Table Of Content

Advanced Functional Metal-Organic Frameworks Due to the structural flexibility, large surface area, tailorable pore size and functional tenability, metal-organic frameworks (MOFs) can lead to materials with unique properties. This book covers the fundamental aspects of MOFs, their synthesis and modification, including their potential applications in different domains. The major focus is on applications including chemical, biosensors, catalysis, drug delivery, supercapacitors, energy storage, magnetics and their future perspectives. The volume: • Covers all aspects related to metal-organic frameworks (MOFs), including characterization, modification, applications and associated challenges • Illustrates designing and synthetic strategies for MOFs • Describes MOFs for gas adsorption, separation and purification, and their role in heterogeneous catalysis • Covers sensing of different types of noxious substances in the aqueous environment • Includes concepts of molecular magnetism, tunable magnetic properties and future aspects This book is aimed at graduate students, and researchers in material science, coordination and industrial chemistry, chemical and environmental engineering and clean technologies. Emerging Materials and Technologies Series Editor: Boris I. Kharissov The Emerging Materials and Technologies series is devoted to highlighting publications centered on emerging advanced materials and novel technologies. Attention is paid to those newly discovered or applied materials with potential to solve pressing societal problems and improve quality of life, corresponding to environmental pro- tection, medicine, communications, energy, transportation, advanced manufacturing and related areas. The series takes into account that, under present strong demands for energy, material and cost savings, as well as heavy contamination problems and worldwide pandemic conditions, the area of emerging materials and related scalable technologies is a highly interdisciplinary field, with the need for researchers, professionals and academics across the spectrum of engineering and technological disciplines. The main objective of this book series is to attract more attention to these materials and technologies and invite conversation among the international R&D community. Emerging Applications of Carbon Nanotubes and Graphene Edited by Bhanu Pratap Singh and Kiran M. Subhedar Micro to Quantum Supercapacitor Devices Fundamentals and Applications Abha Misra Application of Numerical Methods in Civil Engineering Problems M.S.H. Al-Furjan, M. Rabani Bidgoli, Reza Kolahchi, A. Farrokhian, and M.R. Bayati Advanced Functional Metal-Organic Frameworks Fundamentals and Applications Edited by Jay Singh, Nidhi Goel, Ranjana Verma and Ravindra Pratap Singh Nanoparticles in Diagnosis, Drug Delivery and Nanotherapeutics Edited by Divya Bajpai Tripathy, Anjali Gupta, Arvind Kumar Jain, Anuradha Mishra, and Kuldeep Singh For more information about this series, please visit: www.routledge.com/Emerging- Materials-and-Technologies/book-series/CRCEMT Advanced Functional Metal-Organic Frameworks Fundamentals and Applications Edited by Jay Singh, Nidhi Goel, Ranjana Verma and Ravindra Pratap Singh Designed cover image: © Shutterstock First edition published 2023 by CRC Press 6000 Broken Sound Parkway NW, Suite 300, Boca Raton, FL 33487-2742 and by CRC Press 4 Park Square, Milton Park, Abingdon, Oxon, OX14 4RN CRC Press is an imprint of Taylor & Francis Group, LLC © 2023 selection and editorial matter, Jay Singh, Nidhi Goel, Ranjana Verma and Ravindra Pratap Singh; individual chapters, the contributors Reasonable efforts have been made to publish reliable data and information, but the author and publisher cannot assume responsibility for the validity of all materials or the consequences of their use. The authors and publishers have attempted to trace the copyright holders of all material reproduced in this publication and apologize to copyright holders if permission to publish in this form has not been obtained. If any copyright material has not been acknowledged please write and let us know so we may rectify in any future reprint. Except as permitted under U.S. Copyright Law, no part of this book may be reprinted, reproduced, transmitted, or utilized in any form by any electronic, mechanical, or other means, now known or hereafter invented, including photocopying, microfilming and recording, or in any information storage or retrieval system, without written permission from the publishers. For permission to photocopy or use material electronically from this work, access www. copyright.com or contact the Copyright Clearance Center, Inc. (CCC), 222 Rosewood Drive, Danvers, MA 01923, 978-750-8400. For works that are not available on CCC please contact [email protected] Trademark notice: Product or corporate names may be trademarks or registered trademarks and are used only for identification and explanation without intent to infringe. ISBN: 978-1-032-17164-7 (hbk) ISBN: 978-1-032-17165-4 (pbk) ISBN: 978-1-003-25206-1 (ebk) DOI: 10.1201/9781003252061 Typeset in Times by MPS Limited, Dehradun Dedication Dedicated to those who care, conserve, and protect but do not destroy the beauty and unique characteristics of Kshit (Earth) Jal (Water) Pawak (Fire) Gagan (Sky) and Sameera (Air) Contents Editors.......................................................................................................................ix Contributors..............................................................................................................xi Preface.....................................................................................................................xiii Acknowledgments....................................................................................................xv Chapter 1 Overview: What are Metal-Organic Frameworks?............................1 Gunjan Nagpure, Shiva, Nidhi Goel, Ranjana Verma, Jay Singh and Ravindra Pratap Singh Chapter 2 Methods for the Preparation of Metal-Organic Frameworks...........17 Nidhi Goel, Shiva, Shubhranshu Mishra and Naresh Kumar Chapter 3 Properties and Factors Affecting the Preparation of Metal-Organic Frameworks.......................................................................................35 Chansi, Rashi Bhardwaj and Tinku Basu Chapter 4 Promising Functional Metal-Organic Frameworks for Gas Adsorption, Separation and Purification...........................................65 Shabnam Khan, Fahmina Zafar, Farasha Sama, M. Shahid and Mohammad Yasir Khan Chapter 5 Metal-Organic Frameworks in Heterogeneous Catalysis.................99 A. Manjceevan and K. Velauthamurty Chapter 6 Metal-Organic Frameworks as Chemical Sensors for Detection of Environmental Pollutants................................................................125 Nidhi Goel Chapter 7 Recent Advancements in Metal-Organic Frameworks for Drug Delivery...........................................................................................157 Sachin Mishra, Fulden Ulucan-Karnak and Cansu İlke Kuru Chapter 8 Metal-Organic Frameworks for the Development of Biosensors..169 Arpna Tamrakar, Kamlesh Kumar Nigam, Bani Mahanti, Arun Kumar and Mrituanjay D. Pandey vii viii Contents Chapter 9 Potentiality of Magnetic Metal-Organic Frameworks....................189 Sana Ahmed and Fahmina Zafar Chapter 10 Utility of Metal-Organic Frameworks in an Electrochemical Charge Storage................................................................................211 Anil Kumar, Usha Raju and Jyoti Chapter 11 Potential Redox Functions for Catalytic Hybrid Materials of Dimensional Cyanide-Bridged MOFs and Laccase Protein..........237 Takashiro Akitsu, Yoshiyuki Sato and Daisuke Nakane Chapter 12 Metal-Organic Framework–Based Electrochemical Immunosensors for Virus Detection...............................................269 Stephen Rathinaraj Benjamin, Eli José Miranda Ribeiro Júnior, Geanne Matos de Andrade and Reinaldo Barreto Oriá Chapter 13 Future Challenges and Opportunities in the Field of Metal-Organic Frameworks.....................................................................................289 Naresh Kumar and Nidhi Goel Index......................................................................................................................313 Editors Dr Jay Singh is currently working as an assistant professor at the Department of Chemistry, Institute of Sciences, Banaras Hindu University, Varanasi, Uttar Pradesh, since 2017. He received his PhD degree in polymer science from Motilal Nehru National Institute of Technology in 2010 and his MSc and BSc from Allahabad University, Uttar Pradesh, India. He had a postdoctoral fellow at National Physical Laboratory, New Delhi, Chonbuk National University, South Korea and Delhi Technological University, Delhi. Dr. Jay has received many prestigious fellowships like CSIR (RA), DST-Young Scientist fellowship, DST- INSPIRE faculty award, etc. He is actively engaged in the development of nanomaterials (CeO , NiO, rare-earth metal oxide, Ni, Nife O , Cu O, graphene, 2 2 4 2 RGO, etc.), based nanobiocomposite, conducting polymer and self-assembled monolayers based clinically important biosensors for estimation of bioanalaytes such as cholesterol, xanthine, glucose, pathogens and pesticides/toxins using DNA and antibodies. Dr. Jay has published more than 80 international research papers with total citations of more than 3,600 and an h-index being 34. He has completed/ running various research projects in different funding agencies. He has many edited/ authored books (under pipeline) and has authored more than 20 book chapters of internationally reputed press for publications, namely Elsevier, Springer Nature, IOP, Wiley and CRC. He is actively engaged in fabricating metal oxide-based biosensors for clinical diagnosis, food packaging applications, drug delivery and tissue engineering applications. His research has contributed significantly toward the fundamental understanding of interfacial charge transfer processes and sensing aspects of metal nanoparticles. Dr Nidhi Goel received her doctorate in chemistry from the Indian Institute of Technology Roorkee, India. After postdoctoral research (Young Scientist) from the Indian Institute of Science Bangalore, Karnataka, India, she started her independent academic career as an assistant professor in the Department of Chemistry, Institute of Science, Banaras Hindu University, Varanasi, India. Her research focuses on developing strategies, based on supramolecular building approaches, for rational construction of functional metal- organic frameworks. Their prospective uses include magnetic, luminescence and sensing applications. She is also working on topics such as drug design, medicinal chemistry and chemical biology. Dr. Goel has published 51 peer-reviewed research papers and book chapters in reputed international journals/books. Moreover, Dr. Goel is editing several books with international publishers. She has been the principal investigator on three research projects from the government of India, and ix