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Advanced Thermoelectrics Materials, Contacts, Devices, and Systems Series in Materials Science and Engineering Recent books in the series: Advanced Thermoelectrics: Materials, Contacts, Devices, and Systems Zhifeng Ren, Yucheng Lan, Qinyong Zhang (Eds) Silicon Nanomaterials Sourcebook: Two-Volume Set Klaus D. Sattler (Ed) Silicon Nanomaterials Sourcebook: Low-Dimensional Structures, Quantum Dots, and Nanowires, Volume One Klaus D. Sattler (Ed) Silicon Nanomaterials Sourcebook: Hybrid Materials, Arrays, Networks, and Devices, Volume Two Klaus D. Sattler Conductive Polymers: Electrical Interactions in Cell Biology and Medicine Ze Zhang, Mahmoud Rouabhia, Simon E. Moulton (Eds) Physical Methods for Materials Characterisation, Third Edition Peter E J Flewitt, Robert K Wild Multiferroic Materials: Properties, Techniques, and Applications J Wang (Ed) Computational Modeling of Inorganic Nanomaterials S T Bromley, M A Zwijnenburg (Eds) Automotive Engineering: Lightweight, Functional, and Novel Materials B Cantor, P Grant, C Johnston Strained-Si Heterostructure Field Effect Devices C K Maiti, S Chattopadhyay, L K Bera Spintronic Materials and Technology Y B Xu, S M Thompson (Eds) Fundamentals of Fibre Reinforced Composite Materials A R Bunsell, J Renard Novel Nanocrystalline Alloys and Magnetic Nanomaterials B Cantor (Ed) 3-D Nanoelectronic Computer Architecture and Implementation D Crawley, K Nikolic, M Forshaw (Eds) Computer Modelling of Heat and Fluid Flow in Materials Processing C P Hong High-K Gate Dielectrics M Houssa (Ed) Metal and Ceramic Matrix Composites B Cantor, F P E Dunne, I C Stone (Eds) High Pressure Surface Science and Engineering Y Gogotsi, V Domnich (Eds) Advanced Thermoelectrics Materials, Contacts, Devices, and Systems Edited by Zhifeng Ren Yucheng Lan Qinyong Zhang CRC Press Taylor & Francis Group 6000 Broken Sound Parkway NW, Suite 300 Boca Raton, FL 33487-2742 © 2018 by Taylor & Francis Group, LLC CRC Press is an imprint of Taylor & Francis Group, an Informa business No claim to original U.S. Government works Printed on acid-free paper International Standard Book Number-13: 978-1-4987-6572-5 (Hardback) This book contains information obtained from authentic and highly regarded sources. Reasonable efforts have been made to publish reliable data and information, but the author and publisher cannot assume responsibility for the validity of all materials or the consequences of their use. The authors and publishers have attempted to trace the copy- right holders of all material reproduced in this publication and apologize to copyright holders if permission to publish in this form has not been obtained. If any copyright material has not been acknowledged please write and let us know so we may rectify in any future reprint. Except as permitted under U.S. Copyright Law, no part of this book may be reprinted, reproduced, transmitted, or utilized in any form by any electronic, mechanical, or other means, now known or hereafter invented, including pho- tocopying, microfilming, and recording, or in any information storage or retrieval system, without written permission from the publishers. For permission to photocopy or use material electronically from this work, please access www.copyright.com (http:// www .copyright.com/) or contact the Copyright Clearance Center, Inc. (CCC), 222 Rosewood Drive, Danvers, MA 01923, 978-750-8400. CCC is a not-for-profit organization that provides licenses and registration for a variety of users. For organizations that have been granted a photocopy license by the CCC, a separate system of payment has been arranged. Trademark Notice: Product or corporate names may be trademarks or registered trademarks, and are used only for identification and explanation without intent to infringe. Library of Congress Cataloging‑in‑Publication Data Names: Ren, Zhifeng, editor. | Lan, Yucheng, editor. | Zhang, Qinyong, editor. Title: Advanced thermoelectrics : materials, contacts, devices, and systems / edited by Zhifeng Ren, Yucheng Lan, Qinyong Zhang. Other titles: Series in materials science and engineering. Description: Boca Raton, FL : CRC Press, Taylor & Francis Group, [2017] | Series: Series in materials science and engineering | Includes bibliographical references. Identifiers: LCCN 2017010759| ISBN 9781498765725 (hardback ; alk. paper) | ISBN 1498765726 (hardback ; alk. paper) Subjects: LCSH: Thermoelectric materials. | Nanostructured materials. | Thermal conductivity. Classification: LCC TK2950 .A38 2017 | DDC 620.1/1297--dc23 LC record available at https://lccn.loc.gov/2017010759 Visit the Taylor & Francis Web site at http://www.taylorandfrancis.com and the CRC Press Web site at http://www.crcpress.com This book is dedicated to Dr. Jui H. Wang, the late Einstein Chair Professor at the State University of New York at Buffalo, who retired in 2006 at the age of 85 and passed away March 2016 at the age of 95. In 1990, I came to know Professor Jui H. Wang, who changed my life forever and kept giving me hope and encouragement to pursue persistently until successful. He took me in as a postdoctoral researcher to work with him on high-performance superconducting materials. Through his exemplary hard work, smart decisions, and devotion, we made breakthroughs in the areas of bulk thallium-based superconductors, long-length superconducting tapes, and superconducting films. Our joint work resulted in one paper in Science (vol. 271, pp. 329–332 [1996]) and two in Nature (vol. 387, pp. 481–483 [1997] and vol. 395, pp. 360–362 [1998]), in addition to over 60 in other journals and three major research grants from the National Science Foundation, Department of Energy, and Army Research Office all in 1998. In addition, our research branched into other areas such as carbon nanotubes, especially aligned carbon nanotubes, for which we jointly published a milestone paper in Science (vol. 282, pp. 1105–1107 [1998]), which opened a brand-new field for many people worldwide to follow on. Building from that success, I moved to the Department of Physics at Boston College as a tenure-track associate professor in 1999. In 2003, I teamed up with Professor Gang Chen at the Massachusetts Institute of Technology to study thermoelectric materials; we published our first paper in Science (vol. 320, pp. 634–638 [2008]) and have subsequently published more than 150 papers on thermoelectric materials, contacts, devices, and systems, thereby making it possible for me to edit this book. Since 2013, Ren has been with the University of Houston continuing the research on thermoelectrics and also branched into other fields such as high thermal conductivity materials (boron arsenide), efficient catalysts for hydrogen and oxygen evolution reactions (HER and OER) and water splitting, amphiphilic surfactant for enhanced oil recovery, etc. Zhifeng Ren Houston, Texas http://taylorandfrancis.com Contents Series Preface xi Preface xiii Editors xv Contributors xvii Part I thermoelectric Materials Chapter 1 Introduction to Thermoelectric Materials, Contacts, Devices, and Systems 3 Zhifeng Ren, Yucheng Lan, and Qinyong Zhang Chapter 2 Low-Temperature Thermoelectric Materials 9 Koen Vandaele, Joseph P. Heremans, Yiming Zhou, Li-Dong Zhao, Huaizhou Zhao, Zhifeng Ren, Machhindra Koirala, and Stephen R. Boona Chapter 3 Materials for Near-Room Temperatures 67 Weishu Liu, Yucheng Lan, Jiehe Sui, Zihang Liu, and Zhifeng Ren Chapter 4 IV–VI Compounds for Medium Temperatures 107 Qian Zhang, Yu Xiao, Li-Dong Zhao, Eyob Chere, Zhifeng Ren, Xiao Zhang, Cheng Chang, and E. M. Levin Chapter 5 Thermoelectric Sb-Based Skutterudites for Medium Temperatures 195 Gerda Rogl, Andriy Grytsiv, Ernst Bauer, and Peter Rogl Chapter 6 Mg BIV for Medium Temperatures 233 2 Tiejun Zhu, Guanting Yu, Xinbing Zhao, Weishu Liu, Zhifeng Ren, Johannes de Boor, and Udara Saparamadu Chapter 7 Ca Yb Mg Bi and Ca Yb Zn Sb -Related 1–2–2 1−x x 2 2 1−x x 2 2 Zintl Phases 279 Jing Shuai and Zhifeng Ren Chapter 8 Half-Heuslers for High Temperatures 297 Hao Zhang, Zhensong Ren, Shuo Chen, Zhifeng Ren, Ran He, Yucheng Lan, and Lihong Huang vii viii   ■   Contents Chapter 9 Silicon–Germanium Alloys 353 Yucheng Lan, Dezhi Wang, and Zhifeng Ren Chapter 10 Other Thermoelectric Materials 371 Pengfei Qiu, Xun Shi, Lidong Chen, Jiehe Sui, Jing Li, Zihang Liu, Zhifeng Ren, Takao Mori, and Jun Mao Chapter 11 Engineering of Materials 421 Mona Zebarjadi, Gang Chen, Zhifeng Ren, Sunmi Shin, Renkun Chen, Joseph P. Heremans, Bartlomiej Wiendlocha, Hyungyu Jin, Bo Wang, and Qinyong Zhang Chapter 12 Simulation of Phonons 471 David Broido, Matt Heine, Natalio Mingo, and Austin J. Minnich Chapter 13 Reliable Prediction of Efficiency and Output Power and Balance between Materials and Devices in Thermoelectric Power Generators 507 Hee Seok Kim, Weishu Liu, and Zhifeng Ren Chapter 14 Mechanical Properties of Thermoelectric Materials 555 Sonika Gahlawat, Kenneth White, Zhifeng Ren, Yasuo Kogo, and Tsutomu Iida Part II thermoelectric Contacts Chapter 15 Contact for Bi Te -Based Thermoelectric Leg 605 2 3 Weishu Liu, Yucheng Lan, and Zhifeng Ren Chapter 16 Contacts for Skutterudites 625 Qing Jie and Zhifeng Ren Chapter 17 Contacts for PbTe 635 Cheng-Chieh Li and C. Robert Kao Part III thermoelectric Modules and Systems Chapter 18 Bismuth Telluride Modules 661 Pham Hoang Ngan, Nini Pryds, and Li Han Contents   ■   ix Chapter 19 Half-Heusler Modules 683 Giri Raj Joshi, Yucheng Lan, and Zhifeng Ren Chapter 20 Silicide Modules: Practical Issues in Developing Mg Si with 2 Good Stability for Generating Power from Waste Heat Sources 697 Tsutomu Iida, Yasuo Kogo, Atsuo Yasumori, Keishi Nishio, and Naomi Hirayama Chapter 21 Oxide Modules 719 Le Thanh Hung, Ngo Van Nong, and Nini Pryds Chapter 22 Solar Thermoelectric Power Generators 735 Yucheng Lan and Zhifeng Ren Index 769

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