Activation of Unreactive Bonds and Organic Synthesis PDF
265 Pages·1999·2.067 MB·English
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The principal idea of this volume is to offer a Capita Selecta of unconventional and thought-provoking topics in organometallic chemistry, presented by experts in each field. As intended, this approach leads either to reviews covering a specific uncommon class of organometallic compounds or to overviews which relate uncommon physical properties with various classes of organometallic compounds. Content: Structure and electrochemistry of transition metal carbonyl clusters with interstitial or semi-interstitial atoms: contrast between nitrides or phosphides and carbides / Piero Zanello -- Unusual nuclear magnetic shielding and coupling constants related to unusual bonding situations / Bernd Wrackmeyer -- Deuterium spin lattice relaxation and deuterium quadrupole coupling constants. A novel strategy for characterization of transition metal hydrides and dihydrogen complexes in solution / Vladimir I. Bakhmutov -- NMR studies of ligand nuclei in organometallic compounds -- new information from solid-state NMR techniques / Guy M. Bernard, Roderick E. Wasylishen -- Metal atom motion in some iron organometallics / Rolfe H. Herber -- Magnetic communication in binuclear organometallic complexes mediated by carbon-rich bridges / Frďřic Paul, Claude Lapinte -- Molecular cluster complexes with facial arene ligands / Herbert Wadepohl -- Cobaltafulvenes and cobaltapentalenes: highly polar metallacyclic II-systems with unusual properties / Herbert Wadepohl -- Novel highly nucleophilic ylidic ligands for the preparation of unusually stable metal complexes / Norbert Kuhn, Martin Göhner, Gernot Frenking, Yu Chen -- Supramolecular interactions in structures of organic antimony and Bismuth compounds / Gabor Balz̀s, Hans Joachim Breunig. Abstract: The principal idea of this volume is to offer a Capita Selecta of unconventional and thought-provoking topics in organometallic chemistry, presented by experts in each field. As intended, this approach leads either to reviews covering a specific uncommon class of organometallic compounds or to overviews which relate uncommon physical properties with various classes of organometallic compounds
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