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ASSESSMENT OF THE QUALITY OF DRINKING WATER IN KHARTOUM STATE By Eshraga Abd ... PDF

133 Pages·2007·14.85 MB·English
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ASSESSMENT OF THE QUALITY OF DRINKING WATER IN KHARTOUM STATE By Eshraga Abd EIMagid Basllir A thesis Submitted in the Fulfillment ofthe Requirements for the degree of Master ofScience in the University of Khartoum Department of Chemistry Faculty of Education University of Khartoum Jnly, 2005 .-.,U..·.'-I..i>1 '--'...., .~'il i~ L>'(y.) <,'il 'To ~'Y: Latejatfier, qaa6(ess fiim 9v1atfier CBratfier Sisters Laveryfrienas Acknowledgements I wish to express my deepest and sincere thanks first to my god and then to my supervisor professor Mohammed Ahmed Hassan Eltayeb, for his guidance and support to finish this work and supervision. I would like to extend my sincere thanks to my co-supervisor Dr. Taj Elsir Abass Ahmed. Special thanks to Mahgoub Mohammed Taha, the technical advisor of Khartoum State Water Corporation, who made available all the facilities that needed to collection ofsamples and references. Sincere appreciation is extended to Geological Research Institute staff, who made available all the facilities needed to finish this work. My deep thanks go to the staff members of Faculty of Phannacy Omdunnan Islamic University. Thanks are also extended to the staff members of the Sudan Atomic Energy Commission with special reference to Dr. Rifat Kabbashi and Tayser Ismail for their great help, and to Department of Chemistry, Faculty ofEducation, University ofKhartoum. Special thank also to Abd EI Bagi Nasir for his great help. Finally lam grateful to my family for their understanding and encouraging during the progress ofthe work, and to my friends. ABSTRACT Assessment of drinking water quality Khartoum State was 111 the main purpose ofthis study. Seven sites were selected to represent the area of wells water, relevance to environmental pollution in Khartoum area, UI11J11badah near industrial area, Elthawra near apower station, Elfiteihap ncar the White Nile, Elriyadh near a petroleum station, Elkalakla in the last bus station, Elhag Yousif in the market, as well Eldroshap as control area. Raw and treated water samples were collected from the White Nile, the Blue Nile and the River Nile, wells water and treated water from the three Niles these samples stored in metallic and fiber glass tanks in the rainy and dry seasons. Standard methods were lIsed for samples collection and preparation for the measurements using Atomic Absorption Spectromelly (AAS) and flame photometre. Thirteen elements were observed and their concentrations determined in the various locations, those are Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Na, Ni, Pb and Zn. The concentration levels for Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb and Zn were lower than the detection limits for (AAS), and pre-concentration by physical method was found necessary for these elements, the evaporation method of the drinking water samples were used. The data obtained were compared with the data from literature. The results are generally comparable except the concentration ofFe of the raw water for the River Nile in the two seasons as well as the treated water for the River Nile, the treated water for the River Nile stored in fiber glass tank (rainy season), and the treated water for the White Nile stored in metallic tank (rainy season) are lower than the maximum permissible international levels provided by the World Health Organization (WHO) and the concentration of trace elements in drinking water permitted by the Sudanese Standards and Metrology Organization (SSMO). There is no pollution in the ground water resulting from human activities can be made. " tt .:'Yo'r,;;:....f.t.t''i.::,(~.-[.[~~~'fL¢"k.,~.~<:~-.•.~.'".,,;.•·rt~~<[l~'G'~fcb.l.[.12 [ tt~It.~;"E":-[[.(~(..-.fI:"b~ft);.-t'i...,Pi.'~L:-1;&0'•~:~'..[·,f~tL~l""-l.r':-l~_.,~~ F...{[, •~.~["~ t'F~t·.I=.E.,-[~f.'-(;'l-~ t tit:!;; [ L£<'•'f~-~.'-(;.L\tC-'J;;,Ii~i~ 'f,~,l$"I.-[ .:... '':~.i...I;;r.1'i..f.•L·C,~_'-,~;~f'Ii\~.t''-.f[ :~:f f... .r~.~ .. ,-'[..[_1,to;If(;,~~~:t \' [.{. f~I."r~ . ~ ' ~~"'~t.'-'1:,'E't!:..f:"'-..~~,~.~I;;", ~'r.'-[.~.c=t..'-_.l;;'- 'r~1~.B~~1.~~ r.<:[.Ie-. L~~ t .~~ "x·...·r'- '-:·~t.:~ If.~.~ t ;- '-.l ~ ~'- [-'-~ '-.~¥.l;;'-~It.~.~ ".~t~, r~ . ~ ~ ~--0 ~;fA!'"-".t~ lr.'[~, L.:.~fL...:""~ t t f ( 'f-"IE'- L'f[.E..t c'...<:'-LL.·[[ tt:.r'~,to ~.o''i..l.l-~",-~. I>'1~ b"~~.'-.ft.~. t.~.[[.f? Y .L . ~;. 'i..t:.l"c·'- '-[C1-'-[C1-[-t.1[.c-C.'tL ;;•·f·f'-'-.[•.~L1;;.:rr~'i.:f[:'iLC1'E.ct'i tf,~,,-l1,·~'-,"'. 'l.[_I>itn-l'1~."~~.I[:2"-L~(;,t'r[_Fl$.~rr~,~.t.'r1:rr[~.~'i.t'~r '"-tb- t·'~,.t:'r.'6't<:....[.~ ".,~ t.S, L;.f;:~..~ CONTENTS Page Acknowledgements . Abstract............................................................................................... 11 w..,]J ._, I. .~ ························ 111 Contents.............................................................................................. IV List ofTables...... .. .. . IX Lisl ofFigures............................................. Xl Chapter (I): Introdnction 1.1 Importance ofwater. .. 1.2 Water sources . ... -. 2 '" 1.2.1 Rain waler. :........... 2 1.2.2 Ground water................................................... 3 1.2.2.1 The wells........ 5 1.2.3 Surface water................................................... 8 IV 1.2.3.1 The rivers .. 9 1.3 Water storage . 9 1.3.1 Household water storage .. 10 1.4 Water treatment. . 11 1.4.1 Coagulation and nocculation .. II 1.4.2 Sedimentation or notation .. 12 1.4.3 Filtration .. 13 1.4.3.1 Slow sand filtration . 14 1.4.3.2 Rapid sand filtration .. 15 1.4.4 Disinfection .. 16 1.5 Water quality........ 17 1.5.1 Drinking water quality standards........................... 19 1.6 Trace elements....................................................... 22 v 1.6.1 Introduction . 22 1.6.2 Trace elemenls in the water . 23 1.7 Nutrient elements in the water. . 24 1.7.1 Calcium (Ca) . 24 1.7.2 Cobalt (Co) . 25 1.7.3 Copper (Cu) . 25 1.7.4 Iron (Fe) .. 26 1.7.5 Magnesium (Mg) .. 27 1.7.6 Manganese (Mn) . 28 1.7.7 Potassium (K) . 29 1.7.8 Sodium (Na) . 30 1.7.9 Zinc (Zn) .. 31 VI 2.3.3 Sample preparation for AAS . 50 2.4 Flame photometre for the determination ofsodium and 50 potassiUITI . 2.4.1 Reagents . 50 2.4.2 Procedure . 51 2.4.3 Measurements . 51 Chapter (3) Results and Discussion............................................. 54 Chapter (4): Conclusion and Recommendations 4.1 Conclusion................................................. 105 4.2 Recommendalions................................................... 107 Chapter (5) References.. ................................................................ 109 VIII

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then to my supervisor professor Mohammed Ahmed Hassan Eltayeb, .. Rain water harvested with the help of ground catchments will always.
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