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ANALYSIS AND PERFORMANCE OF FIBER COMPOSITES THIRD EDITION Bhagwan D. Agarwal Consultant Lombard, Illinois, USA Lawrence J. Broutman Consultant Chicago, Illinois, USA K. Chandrashekhara University of Missouri-Rolla Rolla, Missouri, USA WILEY Analysis and Performance of Fiber Composites Third Edition Authorized reprint by Wiley India Pvt. Ltd., 4435-36/7, Ansari Road, Daryaganj, New Delhi - 110002. Copyright© 2006 by John Wiley & Sons, Inc. All rights reserved. Cover Image: WIADIMIR BULGAR/Science Photo Library/Corbis No part of this book, including interior design, cover design, and icons, may be reproduced or transmitted in any form except with the permission of John Wiley & Sons, lnc., 111 River Street, Hoboken, NJ 07030, (201) 748-6011, fax (201) 748-6008, or online at http: I /www.wiley.com/go/permissions. Limits of Liability/ Disclaimer of Warranty: The publisher and the author make no representations or warranties with respect to the accuracy or completeness of the contents of this work and specifically disclaim all warranties, including without limitation warranties of fitness for a particular purpose. No warranty may be created or extended by sales or promotional materials. The advice and strategies contained herein may not be suitable for every situation. This work is sold with the understanding that the publisher is not engaged in rendering legal, accounting, or other professional services. If professional assistance is required, the services of a competent professional person should be sought. Neither the publisher nor the author shall be liable for damages arising herefrom. The fact that an organization or website is referred to in this work as a citation and/or a potential source of further information does not mean that the author or the publisher endorses the information the organization or website may provide or recommendations it may make. Further, readers should be aware that Internet websites listed in this work may have changed or disappeared between when this work was written and when it is read. Wiley also publishes its books in a variety of electronic formats. Some content that appears in print may not be available in electronic books. For more information about Wiley products, visit our website at: www.wiley.com. Reprint: 2015 Printed at: Sai Printo Pack Pvt. Ltd. Delhi ISBN: 978-81-265-3636-8 CONTENTS Preface xiii 1 Introduction 1 I.I Definition I 1.2 Characteristics I 2 1.3 Classification I 3 1.4 Particulate Composites I 5 1.5 Fiber-Reinforced Composites I 7 1.6 Applications of Fiber Composites I 10 Exercise Problems I 14 References I 15 2 Fibers, Matrices, and Fabrication of Composites 16 2.1 Advanced Fibers I l 6 2.1.1 Glass Fibers I l 6 2.1.1.1 Production of Glass Fibers I 17 2.1.1.2 Glass Composition and Properties I 18 2.1.1.3 Su,face Treatment of Fibers: Sizes and Coupling Agents I 18 2.1.1.4 Forms of Glass Fiber I 21 2.1.2 Carbon and Graphite Fibers I 23 2.1.3 Aramid Fibers I 26 2.1.4 Boron Fibers I 27 2.1.5 Other Fibers I 28 2.2 Matrix Materials I 30 2.2.1 Polymers I 30 iv CONTENTS 2.2.1.1 Thermosetting and Thermoplastic Polymers I 31 2.2.1.2 Polymer Properties of Importance to the Composite I 31 2.2.1.3 Common Polymeric Matrix Materials I 34 2.2.1.4 Fillers I 39 2.2.2 Metals I 39 2.3 Fabrication of Composites 1 41 2.3.1 Fabrication of Thermosetting Resin Matrix Composites I 42 2.3.1.1 Hand Lay-up Technique I 43 2.3.1.2 Bag Molding Processes I 46 2.3.1.3 Resin Transfer Molding I 49 2.3.1.4 Filament Winding I 49 2.3.1.5 Pultrusion I 51 2.3.1.6 Preformed Molding Compounds I 53 2.3.2 Fabrication of Thermoplastic-Resin Matrix Composites (Short-Fiber Composites) I 55 27.3 Fabrication of Metal Matrix Composites I 58 2.3.4 Fabrication of Ceramic Matrix Composites I 59 Suggested Reading I 60 3 Behavior of Unidirectional Composites 62 3.1 Introduction I 62 3.1.1 Nomenchiture I 62 3.1.2 Volume and Weight Fractions I 64 3.2 Longitudjnal Behavior of Unidirectional C9mposites I 67 3.2.1 Initial Stiffness I 68 3.2.2 Load Sharing I 71 3.2.3 Behavior beyond Initial Deformation I 73 3.2.4 Failure Mechanism and Strength I 74 3.2.5 Factors Influencing Longitudinal Strei;igth and Stiffness I 76 · 3 .3 Transverse Stiffness· and Strength I 80 3.3.1 Constant-Stress Model I 80 3.3.2 Elasticity Methods of Stiffness Prediction I 83 3.3.3 Halpin-Tsai' Equations for Transverse Modulus I 85 CONTENTS V 3.3.4 Transvyrse Strength I 87 3.3.4.1 Micromechanics of Transverse Failure I 88 3.3.4.2 Prediction of Transverse Strength I 90 3.4 Prediction of Shear Modulus I 91 3.5 Prediction of Poisson's Ratio I 95 3.6 Failure Modes I 96 3.6.1 Failure under Longitudinal Tensile Loads I 100 3.6.2 Failure under Longitudinal Compressive Loads I 102 3.6.3 Failure under Transverse Tensile Loads I 106 3.6.4 Failure under Transverse Compressive Loads I 107 3.6.5 Failure under In-Plane Shear Loads I 107 3.7 Expansion Coefficients and Transport 'Properties I 108 3.7.l Thermal Expansion Coefficients I 108 3.7.2 Moisture Expansion Coefficients I 114 3.7.3 Transport Properties I 114 3.7.4 Mass Diffusion I 117 3.8 Typical Unidirectional Fiber Composite Properties I 123 Exercise Problems I 124 References I 129 4 Short-Fiber Composites 132 4.1 Introduction I 132 4.2 Theories of Stress Transfer I 133 4.2.1 Approximate Analysis of Stress Transfer I 133 4.2.2 Stress Distributions from FiniteJElement Analysis I 137 4.2.3 Average Fiber Stress I 139 4.3 Modulus and Strength of Short-Fiber Composites I 140 4.3.1 Prediction of Modulus I 141 4.3.2 Prediction of Strength I 145 4.3.3 Effect of Matrix Ductility I 150 4.4 Ribbon-Reinforced Composites I 152 Exercise Problems I 155 References I l 56 vi CONTENTS 5 Analysis of an Orthotropic Lamina 158 5.1 Introduction I 158 5.1.1 Orthotropic Materials I 158 5.2 Stress-Strain Relations and Engineering Constants I I 60 5 .2.1 Stress-Strain Relations for Specially Orthotropic Lamina I 161 5.2.2 Stress-Strain Relations for Generally Orthotropic Lamina I 164 5.2.3 Transformation of Engineering Constants I I 66 5.3 Hooke's Law and Stiffness and Compliance Matrices I 174 5.3.1 Geaeral Anisotropic Material I 174 5.3.2 Specially Orthotropic Material I 177 5.3.3 Transversely Isotropic Material I 180 5.3.4 Isotropic Material I 181 5.3.5 Specially Orthotropic Material under Plane Stress I 182 5.3.6 Compliance Tensor and Compliance Matrix I 184 5.3.7 Relations between Engineering Constants and Elements of Stiffness and Compliance Matrices I 185 5.3.8 Restrictions on Elastic Constants I 187 5.3.9 Transformation of Stiffness and Compliance Matrices I 189 5.3.10 Invariant Forms of Stiffness and Compliance Matrices I 194 5.4 Strengths ·of an Orthotropic Lamina I 196 5.4.1 Maximum-Stress Theory I 197 5.4.2 Maximum-Strain Theory I 200 5.4.3 Maximum-Work Theory I 203 5.4.4 Importance of Sign of Shear Stress on Strength of Composites I 205 Exercise Problems I 209 References I 212 6 Analysis of Laminated Composites 21~ 6.1 Introduction I 213 6.2 Laminate Strains I 213 6.3 Variation of Stresses in a Laminate 21 q CONTENTS vii 6.4 Resultant Forces and Moments: Synthesis of Stiffness Matrix I 218 6.5 Laminate Description System I 225 6.6 Construction and Properties of Special Laminates I 226 6.6.1 Symmetric Laminates I 227 6.6.2 Unidirectional, Cross-Ply, and Angle-Ply Laminates I 228 6.6.3 Quasi-isotropic Laminates I 229 6.7 Determination of Laminae Stresses and Strains I 238 6.8 Analysis of Laminates after Initial Failure I 247 6.9 Hygrothermal Stresses in Laminates I 263 6.9.1 Concepts of Thermal Stresses I 263 6.9.2 Hygrothermal Stress Calculations I 264 6.10 Laminate Analysis Through Computers I 272 Exercise Problems I 277 References I 281 7 Analysis of Laminated Plates and Beams 282 7.1 Introduction I 282 7.2 Governing Equations for Plates I 283 7 .2.1 Equilibrium Equations I 283 7.2.2 Equilibrium Equations in Terms of Displacements I 286 7 .3 Application of Plate Theory I 288 7.3.1 Bending I 288 7.3.1.1 Bending of General Laminates I 294 7.3.2 Buckling I 295 7.3.3 Free Vibrations I 301 7.4 Deformations Due to Transverse Shear I 306 7.4.1 First-Order Shear Deformation Theory I 306 7.4.1.1 Transverse Shear Deformation Effects in Bending of a Simply Supported Rectangular Specially Orthotropic Plate I 309 7.4.2 Higher-Order Shear Deformation Theory I 311 7 .5 Analysis of Laminated Beams I 314 viii CONTENTS 7.5.1 Governing Equations for Laminated Beams--/ 314 7.5.2 Application of Beam Theory I 315 7.5.2.1 Bending I 315 7.5.2.2 Buckling I 318 7.5.2.3 Free Vibrations I 319 Exercise Problems I 320 References I 322 8 Advanced Topics in Fiber Composites 324 8.1 Interlaminar Stresses and Free-Edge Effects I 324 8.1.1 Concepts of lnterlaminar Stresses I 324 8.1.2 Determination of Interlaminar Stresses I 32 6 8.1.3 Effect of Stacking Sequence on Interlaminar Stresses I 328 8.1.4 Approximate Solutions for Interlaminar Stresses I 330 8.1.5 Summary I 334 8.2 Fracture Mechanics of Fiber Composites I 335 8.2.1 Introduction I 335 8.2.1.1 Microscopic Failure Initiation I 335 8.2.1.2 Fracture Process in Composites I 336 8.2.2 Fracture Mechanics Concepts and Measures of Fracture Toughness I 338 8.2.2.1 Strain-Energy Release Rate (G) I 339 8.2.22 Stress-Intensity Factor (K) I 341 8.2.2.3 ]-Integral I 345 8.2.3 Fracture Toughness of Composite Laminates I 346 8.2.4 Whitney-Nuismer Failure Criteria for Notched Composites I 349 8.3 Joints for Composite Structures I 355 8.3. l Adhesively Bonded Joints I 355 8.3.1.1 Bonding Mechanisms I 355 8.3.1.2 Joint Configurations I 356 8.3.1.3 Joint Failure Modes I 357 8.3.1.4 Stresses in Joints I 358 8.3.1.5 Advantages and Disadvantages of Adhesively Bonded Joints I 359 CONTENTS ix 8.3.2 Mechanically Fastened Joints I .360 8.3.2.1 Failure Modes of Mechanically Fastened Joints I 360 8.3.2.2 Advantages and Disadvantages of Mechanically Fastened Joints I 361 8.3.3 Bonded-Fastened Joints I 361 Exercise Problems I 362 References I 363 9 Performance of Fiber Composites: Fatigue, Impact, and Environmental Effects 368 9 .1 Fatigue I 368 9.1.1 Introduction I 368 9.1.2 Fatigue Damage I 370 9.1.2.1 Damage/Crack Initiation I 370 9.1.2.2 Crack Arrest and Crack Branching I 370 9.1.2.3 Final Fracture I 373 9.1.2.4 Schematic Representation I 373 9.1.2.5 Damage Characterization I 374 9.1.2.6 Influence of Damage on Properties I 375 9 .1.3 Factors Influencing Fatigue Behavior of Composites I 378 9 .1.4 Empirical Relations for Fatigue Damage and Fatigue Life I 385 -- 9.1.5 Fatigue of High-Modulus Fiber-Reinforced Composites I 386 9.1.6 Fatigue of Short-Fiber Composites I 390 9 .2 Impact I 395 9.2.1 Introduction and Fracture Process I 395 9.2.2 Energy-Absorbing Mechanisms and Failure Models I 396 9.2.2.1 Fiber Breakage I 396 9.2.2.2 Matrix Deformation and Cracking I 398 9.2.2.3 Fiber Debonding I 399 9.2.2.4 Fiber Pullout I 399 9.2.2.5 Delamination Cracks I 401 9.2.3 Effect of Mater;als and Testing Variables on Impact Properties I 401 X CONTENTS 9.2.4 Hybrid Composites and Their Impact Strength /. 407 9.2.5 Damage Due to Low-Velocity Impact I 411 9.3 Environmental-Interaction Effects I 416 9 .3 .1 Fiber Strength I 416 9.3.1.l Features ofStress Corrosion I 416 9.3.1.2 Static Fatigue and Stress-Rupture of Fibers I 417 9.3.1.3 Stress Corrosion of Glass Fibers and GRP I 419 9.3.2 Matrix Effects I 422 9.3.2.l Effect of Temperature and Moisture I 422 9.3.2.2 Degradation at Elevated Temperatures I 426 9.3.2.3 Stress-Rupture Characteristics at Modest Temperatures I 429 Exercise Problems I 431 References I 431 10 Experimental Characterization of Composites 439 10.1 Introduction I 439 l 0.2 Measurement of Physical Properties I 440 10.2.l Density I 440 10.2.2 Constituent Weight and Volume Fractions I 441 10.2.3 Void Volume Fraction I 442 10.2.4 Thermal Expansion Coefficients I 442 10.2.5 Moisture Absorption and Diffusivity I 443 I 0.2.6 Moisture Expansion Coefficients I 444 I 0.3 Measurement of Mechanical Properties I 445 10.3.1 Properties in Tension I 445 I 0.3.2 Properties in Compression I 449 I 0.3.3 In-Place Shear Properties I 452 10.3.3.1 Torsion Tube Test I 452 10.3.3.2 Iosipescu Shear Test I 453 10.3.3.3 [±45Js Coupon Test I 455 10.3.3.4 Off-Axis Coupon Test I 456 10.3.3.5 Other Tests I 458 10.3.4 Flexural Properties I 459

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ANALYSIS AND. PERFORMANCE OF. FIBER COMPOSITES. THIRD EDITION. Bhagwan D. Agarwal. Consultant. Lombard, Illinois, USA. Lawrence J. Broutman. Consultant. Chicago, Illinois, USA. K. Chandrashekhara. University of Missouri-Rolla. Rolla, Missouri, USA. WILEY
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