. C-38
-> He(41S) ........................ C-40
-> He(41p) ...... : ................. C-40
-> He(41D) ....................... C-40
-> He(43S) ........................ C-42
-> He(43P) ..... . ........... ........ C-42
-> He (43D) .......................... C-42
i
H_ + H -> H(2B) ......... .............. .... C-44
-> Ii(2p) ......................... U-44
-> H(n=2) ........................ C-48
-> H(n=3 ) ......... .... ........ C-48
-> H(n=4) ......................... C-48
H. + H2 -> H+ + H(2B) + H ........... _ ....... C-50
-> H. + H(2p) + H ................... C-50
-> H+ + H(3p) + H .................... C-52
-> [_(Lyman- a) ..................... C-54
-> H(Balnler-_) .................... C-56
-> H(Balmer-D) .................... C-56
-> H(Balmer-x) .................... C-56J
-> H2(L]allan-Band ) .................... C-58
-> H2(U_llan-Band ) .................... C-58
H+ + He -> He(21S) ....................... C-60
-> He(21p) ..................... C-60
, . . ................ C-60
-->> HHee((2311SS) + 2.1.P.'.)........'............ C-66 O
-> He(31p) ....................... C-66
-> He(31D) ....................... C-66
-> He(41S) ..................... C-68
-> He(41P) ....................... C-68
-> He(41D) ....................... C-68
-> v.u.v. (20-140 nra) .................. C-70
He+ + H -> H(n=2) ........................ C-72
-> H(2s) ........................ C-74
-> H(2p) ....................... C-74
He+ + H2 -> H(b]allan-a) ..................... (;-78
-> H(L_allan-B) .................... C-78 I
-> H(Balmer-a) ..................... C-80
-> H(Balmer-B) . .................. C-80
-> H(2B) ..... .................. C-82
-> H(2p) ...................... C-82
-> H(3B) ..................... C-84
-> H(3p) • ...................... C-84
-> He+(2s) ...................... (]-86
He+ 4 He -> He(21S) [target] ................. C-88
-> He(21p) [ta,rget ] ............... C-88
-> He(23S) [ta,cIet] ............... C-90
-> He(23P) [target] ............ C-90
-> He(31S) target] ............. C-92
-> He(31p) target] ............ C-92
-> He(31D) target] .............. (?-92
-> Iie(33S) ta£_get ] ........... C-94
-->> HHee((33]3PD)) ttaarrggeett]] ...................... CC--9-494 O
i
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vii
c. Excitation and Spectral Line Emission (Co[_t'd)
He+ + He -> H_(41S) [target] .................. C-96
_> He[41p) itarget ] .................. C-96
-> He(_iD) [target] ................. C-96
-> He(4]S) [target] .................. C-98
-> He(43p) [target] .................. C-98
-> He(43D) [target] .................. C-98
-.> He* (n=2) [projectile] ................ C-100
-> He+ (n=3) [projectile ] ................ C-I02
He + H2 --> H(Balmer-_,) ..................... C--I04
-> H(Balmer-B) ..................... C-]04
He + He _> He(21S) ....................... C-I06
_> He(21p) ....................... C-]06
_> He(31p) ..... .................. C-I08
_> He(31D) ...................... C-!08
_> He(33p) ...................... C-I08
_> He(33D) ........................ C-i08
41S) ....................... C-110
-->> HHee((4 _P) ........... ............. C-II0
_> He(43S) ........................ C-I12
_> He(43p) ...................... C-I12
_> He(2s 2 IS) ...................... C-I14
_> He(2s2p3p) ...................... C-I14
_> He(2p 2 ID) ...................... C-I14
_> He(2s2plp) ..................... C-]14
_> He-(is2s 2 2S) .................... C-I14
He2_ + H -> H(2s) ....................... C-i16
-_ H(2p) ........................ C-I16
He(23S) + He(llS) -> He(31p) + He ............... C-I18
-> He(33p) + He ................ C-120
-> He(43S) + He .............. C-122
-> He(43D) + He ................ C-122
-> He 4 He(43S) ................ C-124
-> He + He(43D) ................ C-]24
H+ + 51(2s) -> Li(2p) .................. _ • C-126
-> 5i(670,8 nra) .................. C-126
He+ + Li(2s) -> Li(670.8 nra) ................. C-128
He2+ _ Li(2s) -> bi(2p) ..................... C.-130
-> Li(670.8 nra) .................. C-130
D. Ionization Collisions and Charqe Production
H '- H2 -> Total Slow Positive Ion Production ......... D-2
-> Total Slow Electron Production ............ D-2
-> H + H2. + e ...................... D-4
H/ + H -> H4 + H+ + e ...................... D-6
_|_ + H- -> H2+ + e ....................... D-J2
H+ t. H2 -->> THo.tal+ H2Slo•w e Elec.t.r.o.n......P.r.o.d.u.c.t.i.o.n. .......... DD--J!46
viii
D. Ionization Collisions and Charqe Production (toni'd) O
H* + H2 -> Total Production of H2+ ............... D-16
-> Total Production of H. ................ D-16
H. + He -> Electrons and H- . .................. D-18
-> H* + He* + e ......... D-24
-> (H + He*) or (H+ + He+ + e) .............. D-24
-> H+ + He2+ + 2e . . . . . ................ D-34
-> (H- + He2+) or (H* + He2* + 2e) ............ D-34
He(21S) + H -> He + H+ + e ................... D-42
-> He}l* + e ........... D'42
-> (He + H. + e) or Hell+ + e) ......... D-42
He(23S ) + H -> He + H+ + e ................... D-_4
-> Hell. + e ..................... D-44
-> (He + H* + e) or (Hell_ + e) ........... D-44
He(23S) + H2 -> Total Ionization ................ D-46
-> Rearrangement Ionization ............ D-46
He (21S) + H2 -> Total Ionization ................ D-48
-> Rearrangement Ionization ............ D-48
H* + He_ -> (H. + He2+ + e) .................. D-50
-> (H. + He2. + e) or (H° + He2+) ............ D-50
He. + He* -> (He. + Hez. + e) ......•...w..• • • • D-58
-> (He + He2_) or (He*
+ He2_ + e) .......... D-58
He + H2 -> Total Slow Positive Ion Production ......... D-64
-> Total Slow Electron Production ............ D-64
-> He + H2. + e ..................... D-66
-> Total H+ Production .................. D-66
He + He -> Total Slow Positive Ion Production .......... D-68
-> Total Slow Electron Production ............ D-68
-> He 4 He. + e ...................... D-70
-> He + He2* 4. ?e .................... D-70
He. _ H -> He+ + H. + e ..................... D-72
He. + H2 -> Total Slow Positive Ion Production ......... D-76
-> Total Slow Electrpn P_:oduction ........... D-76
He+ + H2 --> (He + H2.) or (He. + H2+ + e) ............ D-78
-> Total H. Production ................. D-78
-> He+ + H_ 4 H. + 2e ................. D-78
He. + He -> Total Slow Positive Ion Production ......... D-80
-> Total Slow Electron Production . , ......... D-80 I
-> He* + He* + e ............... D-90
-> He+ + He2. + 2e . . . ................ D-90
He2_ + H -> He2. + H+ + e .................... D-96
He2+ + H2 -> Total Slow Positive ]on Production .......... D-]O0
-> Total Slow Electron Production ........... D-lO0
-> Total H. Production ................ D-lO2
-> H_ Production by Ionization Col]islons ....... D-102
-> Total tt2 Production ................ D-lO2
-> 1t2. Production by Single-Ionization ........ I)-.132
ix
D. Ionizatlml ColllSious aild Charqe Production {Con t'd)
He2. + He -> Total Slow Positive Ion Production ......... D-104
-> Total Slow Electron Productiol] ......... _ . . D-lO4
-> He2. + He+ + e ................... D-[I_
-> He2. + He2+ + 2e .................. D-II4
H+ + Li -> H. + Li+ i e . . . , . , . ....... . D-]22
He + + Li -> He_ + Li+ + e ................ .... D-126
He 2+ + Li -> He2. + Li_ + e ................... D-128
E. Electron Loss or Strippinq Collisions
H + H -> H. + H + e ............ ........... E-2
H(2s) + H(Is) -> H+ + H 4 e ........ ..... ..... E-4
H + H2 -> H. + H2 + e ...................... E-6
H(28) + H2 -> H+ + H2 + e ................. .... E-8
H + He -> H. + He + e .................... E_]O
H(2s) + He -> H. + He + e ...... ............. . F,-14
He + H -> He_ + H + e .................. E-16
He + H2 -> He. + H2 + e ..................... E-18
He + Hz -> He2. + Hz + 2e .................. , . B-J8
He* + H2 -> He or He+ ......... E-20
He* + H2 -> He_ + H2 + e ......... ........ . E-20
He* + H2 -> He + H2 .......... ........ E-2 o
e
O HHee •+ HHee -->> HHee+2+ ++HeHe ++ 2e ..................... EE--2222
He _ + H -> He2+ + H 4 e ...................... E-28
He . + H2 -> He2. + H2 + e ........ ............ E-30
He _ 4 He -> He_-. + He + e .................... E-32
F. Electron Detachment Collisions
H- + H -> H + II + e ..................... F-2
-> (H + H + e) or (H + H-) ............... F-2
-> H+ _ H + 2e .................. F-4
11- + H_ -> H + H_ + 2e ............ . ........ F-6
H" + H2 -> H + H2 + e ...................... F-8
-> H+ + H2 + 2e ....................... F-10
H- + He -> H + He + e ...................... F-12
-> H+ + He + 2e ................... F-14
He" + H -> He + H + e ...................... F-16
He" + |I2 -> He + II2 + e ..................... F-18
-> He_ + H2 + 2e ........ . ............ F-18
He- + He -> He + He + e ................... F-20
-> He+ + He + 2e ................... F-20
Li" + H2 -> Li + H2 + e .................... F-22
-> Li+ + '_ + 2e F-22
Li" + He -> Li + He + e .................... F-24
-> Li+ } }le 4 2e .................... F-24
0
X
,
G. Dissociative Coli] sions
H + H2 -> H-4 (H. 4 H*)+ e ................. 0-2
-> H + (H+ + H*) + 2e . • . ..... , , ...... 0-2
-> H+ -! (H_ + H+) + 3e .................... 0-2
-> H + (H + H_) 4 e . . • , ............ . . . 0-4
-> H+ + (li + H_) + 2e ............ . . . , . . . 0-6
-> lt- + (H' + H) ..... • • .............. C_-8
H* 4 li2 -> H+ + H+ + H+ _ 2e ................... , 0-].0
He+ + H2 -> He + + H . + H+ + 2e .... . . . ........... G-12
He2+ 4 H2 -> He2. + (H+ + H) + e (via iSOg) . .......... G-g4
-> He2. + (H . + H) 4 e (via 2POu) ..... ...... 6]-.16
.> He+ + (H. + HI • .................. O218
-> He+ + (H. + H ) + e . . ..... ......... 0-20
-> He2. + (H. + H.) + 2e ........ . . . . . . 0222
-> He + (H+ + H+) ' . .... ............... G-24
H2+ -_. H2 -5. H+proj. . ....................... G-26
H2+ + H -> H_proj.
....... ................... 0-28
H2. + H2 -> ||proJ. ................ ..... G-30
-> (H+ + H) + H2 ............... • .... 0-3.2
H2+ + He -> Total H+ • . • • ........ G-34
-> (H. + H) + He ........ ............ 0-36 O
H2 + H2 -> H.(Fast,Total) .......... .......... G-38
-> H(Fast,To_al ) ................. 0-40
-> Total Destruction of Fast H2 Proj . . ........ G-42
H3 + + H2 -> Total Destruction of H3+ ....... .... 0-44
H2+ + H2 -> Total Destruction of H2+ . .............. 0-46
H3 + H2 -> H.(Total,Projectile) ................. 0-48
-> H2+ (Total, Projectile ) ................ 0-50
-> H(Total, Projectile) ................. G-52
-> H2(Total,Projectile) ................ . . G-54
H3_ + He -> H.(T0 tal) ................... . . . . G-56
-> H2 • • ..................... G-5R
Hell . + H2 -> Total Hell . Disoociation Prod ............ G-60
HeH + + He -> Total HeH . Dissociation Prod. • .......... G-62
H, Particle Interchanqe Reactions
H+ + D2 -> D+ + HD ....................... H-2
-> HD. + D ....................... H-2
HD+ + D2 -> HD2. + D ...... ................ H-4
-> D3+
+ H ............. . ......... H-4 O