Anti-abrasive nanocoatings : current and future applications

627 Pages·2015·46.53 MB·English

by  Mahmood Aliofkhazraei

Anti-Abrasive Nanocoatings
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Woodhead Publishing in Materials
Anti-Abrasive Nanocoatings
Current and future applications
Edited by
Mahmood Aliofkhazraei
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Contents
Listoffigures xi
Listoftables xxiii
Abouttheeditor xxv
Aboutthecontributors xxvii
Preface xli
Part One 1
1 Wear,frictionandpreventionoftribo-surfaces
bycoatings/nanocoatings 3
SunilMohanandAnitaMohan
1.1 Introduction 3
1.2 Frictionofmaterials 4
1.3 Wearinmetals,alloysandcomposites 10
1.4 Materialsandtheirselectionforwearandfrictionapplications 12
1.5 Coatings/nanocoatingsandsurfacetreatments 15
1.6 Conclusion 19
Acknowledgements 19
References 19
2 Aninvestigationintothetribologicalpropertyofcoatings
onmicro-andnanoscale 23
XuesongHan
2.1 Driversofstudyingtheoriginoftribologybehavior 23
2.2 Contactatnanometerscale 27
2.3 Atomicfrictionwithzeroseparation 37
2.4 Scratchingwearatatomicscale 47
2.5 Conclusion 54
References 54
3 Stressonanti-abrasiveperformanceofsol-gelderivednanocoatings 57
ShengzhaoWang
3.1 Classicalcurvaturestressforthinfilmsonplatesubstrates 58
3.2 Thermal stressofthinfilms 61
3.3 Whydodryingfilmscrack? 61
3.4 Cracksbystresscomefromconstraintofshrinkage
bythesubstrate 63
3.5 Rapidsol-gelfabricationtoconfronttensiletrailingcracks 66
vi Contents
3.6 Anti-abrasiveSiO filminapplication:self-assembling
2
covalentlybondednanocoating 68
3.7 Abrasivetest 69
3.8 Anti-abrasiveperformanceofsol-gelnanocoatings 72
3.9 Conclusion 76
Acknowledgments 77
References 77
4 Self-cleaningglass 81
KrishnanSurekhaandSureshbabuSundararajan
4.1 Introduction 81
4.2 Historyofglass 83
4.3 Self-cleaningglass 84
4.4 Hydrophiliccoating 85
4.5 Anti-reflectivecoating 86
4.6 Porousmaterials 86
4.7 PhotocatalyticactivityofTiO 88
2
4.8 Hydrophobiccoatings 89
4.9 Fabricationofself-cleaningglass 90
4.10 Applicationofself-cleaningglasses 99
Acknowledgements 99
References 99
5 Sol-gelnanocompositehardcoatings 105
RamachandraS.R.KalidindiandRaghavanSubasri
5.1 Introduction 105
5.2 Sol-gelnanocompositehardcoatings 106
5.3 Mechanicalpropertystudiesofsol-gelhardcoatings
onvarioussubstrates 110
5.4 Possibleapplicationsofhardcoatings 129
5.5 Summary 132
Acknowledgments 132
References 132
6 Processconsiderationsfornanostructuredcoatings 137
KalRenganathanSharma
6.1 Overview 137
6.2 Anti-reflectioncoatings 140
6.3 Fluidizedbedmethod 143
6.4 Electroplating 144
6.5 Nanografting 145
6.6 Plasmaspraycoating 145
6.7 Nanostructuringinthinfilms 146
6.8 Electrochemicaldeposition 147
6.9 Anti-corrosioncoating 149
6.10 Infraredtransparentelectromagneticshielding 149
Contents vii
6.11 Underlyingscience(cid:1)self-assembly 150
6.12 Conclusions 151
References 152
Part Two 155
7 Nanostructuredelectrolessnickel-boroncoatingsforwearresistance 157
Ve´roniqueVitryandFabienneDelaunois
7.1 Introduction 157
7.2 Synthesisofelectrolessnickel-boroncoatings 157
7.3 Morphologyandstructureofelectrolessnickel-boroncoatings 171
7.4 Mechanicalandwearpropertiesofnanocrystallineelectroless
nickel-boroncoatings 178
7.5 Corrosionresistance 191
7.6 Conclusion 192
References 195
8 Wearresistanceofnanocompositecoatings 201
VaheVardanyan,BouddahPoaty,Ve´ronicLandry,GregoryChauve,
TigranGalstian,andBernardRiedl
8.1 Introduction 201
8.2 Materialsandmethods 206
8.3 Resultsanddiscussion 211
8.4 Conclusions 220
Acknowledgments 220
References 221
9 Machiningmedicalgradetitaniumalloysusingnonabrasive
nanolayeredcuttingtools 225
MarkJ.Jackson,RodneyG.Handy,MichaelD.Whitfield,
JohnW.Burgess,GrantM.Robinson,TamaraNovakov,
WaqarAhmed,AhmedM.Elhissi,StJohnJ.Crean,DavidA.
Phoenix,A´lissonRochaMachado,andMarcioBaccidaSilva
9.1 MetallurgicalAspects 225
9.2 Machiningoftitaniumalloys 233
9.3 Machiningwithcoatedcuttingtools:acasestudy 234
9.4 Conclusions 246
Acknowledgments 246
References 246
10 Functionalnanostructuredcoatingsvialayer-by-layer
self-assembly 249
KatalinHalasz,GeorgeGrozdits,andLeventeCso´ka
10.1 Introduction 249
10.2 LbLprocess 250
viii Contents
10.3 LbL-depositednanostructuredcoatingswithdifferentfunctions 258
10.4 Conclusions 277
Acknowledgment 277
References 277
11 Theoreticalstudyonaninfluenceoffabricationparameters
onthequalityofsmartnanomaterials 283
VelaphiMsomi
11.1 Introduction 283
11.2 LiteraturesurveyonVO 284
2
11.3 Synthesistechniquesdescription 288
11.4 Conclusion 291
References 291
12 Formationofdensenanostructuredcoatingsbymicroarc
oxidationmethod 293
VladimirN.Malyshev
12.1 Introduction 293
12.2 PhenomenaofMAO-coatingformation 293
12.3 Voltage(cid:1)currentcharacteristics 295
12.4 Discussionaboutgrowthmechanism ofMAOcoating 297
12.5 Modeloffractalgrowthofthedensewear-resistantlayer 301
12.6 Macro-andmicrostructureofMAOcoatings 309
12.7 Wear-resistantproperties 315
12.8 Conclusion 327
References 327
13 Currenttrendsinmolecularfunctionalmonolayers 331
PrashantK.Sarswat,AmarchandSathyapalan,andMichaelL.Free
13.1 Introduction 331
13.2 Stepsforself-assembly 332
13.3 Mechanism 335
13.4 CharacterizationofSAMs 336
13.5 UseofSAMsforvariousapplications 337
13.6 Self-assembledmonolayersongoldsubstrates 341
13.7 Si-CmonolayerformationandC-Cbonding 342
13.8 Supramolecularassemblyonsurface(cid:1)host-guestinteractions
andothernon-covalentbonding 344
13.9 Self-assembledmonolayersonothersurfacessuch
astitaniananotubes 344
13.10 Chemicalandelectricalbiosensors 345
13.11 Qualityimprovement 345
13.12 Conclusions 346
References 347
Contents ix
14 Surfaceengineerednanostructuresonmetallicbiomedical
materialsforanti-abrasion 349
KelviiWeiGuo
14.1 Introduction 349
14.2 Surfacetechnologiesonmetallicbiomedicalmaterials
foranti-abrasion 353
14.3 Futureprospects 375
References 376
15 Theoreticalmodelingoffrictionandwearprocesses
atatomiclevel 385
YuriF.Migal
15.1 Introduction 385
15.2 MDmethod 387
15.3 Quantumchemistrymethods 389
15.4 Basictypesofproblems 391
15.5 Lubricationandone-electrontransfers 400
15.6 Conclusion 402
References 403
16 Mechanicalcharacterizationofthinfilmsbydepth-sensing
indentation 407
JorgeM.Antunes,Jose´V.Fernandes,andNatalyiaA.Sakharova
16.1 Introduction 407
16.2 Hardness 408
16.3 Young’smodulus 414
16.4 Conclusion 422
Acknowledgements 422
References 423
Part Three 427
17 Advancedbulkandthinfilmmaterialsforharshenvironment
MEMSapplications 429
CinziaCaliendoandFabioLoCastro
17.1 Introduction 429
17.2 Piezoelectricsubstrates 431
17.3 Non-piezoelectricsubstrates 436
17.4 Thinpiezoelectricfilms 437
17.5 Metalelectrodes 444
17.6 Conclusion 447
References 447